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Si/C Composites as Negative Electrode for High Energy Lithium Ion Batteries
Ist Teil von
Chinese journal of chemistry, 2017, Vol.35 (1), p.21-29
Ort / Verlag
Weinheim: WILEY-VCH Verlag GmbH & Co. KGaA
Erscheinungsjahr
2017
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Silicon is very promising negative electrode materials for improving the energy density of lithium-ion batteries （LIBs） because of its high specific capacity, moderate potential, environmental friendliness, and low cost. However, the volume variation of Si negative electrodes is huge during lithiation/delithiation processes which results in pulverization, low cycling efficiency, and permanent capacity loss. In order to overcome this problem, tremendous efforts have been attempted. Among them the most successful strategy is to incorporate other components into silicon to form composite, especially the carbon medium. In this mini review, the recent progress on Si/C materials used as negative electrode of LIBs is summarized such as Si/amorphous carbon composite, Si/graphene composites, Si/carbon nanotubes or fibers composites. The fabrication, structure, electrochemical performances of different Si/C composites are discussed. In addition, some future directions are pointed out.