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From Enzyme Models to Model Enzymes

1, 2009

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Fast Amide Bond Cleavage Assisted by a Secondary Amino and a Carboxyl Group-A Model for yet Unknown Peptidases?

Molecules (Basel, Switzerland), 2019-02, Vol.24 (3), p.572

2019

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The Most Reactive Amide As a Transition-State Mimic For cis–trans Interconversion

Journal of the American Chemical Society, 2015-01, Vol.137 (2), p.926-930

2015

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New light on phosphate transfer from triesters

Biochimica et biophysica acta, 2013-01, Vol.1834 (1), p.454-463

2013

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Fundamentals of Phosphate Transfer

Accounts of chemical research, 2015-07, Vol.48 (7), p.1806-1814

2015

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Theoretical Study of the Importance of the Spectator Groups on the Hydrolysis of Phosphate Triesters

Journal of organic chemistry, 2012-08, Vol.77 (16), p.7061-7070

2012

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Gemini Surfactants: New Synthetic Vectors for Gene Transfection

Angewandte Chemie (International ed.), 2003-04, Vol.42 (13), p.1448-1457

2003

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Intramolecular Catalysis of Phosphodiester Hydrolysis by Two Imidazoles

Journal of the American Chemical Society, 2010-06, Vol.132 (24), p.8513-8523

2010

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Rational Approaches to the Design of Cationic Gemini Surfactants for Gene Delivery

Journal of the American Chemical Society, 2001-07, Vol.123 (26), p.6215-6220

2001

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Efficiency of Proton Transfer Catalysis in Models and Enzymes

Accounts of chemical research, 1997-07, Vol.30 (7), p.290-296

Kirby, Anthony J

1997

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Activating Water: Efficient Intramolecular General Base Catalysis of the Hydrolysis of a Phosphate Triester

Chemistry : a European journal, 2009-08, Vol.15 (34), p.8475-8479

2009

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Enzyme Mechanisms, Models, and Mimics

Angewandte Chemie (International ed.), 1996-04, Vol.35 (7), p.706-724

Kirby, Anthony J.

1996

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The role of hydrophobicity in supramolecular polymer/surfactant catalysts: An understandable model for enzymatic catalysis

Journal of colloid and interface science, 2021-04, Vol.588, p.456-468

2021

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Physical Organic Chemistry: A Personal Reflection

Israel journal of chemistry, 2016-01, Vol.56 (1), p.93-95

Kirby, Anthony J.

2016

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Supramolecular Polymer/Surfactant Complexes as Catalysts for Phosphate Transfer Reactions

ACS catalysis, 2017-03, Vol.7 (3), p.2230-2239

2017

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The Most Twisted Amide: Structure and Reactions

Angewandte Chemie (International ed.), 1998-04, Vol.37 (6), p.785-786

1998

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Thorpe-Ingold effects in cyclizations to five-membered and six-membered rings containing planar segments. The rearrangement of N(1)-alkyl-substituted dihydroorotic acids to hydantoinacetic acids in base

Organic & biomolecular chemistry, 2004-04, Vol.2 (7), p.1098-1103

2004

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On the Magnitude and Specificity of Medium Effects in Enzyme-like Catalysts for Proton Transfer

Journal of organic chemistry, 2001-08, Vol.66 (17), p.5866-5874

2001

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Phosphorylimidazole Derivatives: Potentially Biosignaling Molecules

Journal of organic chemistry, 2011-10, Vol.76 (19), p.8003-8008

2011

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Intramolecular General Base Catalysis in the Hydrolysis of a Phosphate Diester. Calculational Guidance to a Choice of Mechanism

Journal of organic chemistry, 2013-02, Vol.78 (4), p.1343-1353

2013

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Major mechanistic differences between the reactions of hydroxylamine with phosphate di- and tri-esters

Organic & biomolecular chemistry, 2013-10, Vol.11 (37), p.6272-6284

2013

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Kinetic and computational evidence for an intermediate in the hydrolysis of sulfonate esters

Organic & biomolecular chemistry, 2012-10, Vol.10 (40), p.8095-8101

2012

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Characterization of Proton-Transfer Catalysis by Serum Albumins

Journal of the American Chemical Society, 2000-02, Vol.122 (6), p.1022-1029

2000

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Dephosphorylation Reactions of Mono‑, Di‑, and Triesters of 2,4-Dinitrophenyl Phosphate with Deferoxamine and Benzohydroxamic Acid

Journal of organic chemistry, 2012-12, Vol.77 (23), p.10907-10913

2012

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Biochemistry Enzymes under the nanoscope

Nature (London), 2008-11, Vol.456 (7218), p.45-47

2008

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From Enzyme Models to Model Enzymes

Fast Amide Bond Cleavage Assisted by a Secondary Amino and a Carboxyl Group-A Model for yet Unknown Peptidases?

The Most Reactive Amide As a Transition-State Mimic For cis–trans Interconversion

New light on phosphate transfer from triesters

Fundamentals of Phosphate Transfer

Theoretical Study of the Importance of the Spectator Groups on the Hydrolysis of Phosphate Triesters

Gemini Surfactants: New Synthetic Vectors for Gene Transfection

Intramolecular Catalysis of Phosphodiester Hydrolysis by Two Imidazoles

Rational Approaches to the Design of Cationic Gemini Surfactants for Gene Delivery

Efficiency of Proton Transfer Catalysis in Models and Enzymes

Activating Water: Efficient Intramolecular General Base Catalysis of the Hydrolysis of a Phosphate Triester

Enzyme Mechanisms, Models, and Mimics

The role of hydrophobicity in supramolecular polymer/surfactant catalysts: An understandable model for enzymatic catalysis

Physical Organic Chemistry: A Personal Reflection

Supramolecular Polymer/Surfactant Complexes as Catalysts for Phosphate Transfer Reactions

The Most Twisted Amide: Structure and Reactions

Thorpe-Ingold effects in cyclizations to five-membered and six-membered rings containing planar segments. The rearrangement of N(1)-alkyl-substituted dihydroorotic acids to hydantoinacetic acids in base

On the Magnitude and Specificity of Medium Effects in Enzyme-like Catalysts for Proton Transfer

Phosphorylimidazole Derivatives: Potentially Biosignaling Molecules

Intramolecular General Base Catalysis in the Hydrolysis of a Phosphate Diester. Calculational Guidance to a Choice of Mechanism

Major mechanistic differences between the reactions of hydroxylamine with phosphate di- and tri-esters

Kinetic and computational evidence for an intermediate in the hydrolysis of sulfonate esters

Characterization of Proton-Transfer Catalysis by Serum Albumins

Dephosphorylation Reactions of Mono‑, Di‑, and Triesters of 2,4-Dinitrophenyl Phosphate with Deferoxamine and Benzohydroxamic Acid

Biochemistry Enzymes under the nanoscope

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