Tetrahedron, 1990, Vol.46 (7), p.2401-2410
1990
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Details
- Autor(en) / Beteiligte
- Titel
- Facile isomerization of oxiranes to allyl alcohols by mixed metal bases
- Ist Teil von
- Tetrahedron, 1990, Vol.46 (7), p.2401-2410
- Ort / Verlag
- Oxford: Elsevier Ltd
- Erscheinungsjahr
- 1990
- Quelle
- Elsevier Journal Backfiles on ScienceDirect (DFG Nationallizenzen)
- Beschreibungen/Notizen
- The mixture of lithium diisopropylamide and potassium tert-butoxide (“LIDAKOR reagent”) promotes smooth ring opening of oxiranes to afford allyl alcohols with good to excellent yields. Internal epoxyalkanes and large size epoxy-cycloalkanes give preferentially or exclusively trans-alkenols. The regio- and stereochemistry of the ring opening reaction are essentially the consequence of syn-periplanar elimination mechanisms.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0040-4020eISSN: 1464-5416DOI: 10.1016/S0040-4020(01)82021-4Titel-ID: cdi_crossref_primary_10_1016_S0040_4020_01_82021_4
- Format
- –
- Schlagworte
- Chemistry, Exact sciences and technology, Organic chemistry