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The Combined C–H Functionalization/Cope Rearrangement: Discovery and Applications in Organic Synthesis

Accounts of chemical research, 2012-06, Vol.45 (6), p.923-935

2012

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Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture

Journal of the American Chemical Society, 2013-05, Vol.135 (19), p.7122-7125

2013

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Facile Synthesis of Unsymmetrical Acridines and Phenazines by a Rh(III)-Catalyzed Amination/Cyclization/Aromatization Cascade

Journal of the American Chemical Society, 2013-08, Vol.135 (34), p.12548-12551

2013

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Rhodium-Catalyzed [3 + 2] Annulation of Indoles

Journal of the American Chemical Society, 2010-01, Vol.132 (2), p.440-441

2010

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Preparation of Heteroaryl Ethers from Azine N‑Oxides and Alcohols

Organic letters, 2016-03, Vol.18 (6), p.1362-1365

2016

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Rhodium Carbenoid Approach for Introduction of 4-Substituted (Z)-Pent-2-enoates into Sterically Encumbered Pyrroles and Indoles

Organic letters, 2010-03, Vol.12 (5), p.924-927

2010

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Organophotochemical SNAr Reactions of Mildly Electron‐Poor Fluoroarenes

European journal of organic chemistry, 2020-05, Vol.2020 (18), p.2766-2770

2020

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Catalyst-Controlled Formal [4 + 3] Cycloaddition Applied to the Total Synthesis of (+)-Barekoxide and (−)-Barekol

Journal of the American Chemical Society, 2010-09, Vol.132 (35), p.12422-12425

2010

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Asymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E

Journal of the American Chemical Society, 2009-06, Vol.131 (23), p.8329-8332

2009

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On the Mechanism and Selectivity of the Combined C−H Activation/Cope Rearrangement

Journal of the American Chemical Society, 2011-04, Vol.133 (13), p.5076-5085

2011

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Construction of 1‑Heteroaryl-3-azabicyclo[3.1.0]hexanes by sp3–sp2 Suzuki–Miyaura and Chan–Evans–Lam Coupling Reactions of Tertiary Trifluoroborates

Organic letters, 2017-05, Vol.19 (9), p.2450-2453

2017

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Bi(OTf)3-, TfOH-, and TMSOTf-Mediated, One-Pot Epoxide Rearrangement, Addition, and Intramolecular Silyl-Modified Sakurai (ISMS) Cascade toward Dihydropyrans: Comparison of Catalysts and Role of Bi(OTf)3

Journal of organic chemistry, 2011-11, Vol.76 (22), p.9269-9277

2011

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BiBr3-Initiated Tandem Addition/Silyl-Prins Reactions to 2,6-Disubstituted Dihydropyrans

Journal of organic chemistry, 2006-09, Vol.71 (18), p.7071-7074

2006

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Alkynoate Synthesis through the Vinylogous Reactivity of Rhodium(II) Carbenoids

Angewandte Chemie (International ed.), 2012-08, Vol.51 (34), p.8636-8639

International ed. in English, 2012

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Sequential Transformations to Access Polycyclic Chemotypes: Asymmetric Crotylation and Metal Carbenoid Reactions

Angewandte Chemie (International ed.), 2011-06, Vol.50 (26), p.5938-5942

International ed. in English, 2011

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Rh 2 ( S -biTISP) 2 -Catalyzed Asymmetric Functionalization of Indoles and Pyrroles with Vinylcarbenoids

Organic letters, 2012-04, Vol.14 (7), p.1934-1937

2012

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Synthesis of 2,6-disubstituted dihydropyrans via an efficient BiBr3-initiated three component, one-pot cascade

Tetrahedron, 2009-08, Vol.65 (34), p.6834-6839

2009

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Rhodium(III)-Catalyzed Alkenyl CH Bond Functionalization: Convergent Synthesis of Furans and Pyrroles

Angewandte Chemie (International ed.), 2013-01, Vol.52 (2), p.629-633

2013

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Sequential Xanthalation and O‑Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl Trifluoromethyl Ethers

Journal of organic chemistry, 2019-12, Vol.84 (24), p.15767-15776

2019

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Expedient synthesis of gem-dialkylbenzyl heterocycles through olefinic hydroarylation

