Details

Autor(en) / Beteiligte

• Zhang, Wenli
• Liu, Mei
• Liu, Xiucun
• Li, Li
• Yue, Zhongcheng
• Niu, Yunyin

Titel

Synthesis and Structural Characterization of Cation-Induced Complex: [Cd4(SCN)6(BPB)]n With One-Dimensional Double Helix

Ist Teil von

• Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry, 2013-11, Vol.43 (10), p.1381-1384

Ort / Verlag

Taylor & Francis Group

Erscheinungsjahr

2013

Link zum Volltext

Quelle

Taylor & Francis

Beschreibungen/Notizen

• In this study, colorless crystals of the title inorganic-organic hybrid compound were obtained from the solution-phase reaction of cadmium thiocyanate with BPB·Br 2 in MeOH/DMF(BPB·Br 2 = 1,4-bis(pyridinium)butane dibromine). And single-crystal X-ray diffraction analysis revealed that this polymer crystallized in triclinic, space group P-1 with unit cell parameters a = 5.8855(5) Å, b = 9.5996(8) Å, c = 11.4358(9) Å, α = 69.9710(10)°, β = 75.1100 (10)°, γ = 75.8180(10)°. In this compound, each cadmium atom is octahedrally coordinated in 2S4N geometry and doubly bridged infinite one-dimensional double helix cadmium thiocyanate chains act as inorganic moiety with dication discretely surrounded. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.