Details

Autor(en) / Beteiligte

• Wang, Chang
• Wu, Hong-lin
• Song, Yun-fei
• Yang, Yan-qiang

Titel

Structural deformation of nitro group of nitromethane molecule in liquid phase in an intense femtosecond laser field Project supported by the National Natural Science Foundation of China (Grant Nos. 21673211 and 21203047), the Foundation of Heilongjiang Bayi Agricultural University, China (Grant No. XZR2014-16), and the Science Challenging Program of China (Grant No. JCKY2016212A501)

Ist Teil von

• Chinese physics B, 2017-08, Vol.26 (9)

Ort / Verlag

Chinese Physical Society and IOP Publishing Ltd

Erscheinungsjahr

2017

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane (NM) molecule is detected by time- and frequency-resolved coherent anti-Stokes Raman spectroscopy (CARS) technique with the intense pump laser. Here, we present the mechanism of molecular alignment and deformation. The CARS spectra and its FFT spectra of liquid NM show that the NO2 torsional mode couples with the CN symmetric stretching mode and that the NO2 group undergoes ultrafast structural deformation with a relaxation time of 195 fs. The frequency of the NO2 torsional mode in liquid NM (50.8 ± 0.3 cm−1) at room temperature is found. Our results prove the structural deformation of two groups in liquid NM molecule occur simultaneously in the intense laser field.