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First‐Cycle Oxidative Generation of Lithium Nucleation Sites Stabilizes Lithium‐Metal Electrodes
Ist Teil von
Advanced energy materials, 2021-03, Vol.11 (9), p.n/a
Ort / Verlag
Weinheim: Wiley Subscription Services, Inc
Erscheinungsjahr
2021
Link zum Volltext
Quelle
Wiley Online Library Journals Frontfile Complete
Beschreibungen/Notizen
Although lithium‐metal electrodes have very high capacities, their use as negative electrodes in batteries is associated with stability and safety problems due to formation of dendrites, mossy as well as dead lithium. These problems generally result from the difficulty to ensure that the deposition and stripping of lithium occur homogeneously on the entire electrode surface. As a result, the lithium‐metal electrode is gradually transformed into a thick, porous, and poorly performing electrode. It is therefore essential to develop approaches that facilitate the attainment of homogeneous (i.e., 2D) lithium nucleation and growth. It is also important to note that if the lithium electrode is oxidized on the first half‐cycle, the formed oxidation pits will control the subsequent lithium deposition step. Herein, it is shown that the performance of lithium‐metal electrodes can be straightforwardly improved by introducing a short (e.g., 1 s long) potentiostatic pulse so that the first oxidation step takes place more homogeneously on the lithium surface. This surface activation step gives rise to a large number of preferential lithium nucleation sites facilitating the subsequent attainment of a uniform lithium deposition step. The experimental results indicate that this straightforward pulse approach can significantly increase the lifetime of lithium‐metal electrodes.
A short potentiostatic oxidation/stripping pulse included prior to the first galvanostatic stripping step enables the formation of homogeneously distributed pits which then serve as preferential nucleation sites during the subsequent lithium deposition step. This pulse strategy prevents the deposition from taking place only at the most electrochemically active sites on the lithium‐metal electrodes which improves the stability of the electrodes.