Tetrahedron, 2015-12, Vol.71 (50), p.9509-9514

2015

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Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes

Chemical science (Cambridge), 2012-01, Vol.3 (10), p.3088

2012

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Synthesis of Highly Substituted Aminotetrahydropyrans Enabled by Stereospecific Multivector C–H Functionalization

Organic letters, 2024-04, Vol.26 (14), p.2729-2732

2024

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Organophotochemical S N Ar Reactions of Mildly Electron‐Poor Fluoroarenes

European journal of organic chemistry, 2020-05, Vol.2020 (18), p.2766-2770

2020

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Exploratory Process Development of a Pulmonary Arterial Hypertension Clinical Compound via a Late-Stage Pd-Catalyzed Buchwald–Hartwig C–N Coupling

Synthesis (Stuttgart), 2024-02, Vol.56 (4), p.686-692

2024

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Reversal of the Regiochemistry in the Rhodium-Catalyzed [4+3] Cycloaddition between Vinyldiazoacetates and Dienes

Angewandte Chemie (International ed.), 2014-11, Vol.53 (48), p.13083-13087

International ed. in English, 2014

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The Combined C–H Functionalization/Cope Rearrangement: Discovery and Applications in Organic Synthesis

Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture

Facile Synthesis of Unsymmetrical Acridines and Phenazines by a Rh(III)-Catalyzed Amination/Cyclization/Aromatization Cascade

Rhodium-Catalyzed [3 + 2] Annulation of Indoles

Preparation of Heteroaryl Ethers from Azine N‑Oxides and Alcohols

Rhodium Carbenoid Approach for Introduction of 4-Substituted (Z)-Pent-2-enoates into Sterically Encumbered Pyrroles and Indoles

Organophotochemical SNAr Reactions of Mildly Electron‐Poor Fluoroarenes

Catalyst-Controlled Formal [4 + 3] Cycloaddition Applied to the Total Synthesis of (+)-Barekoxide and (−)-Barekol

Asymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E

On the Mechanism and Selectivity of the Combined C−H Activation/Cope Rearrangement

Construction of 1‑Heteroaryl-3-azabicyclo[3.1.0]hexanes by sp3–sp2 Suzuki–Miyaura and Chan–Evans–Lam Coupling Reactions of Tertiary Trifluoroborates

Bi(OTf)3-, TfOH-, and TMSOTf-Mediated, One-Pot Epoxide Rearrangement, Addition, and Intramolecular Silyl-Modified Sakurai (ISMS) Cascade toward Dihydropyrans: Comparison of Catalysts and Role of Bi(OTf)3

BiBr3-Initiated Tandem Addition/Silyl-Prins Reactions to 2,6-Disubstituted Dihydropyrans

Alkynoate Synthesis through the Vinylogous Reactivity of Rhodium(II) Carbenoids

Sequential Transformations to Access Polycyclic Chemotypes: Asymmetric Crotylation and Metal Carbenoid Reactions

Rh 2 ( S -biTISP) 2 -Catalyzed Asymmetric Functionalization of Indoles and Pyrroles with Vinylcarbenoids

Synthesis of 2,6-disubstituted dihydropyrans via an efficient BiBr3-initiated three component, one-pot cascade

Rhodium(III)-Catalyzed Alkenyl CH Bond Functionalization: Convergent Synthesis of Furans and Pyrroles

Sequential Xanthalation and O‑Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl Trifluoromethyl Ethers

Expedient synthesis of gem-dialkylbenzyl heterocycles through olefinic hydroarylation

Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes

Synthesis of Highly Substituted Aminotetrahydropyrans Enabled by Stereospecific Multivector C–H Functionalization

Organophotochemical S N Ar Reactions of Mildly Electron‐Poor Fluoroarenes

Exploratory Process Development of a Pulmonary Arterial Hypertension Clinical Compound via a Late-Stage Pd-Catalyzed Buchwald–Hartwig C–N Coupling

Reversal of the Regiochemistry in the Rhodium-Catalyzed [4+3] Cycloaddition between Vinyldiazoacetates and Dienes

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