Details

Autor(en) / Beteiligte

• Ruhland, Klaus
• Herdtweck, Eberhardt

Titel

Favored CH Activation in Comparison to Cyclopropyl CC Activation using a Vaska-Analogous Complex

Ist Teil von

• Advanced synthesis & catalysis, 2005-02, Vol.347 (2-3), p.398-404

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2005

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• Through ligand exchange reaction of Vaska's complex with a chelating diphosphinite ligand containing a cyclopropyl group, CH activation rather than CC activation of the strained cyclopropyl ring is induced. The activation takes place as a second step preceded by the ligand exchange reaction. The fixation of the CH bond near to the metal through the geometry of the diphosphinite ligand is essential for the activation process.