Details

Autor(en) / Beteiligte

• Bhadra, Debabrata
• Sannigrahi, J.
• Chaudhuri, B. K.
• Sakata, H.

Titel

Enhancement of the transport and dielectric properties of graphite oxide nanoplatelets-polyvinyl alcohol composite showing low percolation threshold

Ist Teil von

• Polymer composites, 2012-03, Vol.33 (3), p.436-442

Ort / Verlag

Hoboken: Wiley Subscription Services, Inc., A Wiley Company

Erscheinungsjahr

2012

Link zum Volltext

Quelle

Wiley Online Library Journals Frontfile Complete

Beschreibungen/Notizen

• Graphite oxide nanoplatelets (GOnP) were prepared using standard method and used to make GOnP‐polyvinyl alcohol (PVA) composites by using solution cast technique. Significant enhancement of electrical conductivity and dielectric permittivity of the GOnP/PVA composites are observed at low GOnP concentration (fGOnP = fc∼0.41 vol%) which is the percolation threshold value estimated from the concentration dependent transport and dielectric data. Nearly 300 times increase in dielectric permittivity (compared with that of PVA) is observed in the GOnP/PVA composite around fc. We notice interesting metal‐insulator like transition (a sudden increase in resistivity) from the temperature dependent resistivity data in the pure GOnP sample around TMI ∼ 275 K which is shifted to 300 K in the GOnP/PVA composite for fc = 0.41 vol%, indicating drastic change of sp3/sp2 ratio around respective TMI. The present graphite‐based composite material might be processed for different applications. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers