Details

Autor(en) / Beteiligte

• Haag, Mônica Carcuchinski
• dos Santos, João Henrique Zimnoch
• Dupont, Jairton
• Secchi, Argimiro Resende

Titel

Dynamic simulation and experimental evaluation of EPDM terpolymerization with vanadium-based catalyst

Ist Teil von

• Journal of applied polymer science, 1998-11, Vol.70 (6), p.1173-1189

Ort / Verlag

New York: John Wiley & Sons, Inc

Erscheinungsjahr

1998

Link zum Volltext

Quelle

Wiley Online Library All Journals

Beschreibungen/Notizen

• The development of a simplified kinetic model describing some effects observed in catalyzed olefin terpolymerization is presented. Based on the method of moments, the model describes the influence of Al/V ratio and diene concentration on reaction yield and on polymer characteristics such as molecular weight, ethylene incorporation, and polydispersity. In order to verify the model validity, the terpolymerization reactions were performed using VOCl3–Al2Et3Cl3 systems and 2‐ethylidenebi‐cyclo[2.2.1]hept‐5‐ene (ENB) as diene. The results of dynamic simulation fit well the experimental data for Al/V up to 15, but the model fails under high diene concentration, where branching reactions, neglected by reason of simplification, become significant. © 1998 John Wiley & Sons, Inc. J. Appl. Polym. Sci. 70: 1173–1189, 1998