Details

Autor(en) / Beteiligte

• Li, Shaofen,
• Li, Lin,
• Xin, Feng,

Titel

Reaction engineering

Ort / Verlag

Oxford, [England] ; : Butterworth-Heinemann,

Erscheinungsjahr

2017

Beschreibungen/Notizen

• Includes bibliographical references at the end of each chapters and index.
• Front Cover -- Reaction Engineering -- Copyright Page -- Contents -- List of Contributors -- Preface -- 1 Introduction -- 1.1 Chemical Reaction Engineering -- 1.2 Conversion and Yield of Chemical Reactions -- 1.2.1 Extent of Reaction -- 1.2.2 Conversion -- 1.2.3 Yield and Selectivity -- 1.3 Classifications of Chemical Reactors -- 1.4 Operation Modes of Chemical Reactors -- 1.5 Models in Reactor Design -- 1.6 Scale-Up of Industrial Reactors -- Further Reading -- Problems -- 2 Fundamentals of Reaction Kinetics -- 2.1 Reaction Rate -- 2.2 Reaction Rate Equations -- 2.3 Effect of Temperature on Reaction Rate -- 2.4 Multiple Reactions -- 2.4.1 Consumption Rate and Formation Rate -- 2.4.2 Basic Types of Multiple Reactions -- 2.4.3 Reaction Network -- 2.5 Transformation and Integration of Reaction Rate Equations -- 2.5.1 Single Reaction -- 2.5.2 Multiple Reactions -- 2.6 Heterogeneous Catalysis and Adsorption -- 2.6.1 Heterogeneous Catalysis -- 2.6.2 Adsorption and Desorption -- 2.7 Kinetics of Heterogeneous Catalytic Reactions -- 2.7.1 Steady-State Approximation and Rate-Determining Step -- 2.7.2 Rate Equations of Heterogeneous Catalytic Reactions -- 2.8 Determination of Kinetic Parameters -- 2.8.1 Integration Method -- 2.8.2 Differential Method -- 2.9 Procedure for Developing Reaction Rate Equation -- Further Reading -- Problems -- 3 Tank Reactor -- 3.1 Mass Balance for Tank Reactor -- 3.2 Design of Isothermal Batch Tank Reactor (Single Reaction) -- 3.2.1 Calculation of Reaction Time and Reaction Volume -- 3.2.2 Optimal Reaction Time -- 3.3 Design of Isothermal Batch Tank Reactor (Multiple Reactions) -- 3.3.1 Parallel Reactions -- 3.3.2 Consecutive Reactions -- 3.4 Reactor Volume for Continuous Tank Reactor (CSTR) -- 3.5 CSTR in Series and Parallel -- 3.5.1 Overview -- 3.5.2 Calculations for Multiple Reactors in Series.
• 3.5.3 Optimal Reaction Volume Ratio for CSTR in Series -- 3.6 Yield and Selectivity for Multiple Reactions in a Tank Reactor -- 3.6.1 Overall Yield and Overall Selectivity -- 3.6.2 Parallel Reactions -- 3.6.3 Consecutive Reactions -- 3.7 Semibatch Tank Reactor -- 3.8 Nonisothermal Batch Reactor -- 3.9 Steady-State Operation of CSTR -- 3.9.1 Heat Balance for CSTR -- 3.9.2 Steady-States of CSTR -- Summary -- Further Reading -- Problems -- 4 Tubular Reactor -- 4.1 Plug Flow -- 4.2 Design of Isothermal Tubular Reactor -- 4.2.1 Single Reaction -- 4.2.2 Multiple Reactions -- 4.2.3 Pseudo Homogeneous Model -- 4.3 Comparison of Reactor Volumes of Tubular and Tank Reactors -- 4.4 Recycle Reactor -- 4.5 Nonisothermal Tubular Reactor -- 4.5.1 Heat Balance Equation for Tubular Reactor -- 4.5.2 Adiabatic Tubular Reactor -- 4.5.3 Nonadiabatic Nonisothermal Tubular Reactor -- 4.6 Optimal Temperature Sequence for Tubular Reactors -- 4.6.1 Single Reaction -- 4.6.2 Multiple Reactions -- Further Reading -- Problems -- 5 Residence Time Distribution and Flow Models for Reactors -- 5.1 Residence Time Distribution -- 5.1.1 