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Recent applications of C-H functionalization in complex natural product synthesis

Chemical Society reviews, 2018-12, Vol.47 (23), p.8925-8967

2018

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Pd-Catalyzed, ortho C–H Methylation and Fluorination of Benzaldehydes Using Orthanilic Acids as Transient Directing Groups

Journal of the American Chemical Society, 2018-02, Vol.140 (8), p.2789-2792

2018

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Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis

Nature communications, 2015-12, Vol.6 (1), p.10093-10093, Article 10093

2015

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The Uranyl Cation as a Visible-Light Photocatalyst for C(sp3)−H Fluorination

Angewandte Chemie (International ed.), 2016-07, Vol.55 (31), p.8923-8927

International ed. in English, 2016

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An Enantiospecific Synthesis of Jiadifenolide

Angewandte Chemie (International ed.), 2014-05, Vol.53 (21), p.5332-5335

International ed. in English, 2014

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Palladium-Catalyzed Ring-Forming Aminoacetoxylation of Alkenes

Journal of the American Chemical Society, 2005-06, Vol.127 (21), p.7690-7691

2005

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Toward a mild dehydroformylation using base-metal catalysis

Chemical science (Cambridge), 2017-03, Vol.8 (3), p.1954-1959

2017

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Protein-Reactive Natural Products

Angewandte Chemie (International ed.), 2005-09, Vol.44 (36), p.5788-5809

2005

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Installation of multiple aryl ether crosslinks onto non-native substrate peptides by the vancomycin OxyB

Tetrahedron, 2018-06, Vol.74 (26), p.3231-3237

2018

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Rapid Construction of a Benzo-Fused Indoxamycin Core Enabled by Site-Selective C−H Functionalizations

Angewandte Chemie (International ed.), 2016-07, Vol.55 (29), p.8270-8274

International ed. in English, 2016

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Development of a Bio‐Inspired Dual Catalytic System for Alkane Dehydrogenation

Israel journal of chemistry, 2017-04, Vol.57 (3-4), p.259-269

2017

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Crystal Structure of the Cyclostreptin-Tubulin Adduct: Implications for Tubulin Activation by Taxane-Site Ligands

International journal of molecular sciences, 2019-03, Vol.20 (6), p.1392

2019

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Target discovery in small-molecule cell-based screens by in situ proteome reactivity profiling

Nature biotechnology, 2005-10, Vol.23 (10), p.1303-1307

2005

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Synthesis of Fluorenones from Benzaldehydes and Aryl Iodides: Dual C–H Functionalizations Using a Transient Directing Group

Organic letters, 2017-03, Vol.19 (5), p.1140-1143

2017

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A concise synthesis of the molecular framework of pleuromutilin

Chemical communications (Cambridge, England), 2011-01, Vol.47 (5), p.1500-1502

2011

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Pd-Catalyzed Ortho C–H Hydroxylation of Benzaldehydes Using a Transient Directing Group

Organic letters, 2017-12, Vol.19 (23), p.6280-6283

2017

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In Vitro Reconstitution of OxyA Enzymatic Activity Clarifies Late Steps in Vancomycin Biosynthesis

ACS chemical biology, 2017-09, Vol.12 (9), p.2248-2253

2017

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Toward a Synthesis of Hirsutellone B by the Concept of Double Cyclization

Journal of organic chemistry, 2013-10, Vol.78 (19), p.9584-9607

2013

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Tandem Diels–Alder and Retro-Ene Reactions of 1‑Sulfenyl- and 1‑Sulfonyl-1,3-dienes as a Traceless Route to Cyclohexenes

Journal of the American Chemical Society, 2014-07, Vol.136 (28), p.9918-9921

2014

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Synthesis of the Furanosteroidal Antibiotic Viridin

Angewandte Chemie (International ed.), 2004-04, Vol.43 (15), p.1998-2001

2004

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Proteomic profiling of mechanistically distinct enzyme classes using a common chemotype

Nature biotechnology, 2002-08, Vol.20 (8), p.805-809

2002

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A Rapid, Asymmetric Synthesis of the Decahydrofluorene Core of the Hirsutellones

Organic letters, 2009-02, Vol.11 (3), p.701-703

2009

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Albert Eschenmoser (1925–2023)

Science (American Association for the Advancement of Science), 2023-09, Vol.381 (6663), p.1158-1158

2023

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An interrupted Ugi reaction enables the preparation of substituted indoxyls and aminoindoles

Tetrahedron, 2009-04, Vol.65 (16), p.3096-3101

2009

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New luciferin-based probe substrates for human CYP26A1

Biochemistry and biophysics reports, 2020-12, Vol.24, p.100861-100861, Article 100861

2020

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Recent applications of C-H functionalization in complex natural product synthesis

Pd-Catalyzed, ortho C–H Methylation and Fluorination of Benzaldehydes Using Orthanilic Acids as Transient Directing Groups

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis

The Uranyl Cation as a Visible-Light Photocatalyst for C(sp3)−H Fluorination

An Enantiospecific Synthesis of Jiadifenolide

Palladium-Catalyzed Ring-Forming Aminoacetoxylation of Alkenes

Toward a mild dehydroformylation using base-metal catalysis

Protein-Reactive Natural Products

Installation of multiple aryl ether crosslinks onto non-native substrate peptides by the vancomycin OxyB

Rapid Construction of a Benzo-Fused Indoxamycin Core Enabled by Site-Selective C−H Functionalizations

Development of a Bio‐Inspired Dual Catalytic System for Alkane Dehydrogenation

Crystal Structure of the Cyclostreptin-Tubulin Adduct: Implications for Tubulin Activation by Taxane-Site Ligands

Target discovery in small-molecule cell-based screens by in situ proteome reactivity profiling

Synthesis of Fluorenones from Benzaldehydes and Aryl Iodides: Dual C–H Functionalizations Using a Transient Directing Group

A concise synthesis of the molecular framework of pleuromutilin

Pd-Catalyzed Ortho C–H Hydroxylation of Benzaldehydes Using a Transient Directing Group

In Vitro Reconstitution of OxyA Enzymatic Activity Clarifies Late Steps in Vancomycin Biosynthesis

Toward a Synthesis of Hirsutellone B by the Concept of Double Cyclization

Tandem Diels–Alder and Retro-Ene Reactions of 1‑Sulfenyl- and 1‑Sulfonyl-1,3-dienes as a Traceless Route to Cyclohexenes

Synthesis of the Furanosteroidal Antibiotic Viridin

Proteomic profiling of mechanistically distinct enzyme classes using a common chemotype

A Rapid, Asymmetric Synthesis of the Decahydrofluorene Core of the Hirsutellones

Albert Eschenmoser (1925–2023)

An interrupted Ugi reaction enables the preparation of substituted indoxyls and aminoindoles

New luciferin-based probe substrates for human CYP26A1

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