Details

Autor(en) / Beteiligte

• Park, Jihye
• Hinckley, Allison C
• Huang, Zhehao
• Feng, Dawei
• Yakovenko, Andrey A
• Lee, Minah
• Chen, Shucheng
• Zou, Xiaodong
• Bao, Zhenan

Titel

Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal–Organic Framework

Ist Teil von

• Journal of the American Chemical Society, 2018-11, Vol.140 (44), p.14533-14537

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Conductive metal–organic frameworks (c-MOFs) have shown outstanding performance in energy storage and electrocatalysis. Varying the bridging metal species and the coordinating atom are versatile approaches to tune their intrinsic electronic properties in c-MOFs. Herein we report the first synthesis of the oxygen analog of M3(C6X6)2 (X = NH, S) family using Cu­(II) and hexahydroxybenzene (HHB), namely Cu-HHB [Cu3(C6O6)2], through a kinetically controlled approach with a competing coordination reagent. We also successfully demonstrate an economical synthetic approach using tetrahydroxyquinone as the starting material. Cu-HHB was found to have a partially eclipsed packing between adjacent 2D layers and a bandgap of approximately 1 eV. The addition of Cu-HHB to the family of synthetically realized M3(C6X6)2 c-MOFs will enable greater understanding of the influence of the organic linkers and metals, and further broadens the range of applications for these materials.