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Effects of critical interfacial shear strength between a polymer matrix and carbon nanotubes on the interphase strength and Pukanszky's " B " interphase parameter
In this paper, the "
" interphase parameter in the Pukanszky model and interphase strength for polymer carbon nanotube (CNT) nanocomposites are expressed by the critical interfacial shear strength (
) and interfacial shear strength (
) between a polymer matrix and CNTs. A suggested model and a developed Pukanszky model for tensile strength of nanocomposites are combined to develop the equations for "
" and interphase strength. Many experimental data for various samples confirm the models. The impacts of all parameters on the "
" and interphase strength are explained to approve the developed equations. The contour plots display the same trends for the roles of all parameters in the "
" and interphase strength. Low "
", high "
", thin and large CNTs as well as a dense interphase are ideal to obtain the high levels for "
" and interphase strength. Among the studied parameters, CNT size largely controls the "
" and interphase strength, while the waviness and strength of CNTs play insignificant roles.