Details

Autor(en) / Beteiligte

• Sharp-Bucknall, Lachlan
• Tania
• Dutton, Jason L

Titel

Synthesis and Structural Verification of an ArI(OTf) 2 , NO 2 -Ph-I(OTf) 2

Ist Teil von

• Angewandte Chemie (International ed.), 2022-11, Vol.61 (46), p.e202212380

Ort / Verlag

Germany

Erscheinungsjahr

2022

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• PhI(OTf) and related ArI(OTf) species have been incorrectly invoked as intermediates in oxidation reactions for many years. We recently established that such compounds did not yet exist but remain an attractive target. Here we describe the synthesis, isolation, and structural characterization of NO -PhI(OTf) which is resistant to decomposition and more reactive than PhI(OTf)(OAc), the species previously misidentified as PhI(OTf) .