Details

Autor(en) / Beteiligte

• Yang, Yulin
• Mu, Zhongcheng
• Xu, Yan
• Chen, Chao
• Wang, Wei
• Yi, Zhuo
• Ye, Ling
• Liu, Yunlin
• Pang, Wenqin

Titel

Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/8

Ist Teil von

• Journal of solid state chemistry, 2004-06, Vol.177 (6), p.2183-2187

Ort / Verlag

San Diego, CA: Elsevier Inc

Erscheinungsjahr

2004

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A new 3-D fluorogallophosphate Ga 7P 8O 32F 4(C 6H 20N 4) 2·3H 3O +·H 2O (denoted JGP-4) with a Ga/P ratio of 7/8 has been synthesized hydrothermally by using triethylenetetramine as the template. It crystallizes in the tetragonal, space group P 4 ̄ 2 1c (no. 114), with a=15.461(2), b=15.461(2), c=9.3233(1) Å, V=2228.67(5) Å 3 and Z=2. This is the first metal phosphate with a M/P ratio of 7/8. The 3-D anionic framework of JGP-4 is built up from the vertex linkage of the 1-D chains and Ga 5P 4 building units, forming a 3-D open-framework with 8-membered and four square 4-membered rings along the c-axis direction.