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Synthesis and Structural Characterization of Carborane-Containing Neutral, Self-Assembled Pt-Metallacycles
Ist Teil von
Journal of organic chemistry, 2005-12, Vol.70 (25), p.10440-10446
Ort / Verlag
Washington, DC: American Chemical Society
Erscheinungsjahr
2005
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
We have combined carborane chemistry with the newly developed directional bonding strategy to synthesize neutral macrocycles. The m- and p-carborane dicarboxylates were utilized as the donor linkers in conjunction with 1,8-bis[trans-Pt(PEt3)2NO3]anthracene 3, 2,9-bis[trans-Pt(PEt3)2NO3]phenanthrene 5, and cis-Pt(PEt3)2(NO3)2 unit 6. Three new platinum-based macrocycles, 4, 7, and 8, were thus synthesized. 31P{1H} NMR as well as the X-ray characterization of Pt-metallacycles reveal the formation of single highly symmetrical neutral species.