Details

Autor(en) / Beteiligte

• Mo, Juntae
• Choi, Wonseok
• Min, Jiae
• Kim, Cheol-Eui
• Eom, Dahan
• Kim, Sung Hong
• Lee, Phil Ho

Titel

ICl-Mediated Intramolecular Twofold Iodoarylation of Diynes and Diynyl Diethers and Amines: Synthesis of Bis(2H‑hydronaphthalene and chromene) and 2H‑Quinoline Bearing an Alkenyl Iodide Moiety

Ist Teil von

• Journal of organic chemistry, 2013-11, Vol.78 (22), p.11382-11388

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2013

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Electrophilic intramolecular twofold iodoarylation was developed from the reaction of diynes and diynyl diethers and amines with iodine monochloride under mild conditions, which produced bis(2H-hydronaphthalene and chromene) and 2H-quinoline bearing an alkenyl iodide moiety in good to excellent yields. These compounds underwent Pd-catalyzed cross-coupling reactions with arylboronic acid and indium tris(arylthiolate) to produce the functionalized styrene derivatives.