Overview -- 5.1.2 Quantitative Delineation of RTD -- 5.2 Experimental Determination of RTD -- 5.2.1 Pulse Experiments -- 5.2.2 Step Experiments -- 5.3 Statistical Eigenvalues of RTD -- 5.4 RTD of Ideal Reactors -- 5.4.1 Plug-Flow Model -- 5.4.2 Perfectly-Mixed Flow Model -- 5.5 Nonideal Flow Phenomenon -- 5.6 Nonideal Flow Models -- 5.6.1 Segregation Model -- 5.6.2 Tanks-in-Series Model -- 5.6.3 Axial Dispersion Model -- 5.7 Design of Nonideal Reactors -- 5.8 Mixing of Fluids in Flow Reactors -- Further Reading -- Problems -- 6 Chemical Reaction and Transport Phenomena in Heterogeneous System -- 6.1 Steps in Heterogeneous Reactions -- 6.1.1 Macroscopic Structures and Properties of Solid Catalyst Particles -- 6.1.2 Steps in a Catalytic Reaction.
• 6.2 Heat and Mass Transfer Between Bulk Fluid and the Catalyst External Surface -- 6.2.1 Transport Coefficient -- 6.2.2 Concentration and Temperature Difference Between the External Surface of Catalyst and Bulk Fluid -- 6.2.3 Effect of External Diffusion on Heterogeneous Catalytic Reactions -- 6.2.3.1 Single Reaction -- 6.2.3.2 Multiple Reactions -- 6.3 Gas Diffusion in Porous Media -- 6.3.1 Diffusion in Pores -- 6.3.2 Diffusion in Porous Particles -- 6.4 Diffusion and Reaction in Porous Catalysts -- 6.4.1 Reactant Concentration Profile in Porous Catalysts -- 6.4.2 Internal Effectiveness Factor -- 6.4.3 Internal Effectiveness Factor for Non-first Order Reactions -- 6.4.4 Effectiveness Factor Under the Influences of Both Internal and External Diffusions -- 6.5 Effect of Internal Diffusion on Selectivity of Multiple Reactions -- 6.6 Determination of Diffusion Impact on Heterogeneous Reactions -- 6.6.1 Determination of the Effects of External Diffusion -- 6.6.2 Determining the Effects of Internal Diffusion -- 6.7 Effects of Diffusion on Experimental Measurement of Reaction Rate -- Further Reading -- Problems -- 7 Analysis and Design of Heterogeneous Catalytic Reactors -- 7.1 Transport Phenomena Inside Fixed Bed Reactors -- 7.1.1 Fluid Flow Inside a Fixed Bed -- 7.1.2 Mass and Heat Dispersion Along Axial Direction -- 7.1.3 Mass and Heat Transfer in Radial Direction -- 7.2 Mathematical Model for Fixed Bed Reactor -- 7.3 Adiabatic Fixed Bed Reactor -- 7.3.1 Adiabatic Reactors -- 7.3.2 Catalyst Volume for Adiabatic Fixed Bed Reactor -- 7.3.3 Multistage Adiabatic Reactors -- 7.4 Fixed Bed Reactor With Internal Heat Exchanger -- 7.4.1 Overview -- 7.4.2 Analysis for Single Reaction -- 7.4.3 Analysis of Multiple Reaction Systems -- 7.5 Autothermal Fixed Bed Reactors -- 7.5.1 Feed Flow Direction -- 7.5.2 Mathematical Model -- 7.6 Parameter Sensitivity.
• 7.7 Laboratory Catalytic Reactor -- 7.7.1 Basic Requirements -- 7.7.2 Main Types of Experimental Reactor -- 7.7.2.1 Integral Reactor -- 7.7.2.2 Differential Reactor -- 7.7.2.3 External Recycle Reactor -- 7.7.2.4 Internal Recycle Reactor -- Further Reading -- Problems -- 8 Fluidized Bed Reactor -- 8.1 Introduction -- 8.2 Fluidization -- 8.2.1 Fluidization Phenomenon -- 8.2.2 Particle Classifications -- 8.2.3 Fluidization Parameters -- 8.2.3.1 Minimum Fluidization -- 8.2.3.2 Void Fraction at Minimum Fluidization (εmf) -- 8.2.3.3 Particle Terminal Velocity ut -- 8.2.4 Fluidization Regimes -- 8.3 Bubbling Fluidized