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Metal alkoxides: models for metal oxides. 17. Reductive cleavage of carbon monoxide to carbide and oxide by ditungsten and tetratungsten alkoxides. Crystal and molecular structures of W4(.mu.4-C)(OCH2-c-Pen)14, W4(.mu.4-C)(O)(OCH2-tert-Bu)12 and W4(.mu.4-C)(O)(O-i-Pr)12

Journal of the American Chemical Society, 1992-08, Vol.114 (18), p.7056-7065

1992

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Spiked-triangular versus puckered-square geometry in 64-electron osmium clusters. Synthesis and structure of Os4(CO)15(L) (L = CO, PF3, P(OCH2)3CMe)

Organometallics, 1990-10, Vol.9 (10), p.2754-2762

1990

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Reactions of the 12-electron alkoxide-supported tungsten clusters W4(OR)12 (R = CH2-iso-Pr, cyclopentylmethyl) with isocyanides, nitriles, nitric oxide, and alkynes. Comparison with the reactivity of W2(OR)6 compounds

Inorganic chemistry, 1992-09, Vol.31 (20), p.4081-4083

1992

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Photochemical synthesis of trinuclear cluster compounds of osmium and a Group 6 metal atom. Structures of (OC)5M[Os(CO)3(PMe3)]2 (M = chromium, tungsten), (OC)5Mo{Os(CO)3[P(OMe)3]}2/[(MeO)3P](OC)4OsMo(CO)5 (1/1), and (OC)4W[(.mu.-H)Os(CO)3(PMe3)]2

Organometallics, 1992-11, Vol.11 (11), p.3555-3565

1992

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The new binary carbonyl tetraosmium tetradecacarbonyl: an example of carbonyl exchange on the infrared time scale

Organometallics, 1988-08, Vol.7 (8), p.1867-1869

1988

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Derivatives of the type Os4(.mu.-H)(CO)14(ER3) (E = Si, Ge, Sn; R = Me, Ph): structure of tetradecacarbonyl(.mu.-hydrido)(trimethylstannyl)tetraosmium

Inorganic chemistry, 1989-11, Vol.28 (23), p.4212-4216

1989

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Synthesis, structure, and fluxional properties of osmium cluster [(OC)4(tert-BuNC)Os]Os3(CO)11. Evidence for restricted rotation about a metal-metal bond

Organometallics, 1990-01, Vol.9 (1), p.52-59

1990

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Nonrigidity in the isomers of osmium cluster Os3(.mu.-H)2(CO)9(CNBu-tert). Structure of the green isomer

Organometallics, 1990-01, Vol.9 (1), p.45-51

1990

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Synthesis and structure of tetraosmium hexadecacarbonyl, a metal carbonyl analog of cyclobutane

Journal of the American Chemical Society, 1987-12, Vol.109 (26), p.8111-8112

1987

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Evidence for centrally directed bonds in trinuclear metal cluster compounds: the apparent free rotation of the Cr(CO)5 unit in (OC)5Cr[Os(CO)3(PMe3)]2

Journal of the American Chemical Society, 1988-06, Vol.110 (13), p.4451-4453

1988

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Structures of the new binary metal carbonyl Os4(CO)15 and (.eta.5-C5Me5)(OC)IrOs3(CO)11. Clusters with three-center-two-electron metal-metal bonds?

Journal of the American Chemical Society, 1987-11, Vol.109 (23), p.7220-7222

1987

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Reductive cleavage of carbon monoxide to carbide and oxide by ditungsten and tetratungsten alkoxides. Crystal and molecular structures of W4(μ4-C)(OCH2-c-Pen)14, W4(μ4-C)(O)(OCH2-t-Bu)12, and W4(μ4-C)(O)(O-i-Pr)12

Journal of the American Chemical Society, 1992-08, Vol.114 (18), p.7056-7065

1992

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The new binary carbonyl Os4(CO)14: an example of carbonyl exchange on the infrared time scale?

Organometallics, 1988-08, Vol.7 (8), p.1867-1869

1988

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Synthese, Struktur und Bindungsverhältnisse von [CpCoW2(OCH2tBu)6] sowie Bemerkungen über gemeinsame Eigenschaften von CO und CpCo

Angewandte Chemie, 1992-07, Vol.104 (7), p.889-891

1992

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Synthesis and structure of Os4(CO)16, a metal carbonyl analogue of cyclobutane

Journal of the American Chemical Society, 1987-12, Vol.109 (26), p.8111-8112

1987

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Synthesis, structure, and nonrigidity of Os 4 (CO) 15 , Os 4 (CO) 13 (PMe 3 )[P(OMe) 3 ], and Os 4 (CO) 14 (CNBu t )

Canadian journal of chemistry, 1995-07, Vol.73 (7), p.1223-1235

1995

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The tetranuclear carbonyls of osmium and some related derivatives

Johnston, Victor J

1989

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Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W4(μ4-C)(OCH2-c-C5H9)14

Journal of organometallic chemistry, 1990-08, Vol.394 (1-3), p.c16-c20

1990

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Synthesis, structure, and fluxional properties of [(OC)4(ButNC)Os]Os3(CO)11. Evidence for restricted rotation about a metal-metal bond

Organometallics, 1990, Vol.9 (1), p.52-59

1990

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A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands : W4(OCH2Pri)12(μ2,μ4-CO)(CO)2

Journal of organometallic chemistry, 1990-08, Vol.394 (1-3), p.265-274

1990

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Nonrigidity in the isomers of Os3(μ-H)2(CO)9(CNBut). Structure of the green isomer

