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Exploiting Enzymatic Dynamic Reductive Kinetic Resolution (DYRKR) in Stereocontrolled Synthesis

Advanced synthesis & catalysis, 2015-05, Vol.357 (8), p.1619-1632

2015

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Mix-and-inject XFEL crystallography reveals gated conformational dynamics during enzyme catalysis

Proceedings of the National Academy of Sciences - PNAS, 2019-12, Vol.116 (51), p.25634-25640

2019

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Author Correction: Integrative network analyses of transcriptomics data reveal potential drug targets for acute radiation syndrome

Scientific reports, 2021-03, Vol.11 (1), p.7057-7057, Article 7057

2021

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General Linker Diversification Approach to Bivalent Ligand Assembly: Generation of an Array of Ligands for the Cation-Independent Mannose 6-Phosphate Receptor

Organic letters, 2017-08, Vol.19 (16), p.4267-4270

2017

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Human Serine Racemase: Key Residues/Active Site Motifs and Their Relation to Enzyme Function

Frontiers in molecular biosciences, 2019-03, Vol.6, p.8-8

2019

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Rapid Entry into Biologically Relevant α,α-Difluoroalkylphosphonates Bearing Allyl Protection–Deblocking under Ru(II)/(IV)-Catalysis

Organic letters, 2019-12, Vol.21 (24), p.9846-9851

2019

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Use of fluorinated functionality in enzyme inhibitor development: Mechanistic and analytical advantages

Journal of fluorine chemistry, 2008-09, Vol.129 (9), p.731-742

2008

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"Cassette" In Situ Enzymatic Screening Identifies Complementary Chiral Scaffolds for Hydrolytic Kinetic Resolution Across a Range of Epoxides

Angewandte Chemie (International ed.), 2007-01, Vol.46 (37), p.7010-7014

2007

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“Zipped Synthesis” by Cross-Metathesis Provides a Cystathionine β‑Synthase Inhibitor that Attenuates Cellular H2S Levels and Reduces Neuronal Infarction in a Rat Ischemic Stroke Model

ACS central science, 2016-04, Vol.2 (4), p.242-252

2016

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Rapid Enantioselective and Diastereoconvergent Hybrid Organic/Biocatalytic Entry into the Oseltamivir Core

Journal of organic chemistry, 2021-05, Vol.86 (9), p.6494-6503

2021

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Combining a Clostridial Enzyme Exhibiting Unusual Active Site Plasticity with a Remarkably Facile Sigmatropic Rearrangement: Rapid, Stereocontrolled Entry into Densely Functionalized Fluorinated Phosphonates for Chemical Biology

Journal of the American Chemical Society, 2015-03, Vol.137 (10), p.3600-3609

2015

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Synthesis and Deployment of an Elusive Fluorovinyl Cation Equivalent: Access to Quaternary α‑(1′-Fluoro)vinyl Amino Acids as Potential PLP Enzyme Inactivators

Journal of the American Chemical Society, 2017-10, Vol.139 (40), p.14077-14089

2017

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Use of a Robust Dehydrogenase from an Archael Hyperthermophile in Asymmetric Catalysis−Dynamic Reductive Kinetic Resolution Entry into (S)-Profens

Journal of the American Chemical Society, 2010-05, Vol.132 (17), p.5930-5931

2010

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Information-Rich, Dual-Function 13C/2H‑Isotopic Crosstalk NMR Assay for Human Serine Racemase (hSR) Provides a PLP-Enzyme “Partitioning Fingerprint” and Reveals Disparate Chemotypes for hSR Inhibition

Journal of the American Chemical Society, 2023-02, Vol.145 (5), p.3158-3174

2023

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Integrative network analyses of transcriptomics data reveal potential drug targets for acute radiation syndrome

Scientific reports, 2021-03, Vol.11 (1), p.5585-5585, Article 5585

2021

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A Review of Radiation-Induced Alterations of Multi-Omic Profiles, Radiation Injury Biomarkers, and Countermeasures

Radiation research, 2023-01, Vol.199 (1), p.89

2023

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Biomacromolecule-Assisted Screening for Reaction Discovery and Catalyst Optimization

Chemical reviews, 2022-08, Vol.122 (16), p.13800-13880

2022

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Crystal Structures of Cystathionine β‑Synthase from Saccharomyces cerevisiae: One Enzymatic Step at a Time

Biochemistry (Easton), 2018-06, Vol.57 (22), p.3134-3145

2018

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Information-Rich, Dual-Function 13 C/ 2 H-Isotopic Crosstalk NMR Assay for Human Serine Racemase (hSR) Provides a PLP-Enzyme "Partitioning Fingerprint" and Reveals Disparate Chemotypes for hSR Inhibition

Journal of the American Chemical Society, 2023-02, Vol.145 (5), p.3158-3174

2023

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Human serine racemase structure/activity relationship studies provide mechanistic insight and point to position 84 as a hot spot for β-elimination function

