Details

Autor(en) / Beteiligte

• Bange, Christine A
• Ghebreab, Michael B
• Ficks, Arne
• Mucha, Neil T
• Higham, Lee
• Waterman, Rory

Titel

Zirconium-catalyzed intermolecular hydrophosphination using a chiral, air-stable primary phosphineElectronic supplementary information (ESI) available: Experimental and characterization details (pdf) and X-ray crystallographic analysis. CCDC 1421827 (4). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt03544a

Erscheinungsjahr

2016-01

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Catalytic hydrophosphination of alkenes using a chiral, air-stable primary phosphine, ( R )-[2′-methoxy(1,1′-binapthalen)-2-yl]phosphine, ( R )-MeO-MOPH 2 , proceeds under mild conditions with a zirconium catalyst, [κ 5 - N , N , N , N , C -(Me 3 SiNCH 2 CH 2 ) 2 NCH 2 CH 2 NSiMe 2 CH]Zr ( 1 ), to selectively furnish anti-Markovnikov, air-stable secondary phosphines or tertiary phosphines with slight modification of the protocol. An intermediate in the catalysis, [(N 3 N)Zr( R )-MeO-MOPH] ( 4 ), was structurally characterized. Catalytic hydrophosphination of alkenes using a chiral, air-stable primary phosphine, ( R )-MeO-MOPH 2 , proceeds under mild conditions with a zirconium catalyst to selectively furnish anti-Markovnikov, air-stable secondary phosphine or tertiary phosphine prodcuts with slight modification of the protocol.