Angewandte Chemie International Edition, 2002-05, Vol.41 (9), p.1538-1541
2002
Volltextzugriff (PDF)
Details
- Autor(en) / Beteiligte
- Titel
- Characterization and Photochemistry of the Silane-Aluminum Complex AlSiH sub(4) and Its Photoproducts HAlSiH sub(3) and AlSiH sub(3) in a Solid Argon Matrix
- Ist Teil von
- Angewandte Chemie International Edition, 2002-05, Vol.41 (9), p.1538-1541
- Erscheinungsjahr
- 2002
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Matrix isolation experiments have enabled the first characterization of the aluminum-silane complex AlSiH sub(4) ( eta super(2) coordination) which can be converted reversibly by selective photolysis into its tautomer HAlSiH sub(3) [Eq. (1)]. Broadband UV/Vis photolysis causes decomposition of HAlSiH sub(3) to give the aluminum(I) species AlSiH sub(3).
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/1521-3773(20020503)41:9<1538::AID-ANIE1538>3.0.CO;2-KTitel-ID: cdi_proquest_miscellaneous_1701062128
- Format
- –
- Schlagworte
- Aluminum, Argon, Broadband, Decomposition, Photochemistry, Photolysis, Tautomers