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Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

Chemical reviews, 2017-07, Vol.117 (13), p.9247-9301

2017

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Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

Accounts of chemical research, 2015-04, Vol.48 (4), p.1040-1052

2015

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Cobalt(III)-Catalyzed C–H Amidation of Arenes using Acetoxycarbamates as Convenient Amino Sources under Mild Conditions

ACS catalysis, 2015-02, Vol.5 (2), p.853-858

2015

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The Use of Ammonia as an Ultimate Amino Source in the Transition Metal-Catalyzed C–H Amination

Accounts of chemical research, 2017-03, Vol.50 (3), p.482-486

2017

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Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source

Accounts of chemical research, 2021-06, Vol.54 (11), p.2683-2700

2021

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A New Combined Source of “CN” from N,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C−H Bonds

Journal of the American Chemical Society, 2010-08, Vol.132 (30), p.10272-10274

2010

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Regioselective Introduction of Heteroatoms at the C‑8 Position of Quinoline N‑Oxides: Remote C–H Activation Using N‑Oxide as a Stepping Stone

Journal of the American Chemical Society, 2014-07, Vol.136 (30), p.10770-10776

2014

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Comparison of the Reactivities and Selectivities of Group 9 [CpMIII] Catalysts in C−H Functionalization Reactions

Chemistry, an Asian journal, 2018-05, Vol.13 (9), p.1089-1102

2018

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Synthesis of Aromatic Nitriles Using Nonmetallic Cyano-Group Sources

Angewandte Chemie (International ed.), 2012-11, Vol.51 (48), p.11948-11959

International ed. in English, 2012

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Recent advances in the transition metal-catalyzed twofold oxidative C-H bond activation strategy for C-C and C-N bond formation

Chemical Society reviews, 2011-01, Vol.40 (10), p.5068-5083

2011

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Rhodium(III)-Catalyzed C–C Bond Formation of Quinoline N‑Oxides at the C‑8 Position under Mild Conditions

Organic letters, 2014-09, Vol.16 (17), p.4598-4601

2014

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Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

Journal of the American Chemical Society, 2011-04, Vol.133 (15), p.5996-6005

2011

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Direct CH Amidation of Benzoic Acids to Introduce meta- and para-Amino Groups by Tandem Decarboxylation

Chemistry : a European journal, 2015-03, Vol.21 (14), p.5364-5368

2015

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Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C–H Activation and Oxygen Atom Transfer

Journal of the American Chemical Society, 2015-04, Vol.137 (15), p.4908-4911

2015

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Copper-Catalyzed Direct C–H Alkylation of Polyfluoroarenes by Using Hydrocarbons as an Alkylating Source

Journal of the American Chemical Society, 2020-04, Vol.142 (16), p.7487-7496

2020

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On the Origin of Rh-Catalyzed Selective Ring-Opening Amidation of Substituted Cyclopropanols to Access β2‑Amino Ketones

Journal of the American Chemical Society, 2022-03, Vol.144 (8), p.3667-3675

2022

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N‑Substituted Hydroxylamines as Synthetically Versatile Amino Sources in the Iridium-Catalyzed Mild C–H Amidation Reaction

Organic letters, 2014-06, Vol.16 (12), p.3328-3331

2014

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[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium‐Catalyzed Process by Tuning the Cp Ligand

Angewandte Chemie International Edition, 2017-02, Vol.56 (9), p.2408-2412

2017

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Iridium-Catalyzed Enantioselective C(sp3)–H Amidation Controlled by Attractive Noncovalent Interactions

Journal of the American Chemical Society, 2019-05, Vol.141 (17), p.7194-7201

2019

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Nitrene-mediated intermolecular N–N coupling for efficient synthesis of hydrazides

Nature chemistry, 2021-04, Vol.13 (4), p.378-385

2021

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Ir(III)-Catalyzed Mild C–H Amidation of Arenes and Alkenes: An Efficient Usage of Acyl Azides as the Nitrogen Source

Journal of the American Chemical Society, 2013-08, Vol.135 (34), p.12861-12868

2013

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Merging NiH Catalysis and Inner-Sphere Metal-Nitrenoid Transfer for Hydroamidation of Alkynes

Journal of the American Chemical Society, 2021-04, Vol.143 (15), p.5867-5877

2021

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Endo-Selective Intramolecular Alkyne Hydroamidation Enabled by NiH Catalysis Incorporating Alkenylnickel Isomerization

Journal of the American Chemical Society, 2022-06, Vol.144 (22), p.10064-10074

2022

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Selective formation of γ-lactams via C-H amidation enabled by tailored iridium catalysts

Science (American Association for the Advancement of Science), 2018-03, Vol.359 (6379), p.1016-1021

2018

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Rhodium-Catalyzed Selective Olefination of Arene Esters via C−H Bond Activation

Organic letters, 2011-05, Vol.13 (9), p.2372-2375

2011

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Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

Cobalt(III)-Catalyzed C–H Amidation of Arenes using Acetoxycarbamates as Convenient Amino Sources under Mild Conditions

The Use of Ammonia as an Ultimate Amino Source in the Transition Metal-Catalyzed C–H Amination

Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source

A New Combined Source of “CN” from N,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C−H Bonds

Regioselective Introduction of Heteroatoms at the C‑8 Position of Quinoline N‑Oxides: Remote C–H Activation Using N‑Oxide as a Stepping Stone

Comparison of the Reactivities and Selectivities of Group 9 [CpMIII] Catalysts in C−H Functionalization Reactions

Synthesis of Aromatic Nitriles Using Nonmetallic Cyano-Group Sources

Recent advances in the transition metal-catalyzed twofold oxidative C-H bond activation strategy for C-C and C-N bond formation

Rhodium(III)-Catalyzed C–C Bond Formation of Quinoline N‑Oxides at the C‑8 Position under Mild Conditions

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

Direct CH Amidation of Benzoic Acids to Introduce meta- and para-Amino Groups by Tandem Decarboxylation

Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C–H Activation and Oxygen Atom Transfer

Copper-Catalyzed Direct C–H Alkylation of Polyfluoroarenes by Using Hydrocarbons as an Alkylating Source

On the Origin of Rh-Catalyzed Selective Ring-Opening Amidation of Substituted Cyclopropanols to Access β2‑Amino Ketones

N‑Substituted Hydroxylamines as Synthetically Versatile Amino Sources in the Iridium-Catalyzed Mild C–H Amidation Reaction

[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium‐Catalyzed Process by Tuning the Cp Ligand

Iridium-Catalyzed Enantioselective C(sp3)–H Amidation Controlled by Attractive Noncovalent Interactions

Nitrene-mediated intermolecular N–N coupling for efficient synthesis of hydrazides

Ir(III)-Catalyzed Mild C–H Amidation of Arenes and Alkenes: An Efficient Usage of Acyl Azides as the Nitrogen Source

Merging NiH Catalysis and Inner-Sphere Metal-Nitrenoid Transfer for Hydroamidation of Alkynes

Endo-Selective Intramolecular Alkyne Hydroamidation Enabled by NiH Catalysis Incorporating Alkenylnickel Isomerization

Selective formation of γ-lactams via C-H amidation enabled by tailored iridium catalysts

Rhodium-Catalyzed Selective Olefination of Arene Esters via C−H Bond Activation

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