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Beschreibungen/Notizen
Photoelectron spectroscopy results on single crystals of the superconductors Bi
2Sr
2CaCu
2O
8,Bi
2Sr
2CuO
6, Ba
0.6K
0.4BiO
3 and the semiconductor Ba
0.9K
0.1BiO
3 are reported for the photon energy region around the O
K absorption threshold. The development of the O-
KVV Auger structure has been carefully monitored as a function of photon energy. A non-monotonic behavior displaying a feature at a constant binding energy of about 14 eV was found for Bi
2Sr
2CaCu
2O
8 and Bi
2Sr
2CuO
6 in a narrow photon energy region of 1 eV at the main edge of the O
K absorption spectrum around 530 eV. The corresponding enhancement, connected with the autoionization of O 2
p states, is absent in Ba
1−
x
K
x
BiO
3 in contrast to Bi
2Sr
2CaCu
2O
8 and Bi
2Sr
2CuO
6. The resonant enhancement is more pronounced for Bi
2Sr
2CuO
6 as compared to Bi
2Sr
2CaCu
2O
8, which can be explained by a lower charge carrier concentration in the former case, leading to a more localized nature of intermediate O 2
p states. The model parameters Cu
d–
d and O
p–
p Coulomb interactions and the charge transfer energy
Δ are estimated from the experiments.