Organometallics, 1990, Vol.9 (1), p.45-51

1990

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A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands: W 4(OCH 2Pr i) 12(η 2,μ 4-CO)(CO) 2

Journal of organometallic chemistry, 1990, Vol.394 (1), p.265-274

1990

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Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W 4(μ 4-C)(OCH 2-c-C 5H 9) 14

Journal of organometallic chemistry, 1990, Vol.394 (1), p.c16-c20

1990

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A trinuclear cluster of osmium and molybdenum. Crystal structure of the co-crystallized molecules MoOs 2(CO) 11[P(OMe) 3] 2 and [(MeO) 3P](OC) 4OsMo(CO) 5

Journal of organometallic chemistry, 1987, Vol.319 (2), p.C25-C27

1987

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Synthese, Struktur und Bindungsverhältnisse von [CpCoW2(OCH2tBu)6] sowie Bemerkungen über gemeinsame Eigenschaften von CO und CpCo

Angewandte Chemie, 1992-07, Vol.104 (7), p.889-891

1992

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Metal alkoxides: models for metal oxides. 17. Reductive cleavage of carbon monoxide to carbide and oxide by ditungsten and tetratungsten alkoxides. Crystal and molecular structures of W4(.mu.4-C)(OCH2-c-Pen)14, W4(.mu.4-C)(O)(OCH2-tert-Bu)12 and W4(.mu.4-C)(O)(O-i-Pr)12

Spiked-triangular versus puckered-square geometry in 64-electron osmium clusters. Synthesis and structure of Os4(CO)15(L) (L = CO, PF3, P(OCH2)3CMe)

Reactions of the 12-electron alkoxide-supported tungsten clusters W4(OR)12 (R = CH2-iso-Pr, cyclopentylmethyl) with isocyanides, nitriles, nitric oxide, and alkynes. Comparison with the reactivity of W2(OR)6 compounds

Photochemical synthesis of trinuclear cluster compounds of osmium and a Group 6 metal atom. Structures of (OC)5M[Os(CO)3(PMe3)]2 (M = chromium, tungsten), (OC)5Mo{Os(CO)3[P(OMe)3]}2/[(MeO)3P](OC)4OsMo(CO)5 (1/1), and (OC)4W[(.mu.-H)Os(CO)3(PMe3)]2

The new binary carbonyl tetraosmium tetradecacarbonyl: an example of carbonyl exchange on the infrared time scale

Derivatives of the type Os4(.mu.-H)(CO)14(ER3) (E = Si, Ge, Sn; R = Me, Ph): structure of tetradecacarbonyl(.mu.-hydrido)(trimethylstannyl)tetraosmium

Synthesis, structure, and fluxional properties of osmium cluster [(OC)4(tert-BuNC)Os]Os3(CO)11. Evidence for restricted rotation about a metal-metal bond

Nonrigidity in the isomers of osmium cluster Os3(.mu.-H)2(CO)9(CNBu-tert). Structure of the green isomer

Synthesis and structure of tetraosmium hexadecacarbonyl, a metal carbonyl analog of cyclobutane

Evidence for centrally directed bonds in trinuclear metal cluster compounds: the apparent free rotation of the Cr(CO)5 unit in (OC)5Cr[Os(CO)3(PMe3)]2

Structures of the new binary metal carbonyl Os4(CO)15 and (.eta.5-C5Me5)(OC)IrOs3(CO)11. Clusters with three-center-two-electron metal-metal bonds?

Reductive cleavage of carbon monoxide to carbide and oxide by ditungsten and tetratungsten alkoxides. Crystal and molecular structures of W4(μ4-C)(OCH2-c-Pen)14, W4(μ4-C)(O)(OCH2-t-Bu)12, and W4(μ4-C)(O)(O-i-Pr)12

The new binary carbonyl Os4(CO)14: an example of carbonyl exchange on the infrared time scale?

Synthese, Struktur und Bindungsverhältnisse von [CpCoW2(OCH2tBu)6] sowie Bemerkungen über gemeinsame Eigenschaften von CO und CpCo

Synthesis and structure of Os4(CO)16, a metal carbonyl analogue of cyclobutane

Synthesis, structure, and nonrigidity of Os 4 (CO) 15 , Os 4 (CO) 13 (PMe 3 )[P(OMe) 3 ], and Os 4 (CO) 14 (CNBu t )

The tetranuclear carbonyls of osmium and some related derivatives

Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W4(μ4-C)(OCH2-c-C5H9)14

Synthesis, structure, and fluxional properties of [(OC)4(ButNC)Os]Os3(CO)11. Evidence for restricted rotation about a metal-metal bond

A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands : W4(OCH2Pri)12(μ2,μ4-CO)(CO)2

Nonrigidity in the isomers of Os3(μ-H)2(CO)9(CNBut). Structure of the green isomer

A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands: W 4(OCH 2Pr i) 12(η 2,μ 4-CO)(CO) 2

Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W 4(μ 4-C)(OCH 2-c-C 5H 9) 14

A trinuclear cluster of osmium and molybdenum. Crystal structure of the co-crystallized molecules MoOs 2(CO) 11[P(OMe) 3] 2 and [(MeO) 3P](OC) 4OsMo(CO) 5

Synthese, Struktur und Bindungsverhältnisse von [CpCoW2(OCH2tBu)6] sowie Bemerkungen über gemeinsame Eigenschaften von CO und CpCo

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