Details

Autor(en) / Beteiligte

• Liu, Jing
• He, Jing
• Wang, Luying
• Li, Rong
• Chen, Pan
• Rao, Xin
• Deng, Lihong
• Rong, Long
• Lei, Jiandu

Titel

NiO-PTA supported on ZIF-8 as a highly effective catalyst for hydrocracking of Jatropha oil

Ist Teil von

• Scientific reports, 2016-03, Vol.6 (1), p.23667-23667, Article 23667

Ort / Verlag

England: Nature Publishing Group

Erscheinungsjahr

2016

Link zum Volltext

Quelle

Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals

Beschreibungen/Notizen

• Nickel oxide (NiO) and phosphotungstic acid (PTA) supported on a ZIF-8 (NiO-PTA/ZIF-8) catalyst was first synthesized and it showed high activity and good selectivity for the hydrocracking of Jatropha oil. The catalyst was characterized by SEM, SEM-EDS, TEM, N2 adsorption, FT-IR, XRD and XPS. Compared with the NiO-PTA/Al2O3 catalyst, the selectivity of C15-C18 hydrocarbon increased over 36%, and catalytic efficiency increased 10 times over the NiO-PTA/ZIF-8 catalyst. The prepared NiO-PTA/ZIF-8 catalyst was stable for a reaction time of 104 h and the kinetic behavior was also analyzed. This catalyst was found to bypass the presulfurization process, showing promise as an alternative to sulfided catalysts for green diesel production.