Details

Autor(en) / Beteiligte

• Zhang, Yuan-Zhu
• Zhao, Han-Hua
• Funck, Edward
• Dunbar, Kim R.

Titel

A Single-Chain Magnet Tape Based on Hexacyanomanganate(III)

Ist Teil von

• Angewandte Chemie (International ed.), 2015-05, Vol.54 (19), p.5583-5587

Auflage

International ed. in English

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2015

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The tape‐like chain {[(tptz)MnII(H2O)MnIII(CN)6]2MnII(H2O)2}n⋅4n MeOH⋅2n H2O based on the anisotropic building block hexacyanomanganate(III) exhibits long‐range magnetic ordering below 5.1 K as well as single‐chain magnetic behavior at lower temperatures with an effective energy barrier of 40.5(7) K. A tape‐like compound consisting of quadruply cyanide‐bridged MnIII‐MnII zig‐zag chains based on hexacyanomanganate(III) was synthesized and characterized. Magnetic studies revealed that the compound exhibits long‐range magnetic ordering below 5.1 K as well as single‐chain magnetic behavior at lower temperatures with an effective energy barrier of 40.5(7) K.