Details

Autor(en) / Beteiligte

• Moloney, Mark G.,

Titel

Organic reaction mechanisms 2018 : an annual survey covering the literature dated january to december 2018

Ort / Verlag

Hoboken, New Jersey : John Wiley & Sons,

Erscheinungsjahr

[2021]

Link zum Volltext

• Wiley Online Library - AutoHoldings Books

Beschreibungen/Notizen

• Includes bibliographical references and index.
• Cover -- Title Page -- Copyright -- Contributors -- Preface -- Contents -- Chapter 1 Reactions of Aldehydes and Ketones and their Derivatives -- Formation and Reactions of Acetals and Related Species -- Reactions of Glucosides -- Reactions of Ketenes and Related Cumulenes -- Formation and Reactions of Nitrogen Derivatives -- Imines: Synthesis, and General and Iminium Chemistry -- Mannich and Mannich‐type Reactions -- Other 'Name' Reactions of Imines -- Stereoselective Hydrogenation of Imines, and other Reductive Processes -- Cyclizations of Imines -- Other Reactions of Imines -- Oximes, Oxime Ethers, and Oxime Esters -- Hydrazones and Related Species -- C-C Bond Formation and Fission: Aldol and Related Reactions -- The Asymmetric Aldol -- The Mukaiyama Aldol -- The Morita-Baylis-Hilman Reaction, and its Aza‐variants -- Other Aldol and Aldol‐type Reactions -- The Michael Addition -- Other Addition and Related Reactions -- The Wittig and other Olefinations -- Miscellaneous Additions -- Reactions of Enolates and Related Reactions -- Oxidation of Carbonyl Compounds -- Cross‐Dehydrogenative and Related C-C Coupling Processes, and C(spn)-H Activations -- Other Oxidative Processes -- Reduction of Carbonyl Compounds -- Miscellaneous Cyclizations -- Other Reactions -- References -- Chapter 2 Reactions of Carboxylic, Phosphoric and Sulfonic Acids and their Derivatives -- Intermolecular Catalysis and Reactions -- Carboxylic Acids and their Derivatives -- Esters -- Anhydrides -- Amides -- Carbonates and Carbamates -- Sulfonic Acids and their Derivatives -- Sulfonates and Sulfonyl Halides -- Intramolecular Catalysis -- Association‐prefaced Catalysis -- Biologically Significant Reactions -- Carboxylic Acids and their Derivatives -- Amides and Peptides -- Phosphoric Acids and their Derivatives -- Phosphate and Boranephosphonate Diesters -- Phosphate Triesters.
• References -- Chapter 3 Oxidation and Reduction -- Oxidation by Metal Ions and Related Species -- Manganese, Nickel and Cobalt -- Copper, Silver and Gold -- Molybdenum and Vanadium -- Palladium, Iridium, Rhodium and Platinum -- Iron and Ruthenium -- Oxidation by Compounds of Non‐metallic Elements -- Nitrogen and Sulfur -- Halogens -- Ozonolysis and Ozonation -- Peracids and Peroxides -- Photo‐oxygenation and Singlet Oxygen -- Triplet Oxygen and Autoxidation -- Electrochemical Oxidations -- Other Oxidations -- Reduction by Complex Metal Hydrides -- Hydrogenation -- Transfer Hydrogenation -- Other Reductions -- References -- Chapter 4 Carbenes and Nitrenes -- Reviews -- Generation, Structure, and Reactivity -- Carbenes in Coordination Chemistry -- Addition/Fragmentation Reactions Involving Carbenes -- Free Carbenes or Main Group Carbenoid Reactions -- Transition Metal‐assisted Reactions -- Insertion/Abstraction Reactions Involving Carbenes -- Free Carbenes or Carbenoids Reactions -- Transition Metal‐assisted Reactions -- Rearrangements of Carbenes -- Free Carbenes or Carbenoids Reactions -- Transition Metal‐assisted Reactions -- Nucleophilic Carbenes-Carbenes as Organocatalysts -- Transformations Mediated by Breslow‐type Intermediates -- Transformations Non‐mediated by Breslow‐type Intermediates -- Nitrenes -- Free Nitrenes-Generation and Reactivity -- Transition Metal‐assisted Reactions -- Heavy‐atom Carbene Analogues -- References -- Chapter 5a Nucleophilic Aromatic Substitution -- General -- Reactions of Arenediazonium Salts -- The SNAr Mechanism -- Meisenheimer and Related Complexes -- Benzyne and Related Intermediates -- Transition‐Metal‐Catalysed Carbon-Carbon Bond Formation -- References -- Chapter 5b Electrophilic Aromatic Substitution -- General Introduction -- Protonation and Deuteration -- Halogenation -- Fluorination -- Chlorination.
