Details

Autor(en) / Beteiligte

• Luo, Yusen
• Tran, Jens H
• Wächtler, Maria
• Schulz, Martin
• Barthelmes, Kevin
• Winter, Andreas
• Rau, Sven
• Schubert, Ulrich S
• Dietzek, Benjamin

Titel

Remote control of electronic coupling - modification of excited-state electron-transfer rates in Ru(tpy) 2 -based donor-acceptor systems by remote ligand design

Ist Teil von

• Chemical communications (Cambridge, England), 2019-02, Vol.55 (16), p.2273-2276

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A comprehensive understanding of how the molecular structure influences the electronic coupling is crucial in optimizing (supra) molecular assemblies for photoinduced electron transfer. Here, we report that the electronic coupling underlying electron transfer from a phenothiazine donor to a photoexcited Ru(tpy)2 acceptor is modulated by substitution of the second (remote) tpy-ligand.