Angewandte Chemie (International ed.), 2013-07, Vol.52 (31), p.7958-7962
International ed. in English, 2013
Details
- Autor(en) / Beteiligte
- Titel
- Enantiopure Water-Soluble [Fe4L6] Cages: Host-Guest Chemistry and Catalytic Activity
- Ist Teil von
- Angewandte Chemie (International ed.), 2013-07, Vol.52 (31), p.7958-7962
- Auflage
- International ed. in English
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2013
- Link zum Volltext
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Inside information: The new enantiopure cage molecule ΔΔΔΔ‐Fe4L6 (and its enantiomer, ΛΛΛΛ‐Fe4L6) was prepared by subcomponent self‐assembly. It binds a range of organic guests (A, see scheme) in its cavity and distinguishes between the enantiomers of a chiral organic guest. Host ΔΔΔΔ‐Fe4L6 is also a catalyst for the hydrolysis (giving B and C) of the neurotoxic organophosphate dichlorvos.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201302136Titel-ID: cdi_proquest_miscellaneous_1701052339
- Format
- –
- Schlagworte
- Cage molecules, Cages, Catalysis, Catalytic activity, chirality, Enantiomers, Holes, host-guest systems, Hydrolysis, Iron - chemistry, Ligands, Models, Molecular, Organophosphates, Organophosphates - chemistry, Pyridines - chemistry, Self assembly, Stereoisomerism, supramolecular chemistry, Water - chemistry