Angewandte Chemie (International ed.), 2014-06, Vol.53 (26), p.6692-6695
2014
Details
- Autor(en) / Beteiligte
- Titel
- Ligand-Enabled Triple CH Activation Reactions: One-Pot Synthesis of Diverse 4-Aryl-2-quinolinones from Propionamides
- Ist Teil von
- Angewandte Chemie (International ed.), 2014-06, Vol.53 (26), p.6692-6695
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2014
- Link zum Volltext
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Diverse 4‐aryl‐2‐quinolinones are prepared from propionamides in one pot by ligand‐promoted triple sequential CH activation reactions and a stereospecific Heck reaction. In these cascade reactions, three new CC bonds and one CN bond are formed to rapidly build molecular complexity from propionic acid. Building complexity: Diverse 4‐aryl‐2‐quinolinones such as 1 are prepared from propionamides in one pot by pyridine ligand‐promoted triple sequential CH activation reactions and a stereospecific Heck reaction. In these cascade reactions, three new CC bonds and one CN bond are formed to rapidly build molecular complexity from propionic acid.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201403878Titel-ID: cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4114037
- Format
- –
- Schlagworte
- Activation, amidation, Amides - chemistry, arylation, Buildings, C-H activation, Carbon - chemistry, Cascades, Catalysis, Complexity, Construction, dehydrogenation, Hydrogen - chemistry, Ligands, Palladium - chemistry, Propionic acid, Pyridines, quinolinone, Quinolones - chemistry, Solvents - chemistry, Stereoisomerism, Synthesis