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State-to-state photodissociation of carbonyl sulfide ( ν 2 = 0 , 1 ∣ J l M ) .II. The effect of initial bending on coherence of S ( D 2 1 ) polarization
Ist Teil von
The Journal of chemical physics, 2005-10, Vol.123 (16), p.164313-164313-8
Ort / Verlag
United States: American Institute of Physics
Erscheinungsjahr
2005
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Photodissociation studies using ion imaging are reported, measuring the coherence of the polarization of the
S
(
D
2
1
)
fragment from the photolysis of single-quantum state-selected carbonyl sulfide (OCS) at 223 and
230
nm
. A hexapole state-selector focuses a molecular beam of OCS parent molecules in the ground state
(
ν
2
=
0
∣
J
M
=
10
)
or in the first excited bending state
(
ν
2
=
1
∣
J
l
M
=
111
)
. At
230
nm
photolysis the
Im
[
a
1
(
1
)
(
||
,
⊥
)
]
moment for the fast
S
(
D
2
1
)
channel increases by about 50% when the initial OCS parent state changes from the vibrationless ground state to the first excited bending state. No dependence on the initial bending state is found for photolysis at
223
nm
. We observe separate rings in the slow channel of the velocity distribution of
S
(
D
2
1
)
correlating to single
C
O
(
J
)
rotational states. The additional available energy for photolysis at
223
nm
is found to be channeled mostly into the
C
O
(
J
)
rotational motion. An improved value for the OC-S bond energy
D
0
=
4.292
eV
is reported.