Angewandte Chemie (International ed.), 2013-07, Vol.52 (31), p.7985-7989
2013
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Details
- Autor(en) / Beteiligte
- Titel
- Metal-Free Radical Azidoarylation of Alkenes: Rapid Access to Oxindoles by Cascade CN and CC Bond-Forming Reactions
- Ist Teil von
- Angewandte Chemie (International ed.), 2013-07, Vol.52 (31), p.7985-7989
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2013
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- A novel method for the oxidative radical azidation of alkenes relies on an azide in combination with a hypervalent iodine reagent. A cascade of CN and CC bond‐forming reactions yields 2‐oxindoles under metal‐free conditions with high reaction rates at ambient temperature and provides access to complex products (see scheme; TMS=trimethylsilyl).
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201303550Titel-ID: cdi_proquest_miscellaneous_1412558585
- Format
- –
- Schlagworte
- Alkenes, Alkenes - chemistry, Ambient temperature, azidation, Azides - chemistry, Bonding, Carbon - chemistry, Cascades, Free Radicals - chemistry, hypervalent compounds, Indoles - chemistry, Iodine, metal-free reactions, Metals - chemistry, Nitrogen - chemistry, oxindoles, Radicals, Temperature