The Journal of biological chemistry, 2017-08, Vol.292 (34), p.13986-14002

2017

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Enantioselective, Ketoreductase-Based Entry into Pharmaceutical Building Blocks: Ethanol as Tunable Nicotinamide Reductant

Organic letters, 2009-01, Vol.11 (2), p.305-308

2009

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Mono- and Bivalent Ligands Bearing Mannose 6-Phosphate (M6P) Surrogates: Targeting the M6P/Insulin-Like Growth Factor II Receptor

Organic letters, 2004-12, Vol.6 (26), p.4921-4924

2004

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Enzyme-Assisted Asymmetric Total Synthesis of (−)-Podophyllotoxin and (−)-Picropodophyllin

Journal of organic chemistry, 2000-02, Vol.65 (3), p.847-860

2000

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A set of phosphatase-inert “molecular rulers” to probe for bivalent mannose 6-phosphate ligand–receptor interactions

Bioorganic & medicinal chemistry, 2008-05, Vol.18 (10), p.3085-3089

2008

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A new dehydrogenase from Clostridium acetobutylicum for asymmetric synthesis: dynamic reductive kinetic resolution entry into the Taxotère side chain

Chemical communications (Cambridge, England), 2011-01, Vol.47 (8), p.2420-2422

2011

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Exploiting Enzymatic Dynamic Reductive Kinetic Resolution (DYRKR) in Stereocontrolled Synthesis

Mix-and-inject XFEL crystallography reveals gated conformational dynamics during enzyme catalysis

Author Correction: Integrative network analyses of transcriptomics data reveal potential drug targets for acute radiation syndrome

General Linker Diversification Approach to Bivalent Ligand Assembly: Generation of an Array of Ligands for the Cation-Independent Mannose 6-Phosphate Receptor

Human Serine Racemase: Key Residues/Active Site Motifs and Their Relation to Enzyme Function

Rapid Entry into Biologically Relevant α,α-Difluoroalkylphosphonates Bearing Allyl Protection–Deblocking under Ru(II)/(IV)-Catalysis

Use of fluorinated functionality in enzyme inhibitor development: Mechanistic and analytical advantages

"Cassette" In Situ Enzymatic Screening Identifies Complementary Chiral Scaffolds for Hydrolytic Kinetic Resolution Across a Range of Epoxides

“Zipped Synthesis” by Cross-Metathesis Provides a Cystathionine β‑Synthase Inhibitor that Attenuates Cellular H2S Levels and Reduces Neuronal Infarction in a Rat Ischemic Stroke Model

Rapid Enantioselective and Diastereoconvergent Hybrid Organic/Biocatalytic Entry into the Oseltamivir Core

Combining a Clostridial Enzyme Exhibiting Unusual Active Site Plasticity with a Remarkably Facile Sigmatropic Rearrangement: Rapid, Stereocontrolled Entry into Densely Functionalized Fluorinated Phosphonates for Chemical Biology

Synthesis and Deployment of an Elusive Fluorovinyl Cation Equivalent: Access to Quaternary α‑(1′-Fluoro)vinyl Amino Acids as Potential PLP Enzyme Inactivators

Use of a Robust Dehydrogenase from an Archael Hyperthermophile in Asymmetric Catalysis−Dynamic Reductive Kinetic Resolution Entry into (S)-Profens

Information-Rich, Dual-Function 13C/2H‑Isotopic Crosstalk NMR Assay for Human Serine Racemase (hSR) Provides a PLP-Enzyme “Partitioning Fingerprint” and Reveals Disparate Chemotypes for hSR Inhibition

Integrative network analyses of transcriptomics data reveal potential drug targets for acute radiation syndrome

A Review of Radiation-Induced Alterations of Multi-Omic Profiles, Radiation Injury Biomarkers, and Countermeasures

Biomacromolecule-Assisted Screening for Reaction Discovery and Catalyst Optimization

Crystal Structures of Cystathionine β‑Synthase from Saccharomyces cerevisiae: One Enzymatic Step at a Time

Information-Rich, Dual-Function 13 C/ 2 H-Isotopic Crosstalk NMR Assay for Human Serine Racemase (hSR) Provides a PLP-Enzyme "Partitioning Fingerprint" and Reveals Disparate Chemotypes for hSR Inhibition

Human serine racemase structure/activity relationship studies provide mechanistic insight and point to position 84 as a hot spot for β-elimination function

Enantioselective, Ketoreductase-Based Entry into Pharmaceutical Building Blocks: Ethanol as Tunable Nicotinamide Reductant

Mono- and Bivalent Ligands Bearing Mannose 6-Phosphate (M6P) Surrogates: Targeting the M6P/Insulin-Like Growth Factor II Receptor

Enzyme-Assisted Asymmetric Total Synthesis of (−)-Podophyllotoxin and (−)-Picropodophyllin

A set of phosphatase-inert “molecular rulers” to probe for bivalent mannose 6-phosphate ligand–receptor interactions

A new dehydrogenase from Clostridium acetobutylicum for asymmetric synthesis: dynamic reductive kinetic resolution entry into the Taxotère side chain

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