Bed -- 8.3.1 Bubble Behaviors -- 8.3.1.1 Structure of the Bubble -- 8.3.1.2 Bubble Rising Velocity -- 8.3.1.3 Bubble Size -- 8.3.2 Mathematical Model of Bubbling Fluidized Bed -- 8.3.2.1 Fraction of Bed in the Different Phases -- 8.3.2.2 Distribution of Particles in the Various Phases -- 8.3.2.3 Mass Transfer Between Phases -- 8.3.2.4 Reactor Model Equations based on Material Balance -- 8.4 Turbulent Fluidized Bed -- 8.4.1 Regime Transition -- 8.4.2 Hydrodynamic Characteristics -- 8.5 Circulating Fluidized Bed -- 8.5.1 Introduction -- 8.5.2 Configuration of CFB -- 8.5.3 Mathematical Models of CFB -- 8.5.3.1 Diffusion-Segregation One-Dimensional Model -- 8.5.3.2 Core-Annulus Model -- 8.6 Downer Reactor -- Further Reading -- Problems -- 9 Multiple-Phase Reactors -- 9.1 Gas-Liquid Reactions -- 9.1.1 Pseudo First Order Reaction -- 9.2 Gas-Liquid Reactors -- 9.2.1 Main Types of Reactors -- 9.2.2 Design of Bubble Column Reactor -- 9.2.3 Design of Stirred Tank Reactor -- 9.3 Gas-Liquid-Solid Reactions -- 9.3.1 Introduction -- 9.3.2 Mass Transfer Steps and Rates in Gas-Solid-Liquid Catalytic Reactions -- 9.4 Trickle Bed Reactors -- 9.4.1 Introduction -- 9.4.2 Mathematical Model -- 9.5 Slurry Reactor -- 9.5.1 Types of Reactors.
• 9.5.2 Mass Transfer and Reaction -- 9.5.3 Design of Mechanically Stirred Slurry Tank Reactor -- Further Reading -- Problems -- 10 Fluid-Solid Noncatalytic Reaction Kinetics and Reactors -- 10.1 Fluid-Solid Noncatalytic Reactions and Their Applications -- 10.2 Reaction Rate of Particles in Different Shapes -- 10.3 Theoretical Models of Solid Reactions -- 10.4 Kinetic Analysis of Continuous Model -- 10.5 Kinetic Analysis at Constant Particle Size Using the Shrinking Core Model -- 10.5.1 Overall Macroreaction Rate -- 10.5.2 Macroreaction Rate Under Internal Diffusion Control -- 10.5.3 Macroreaction Rate Under External Diffusion Control -- 10.5.4 Intrinsic Reaction Rate Under Surface Reaction Control -- 10.5.5 Comparison and Differentiation of Rate-Controlling Steps at Constant Particle Size -- 10.6 Kinetic Analysis With Changing Particle Diameter Using the Shrinking Core Model -- 10.6.1 Internal Diffusion Control -- 10.6.2 External Diffusion Control -- 10.6.3 Chemical Reaction Control -- 10.6.4 Overall Reaction Time -- 10.7 Microparticle Model -- 10.8 Chemical Vapor Deposition -- 10.9 Design of Fluid-Solid Noncatalytic Reactor -- 10.9.1 Reactor Types -- 10.9.2 Flowing and Mixing of Reaction Components -- 10.9.3 Reactor Design When Fluid Is a Complete Mixing Flow and Solid Phase Is a Plug Flow -- 10.9.4 Reactor Design When Fluid and Solid Phases Can Be Treated as Complete Mixing Flow -- Further Reading -- Problems -- 11 Fundamentals of Biochemical Reaction Engineering -- 11.1 Introduction -- 11.2 Fundamentals of Biochemical Reaction Kinetics -- 11.2.1 Enzyme-Catalyzed Reactions and Its Kinetics -- 11.2.1.1 Characteristics of Enzymes -- 11.2.1.2 Single-Substrate Enzyme Kinetics (Michaelis-Menten Equation) -- 11.2.1.3 Kinetics of Enzyme-Catalyzed Reactions With Inhibition -- 11.2.1.4 Factors Affecting Reaction Rate of Enzyme-Catalyzed Reactions.
• 11.2.2 Kinetics of Microbial Reactions.
• Description based on online resource; title from PDF title page (ebrary, viewed August 10, 2017).