Chemistry : a European journal, 2016-08, Vol.22 (33), p.11597-11600
2016
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Details
- Autor(en) / Beteiligte
- Titel
- A Short Synthesis of Aphanamol I in Both Racemic and Enantiopure Forms
- Ist Teil von
- Chemistry : a European journal, 2016-08, Vol.22 (33), p.11597-11600
- Ort / Verlag
- Germany: Blackwell Publishing Ltd
- Erscheinungsjahr
- 2016
- Quelle
- Wiley Online Library Journals Frontfile Complete
- Beschreibungen/Notizen
- A short synthesis of the biologically active sesquiterpene natural product (+)‐aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclization, and a ring‐expanding Claisen rearrangement. Get shorty: A short synthesis of the biologically active sesquiterpene natural product (+)‐aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclization, and a ring‐expanding Claisen rearrangement.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0947-6539eISSN: 1521-3765DOI: 10.1002/chem.201602669Titel-ID: cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5096262
- Format
- –
- Schlagworte
- aphanamol, Biological Products, Catalysis, Catalysts, Chemistry, Claisen rearrangement, Communication, Communications, conjugate addition, Conjugates, Cyclization, Enantiomers, Natural products, Oxidation-Reduction, radical cyclization, Radicals, Sesquiterpenes - chemical synthesis, Sesquiterpenes - chemistry, Stereoisomerism, Synthesis, total synthesis