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Metal-mediated activation of carbon dioxide in the gas phase: Mechanistic insight derived from a combined experimental/computational approach

Coordination chemistry reviews, 2017-03, Vol.334, p.112-123

Schwarz, Helmut

2017

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Doping Effects in Cluster-Mediated Bond Activation

Angewandte Chemie (International ed.), 2015-08, Vol.54 (35), p.10090-10100

Schwarz, Helmut

International ed. in English, 2015

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Ménage-à-trois: single-atom catalysis, mass spectrometry, and computational chemistry

Catalysis science & technology, 2017, Vol.7 (19), p.432-4314

Schwarz, Helmut

2017

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How and Why Do Cluster Size, Charge State, and Ligands Affect the Course of Metal-Mediated Gas-Phase Activation of Methane?

Israel journal of chemistry, 2014-10, Vol.54 (10), p.1413-1431

Schwarz, Helmut

2014

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Nichtlineare Regelungssysteme: Systemtheoretische Grundlagen

Schwarz, Helmut

1, 2019

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Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry

Angewandte Chemie (International ed.), 2012-06, Vol.51 (23), p.5544-5555

International ed. in English, 2012

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Complete cleavage of the N≡N triple bond by Ta₂N⁺ via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle

Proceedings of the National Academy of Sciences - PNAS, 2019-10, Vol.116 (43), p.21416-21420

2019

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Effects of Ligands, Cluster Size, and Charge State in Gas-Phase Catalysis: A Happy Marriage of Experimental and Computational Studies

Catalysis letters, 2012-11, Vol.142 (11), p.1265-1278

2012

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Gas-Phase Activation of Methane by Ligated Transition-Metal Cations

Proceedings of the National Academy of Sciences - PNAS, 2008-11, Vol.105 (47), p.18114-18119

2008

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Relativistic Effects in Gas-Phase Ion Chemistry: An Experimentalist's View

Angewandte Chemie (International ed.), 2003-09, Vol.42 (37), p.4442-4454

Schwarz, Helmut

2003

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On the spin-forbiddeness of gas-phase ion–molecule reactions: a fruitful intersection of experimental and computational studies

International journal of mass spectrometry, 2004-09, Vol.237 (1), p.75-105

Schwarz, Helmut

2004

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Bond Activation by Metal–Carbene Complexes in the Gas Phase

Accounts of chemical research, 2016-03, Vol.49 (3), p.494-502

2016

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Chemistry with Methane: Concepts Rather than Recipes

Angewandte Chemie (International ed.), 2011-10, Vol.50 (43), p.10096-10115

Schwarz, Helmut

International ed. in English, 2011

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Intrinsic Reactivity of Diatomic 3d Transition-Metal Carbides in the Thermal Activation of Methane: Striking Electronic Structure Effects

Journal of the American Chemical Society, 2019-01, Vol.141 (1), p.599-610

2019

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Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts

Angewandte Chemie (International ed.), 2005-04, Vol.44 (16), p.2336-2354

2005

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Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions

Journal of the American Chemical Society, 2016-09, Vol.138 (35), p.11368-11377

2016

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Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane

Angewandte Chemie (International ed.), 2017-08, Vol.56 (34), p.10219-10223

International ed. in English, 2017

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Unexpected Mechanistic Variants in the Thermal Gas-Phase Activation of Methane

Organometallics, 2017-01, Vol.36 (1), p.8-17

2017

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Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO2]+ (X, Y = Al, Si, Mg): Competition between Proton-Coupled Electron Transfer and Hydrogen-Atom Transfer

Journal of the American Chemical Society, 2016-06, Vol.138 (25), p.7973-7981

2016

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Thermal hydrogen-atom transfer from methane: A mechanistic exercise

Chemical physics letters, 2015-06, Vol.629, p.91-101

Schwarz, Helmut

2015

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Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al2ZnO4].

Angewandte Chemie (International ed.), 2017-11, Vol.56 (45), p.14297-14300

International ed. in English, 2017

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Efficient Room-Temperature Activation of Methane by TaN+ under C−N Coupling

Angewandte Chemie (International ed.), 2016-09, Vol.55 (38), p.11678-11681

International ed. in English, 2016

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Mechanistic Study on the Gas-Phase Generation of “Rollover”-Cyclometalated [M(bipy − H)]+ (M = Ni, Pd, Pt)

Organometallics, 2010-11, Vol.29 (22), p.6002-6011

2010

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Thermal Dehydrogenation of Methane by [ReN]

Angewandte Chemie (International ed.), 2016-11, Vol.55 (47), p.14863-14866

International ed. in English, 2016

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Bonding in Cationic MCH2+ (M=K-La, Hf-Rn): A Theoretical Study on Periodic Trends

Chemistry : a European journal, 2010-05, Vol.16 (20), p.5882-5888

2010

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Metal-mediated activation of carbon dioxide in the gas phase: Mechanistic insight derived from a combined experimental/computational approach

Doping Effects in Cluster-Mediated Bond Activation

Ménage-à-trois: single-atom catalysis, mass spectrometry, and computational chemistry

How and Why Do Cluster Size, Charge State, and Ligands Affect the Course of Metal-Mediated Gas-Phase Activation of Methane?

Nichtlineare Regelungssysteme: Systemtheoretische Grundlagen

Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry

Complete cleavage of the N≡N triple bond by Ta₂N⁺ via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle

Effects of Ligands, Cluster Size, and Charge State in Gas-Phase Catalysis: A Happy Marriage of Experimental and Computational Studies

Gas-Phase Activation of Methane by Ligated Transition-Metal Cations

Relativistic Effects in Gas-Phase Ion Chemistry: An Experimentalist's View

On the spin-forbiddeness of gas-phase ion–molecule reactions: a fruitful intersection of experimental and computational studies

Bond Activation by Metal–Carbene Complexes in the Gas Phase

Chemistry with Methane: Concepts Rather than Recipes

Intrinsic Reactivity of Diatomic 3d Transition-Metal Carbides in the Thermal Activation of Methane: Striking Electronic Structure Effects

Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts

Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions

Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane

Unexpected Mechanistic Variants in the Thermal Gas-Phase Activation of Methane

Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO2]+ (X, Y = Al, Si, Mg): Competition between Proton-Coupled Electron Transfer and Hydrogen-Atom Transfer

Thermal hydrogen-atom transfer from methane: A mechanistic exercise

Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al2ZnO4].

Efficient Room-Temperature Activation of Methane by TaN+ under C−N Coupling

Mechanistic Study on the Gas-Phase Generation of “Rollover”-Cyclometalated [M(bipy − H)]+ (M = Ni, Pd, Pt)

Thermal Dehydrogenation of Methane by [ReN]

Bonding in Cationic MCH2+ (M=K-La, Hf-Rn): A Theoretical Study on Periodic Trends

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