Details

Autor(en) / Beteiligte

• Zhao, Huaiqing
• Zhou, Xi
• Li, Bo
• Liu, Xiufen
• Guo, Ningxin
• Lu, Zhengliang
• Wang, Shoufeng

Titel

Rhodium(III)-Catalyzed C(sp3)–H Bond Aminocarbonylation with Isocyanates

Ist Teil von

• Journal of organic chemistry, 2018-04, Vol.83 (7), p.4153-4159

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Rh­(III)-catalyzed C­(sp3)–H bond aminocarbonylation of 8-methylquinolines and isocyanates has been realized under mild conditions. This approach is applicable to different aryl and alkyl isocyanates, leading to the synthesis of various α-quinolinyl amide compounds in moderate to excellent yields. A plausible mechanism for this transformation is proposed according to the experimental results obtained.