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Thin solid films, 2010-09, Vol.518 (22), p.6567-6572
2010

Details

Autor(en) / Beteiligte
Titel
Growth of Cu2ZnSnS4 thin films using sulfurization of stacked metallic films
Ist Teil von
  • Thin solid films, 2010-09, Vol.518 (22), p.6567-6572
Ort / Verlag
Amsterdam: Elsevier
Erscheinungsjahr
2010
Link zum Volltext
Quelle
Elsevier ScienceDirect Journals Complete
Beschreibungen/Notizen
  • We fabricated Cu2ZnSnS4 (CZTS) thin films through sulfurization of stacked metallic films. Three types of Cu-Zn-Sn metallic films, i.e., Cu-rich, Cu-correct and Cu-poor precursor films were sputtered onto Mo-coated glass. The sulfurization of stacked Cu-Zn-Sn alloy films was performed at a relatively high temperature, 570C, with S-powder evaporation. CZTS films from Cu-rich and Cu-correct precursors showed a Cu sub(2-x)S phase on the film surface, while CZTS films from Cu-poor precursors didn't show the Cu sub(2-x)S phase. However, all films didn't exhibit any extra secondary phase and exhibited good crystalline textures even with Cu-ratio differences in metallic precursor films. Fabricated CZTS films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and Raman scattering measurements. SEM cross-section images of CZTS films showed that Cu-poor CZTS films were grown with more smooth film surface compared with other types of CZTS films.

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