Details

Autor(en) / Beteiligte

• Rolker, Jörn
• Lenormant, Thibaut
• Seiler, Matthias

Titel

A New Chemical System Solution for Acid Gas Removal

Ist Teil von

• Chemie ingenieur technik, 2012-06, Vol.84 (6), p.849-858

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2012

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• An energy‐efficient absorbent formulation for separating acid gases (e.g. CO2, H2S) from gas streams such as natural gas, syngas or flue gas is important for a number of industrial applications. In many cases, a substantial share of their costs is driven by the operational expenditure (OPEX) of the CO2 separation unit. One possible strategy for reducing OPEX is the improvement of the absorbent performance. Although a number of absorbents for the separation of CO2 from gas streams exist, there is still a need to develop CO2 absorbents with an improved absorption performance, less corrosion and foaming, no nitrosamine formation, lower energy requirement and therefore less OPEX. Selected performance results of a new family of amine‐based CO2 absorbents are summarized. High cyclic capacities in the range of 2.9 to 3.2 mol CO2 kg–1 absorbent and low absorption enthalpies of about –30 kJ mol–1 allow for significant savings in the regeneration energy of the absorbent. Calculations with the modified Kremser model indicated a reduction in the specific reboiler heat duty of 45 %. Furthermore, the absorbents developed show much lower corrosion rates than state‐of‐the‐art solutions that are currently employed. The use of new specialty amine systems for separating acid gases from various industrial gas streams such as natural gas, synthesis gas and flue gas is evaluated. The main parameters for the reduction of operational expenditures are discussed and the performance of the new, competitive absorbent solutions is compared to state‐of‐the‐art systems.