• Bromination -- Iodination -- Nitration -- Hydroxylation -- Amidation -- Borylation and Silylation -- Sulfonation and Sulfanylation -- Selenylation -- Metallation (General) -- C-C Bond Forming Reactions -- Alkylation -- Friedel-Crafts -- Metallation -- Acylation -- References -- Chapter 6 Carbocations -- Introduction -- Alkyl and Cycloalkyl Cations -- Vinyl, Allyl and Propargyl Cations -- Benzyl Cations -- Arenium Ions -- Aromatic Cations -- Oxonium, Sulfonium and Iminium Cations -- New Cations and Synthetic Methods -- Nonclassical carbocations -- Carbocation rearrangements -- Carbocations in biosynthesis -- References -- Chapter 7 Nucleophilic Aliphatic Substitution 2018 -- General -- SN1 Mechanistic Studies -- SN2 Mechanistic Studies -- SN - General Mechanistic Studies -- Nucleophiles -- Fluorination -- Propargyl Substitutions -- Glycosylations -- Reactions -- Boron‐mediated Processes -- Iodine‐mediated Processes -- Metal‐catalysed Processes -- Photomediated Processes -- Nucleophilic Substitutions at Heteroatoms -- Other Reactions -- References -- Chapter 8 Carbanions and Electrophilic Aliphatic Substitution -- Carbanion Reactions -- Enolates and Related Species -- Heteroatom‐stabilized Species -- Organometallic Species -- Organolithium species -- Organomagnesium species -- Organozinc species -- Other organometallic species -- Miscellaneous -- References -- Chapter 9 Elimination Reactions -- Solvolytic Reactions -- Pyrolytic Reactions -- Halogen Derivatives -- Oxygen Derivatives -- Other Pyrolytic Reaction -- Elimination Reactions in Synthesis -- Other Reactions -- References -- Chapter 10 Addition Reactions: Polar Addition -- Reviews -- Electrophilic Additions -- Halogenation and Related Reactions -- Bromine -- Chlorine -- Iodine -- Fluorine -- Additions of ArSX, ArSeX, and Related Reagents -- Additions of Hydrogen Halides and Other Brønsted Acids.
• Additions of Electrophilic Carbon -- Additions of Electrophilic Nitrogen -- Additions of Electrophilic Oxygen -- Additions Initiated by Metals and Metal Ions as Electrophiles -- Boron -- Silicon -- Palladium -- Ruthenium -- Rhodium -- Iridium -- Rhenium -- Copper -- Zinc -- Iron -- Cobalt -- Nickel -- Molybdenum -- Titanium -- Gold -- Silver -- Manganese -- Vanadium -- Gallium -- Indium -- Niobium -- Additions Initiated by Light -- Miscellaneous Electrophilic Additions -- Nucleophilic Additions -- Additions to Multiple Bonds Conjugated with C&amp -- equals -- O -- Nitrogen nucleophiles -- Oxygen nucleophiles -- Sulfur and selenium nucleophiles -- Phosphorus nucleophiles -- Carbon nucleophiles -- Morita-Baylis-Hillman reaction (MBH) -- Additions to Multiple Bonds Activated by Other Electron‐Withdrawing Groups -- Vinyl sulfone, vinyl selenone, and vinyl sulfoxide acceptors -- Acrylonitrile acceptors -- Nitroalkene acceptors -- Other EWG -- Additions of Organometallics to Activated Double Bonds -- Lithium -- Boron -- Silicon -- Magnesium -- Copper -- Palladium -- Ruthenium -- Rhodium -- Silver -- Titanium -- Zinc -- Miscellaneous Nucleophilic Additions -- Acronyms -- Acronyms and Abbreviations -- References -- Chapter 11 Addition Reactions: Cycloaddition -- [2 + 2]‐Cycloaddition -- [2 + 3]‐Cycloaddition -- [2 + 4]‐Cycloaddition -- Miscellaneous Cycloadditions -- References -- Chapter 12 Molecular Rearrangements -- Pericyclic Reactions -- Cycloaddition Reactions -- 1,3 Dipolar Addition -- Electrocyclic -- Ene -- Sigmatropic -- Photooxygenation -- Pyrolysis -- Enzyme -- Miscellaneous -- Boron -- Fluorine -- Metal Catalysed Reactions -- Copper -- Cobalt -- Gold -- Iridium -- Manganese -- Molybdenum -- Nickel -- Osmium -- Platinum -- Palladium -- Ruthenium -- Rhodium -- Rhenium -- Tantalum -- Titanium -- Tungsten -- Thallium -- Zirconium -- Uranium.
• General -- Metathesis Reactions -- Ruthenium -- Molybdenum -- Hafnium -- Tungsten -- Palladium -- Scandium -- Miscellaneous -- Photochemical -- Named Reactions -- Beckmann -- Dimroth -- Deslongchamps -- Friedel-Craft -- Fischer-Tropsch -- Knoevenagel -- Meyer-Schuster -- Mitsunobu -- Nazarov -- Newman-Kwart -- Pinacol -- Pinner/Dimroth -- Pummerer -- Smiles -- Sommelet-Hauser -- Stevens -- Suzuki -- Suzuki-Miyaura -- Wacker -- Wittig -- Photochemical Reactions -- Polymer -- Synthesis -- Sugar -- Miscellaneous reactions -- References -- Chapter 13 Transition‐Metal Catalyzed Reactions -- Reactions not Involving C-H Bond Activation -- Cross‐coupling Reactions with C‐C Bond Formation -- Suzuki-Miyaura‐type, Negishi‐type and Kumada‐type reactions -- Heck‐type and Sonogashira‐type Reactions -- Other C-C Bond Formation Reactions -- Cross‐coupling Reactions with C-X Bond Formation (X: N, B, O) -- Reductive Transformations -- Reactions Involving C-H Bond Activation -- C-H Alkylation Reactions -- C-H Alkenylation, Alkynylation and Allylation Reactions -- C-H Arylation and Hydroarylation Reactions -- Annulation Reactions -- C-X Bond Formation via C-H Activation (X &amp -- equals -- halogen, O, N, B, S, Se, Te) -- C-H Bond Metalation Reactions -- Dehydrogenative‐couplings -- C-H Acylation, Cyanation Reactions and other C-H Functionalizations -- References -- Chapter 14 Radical Reactions -- Generation and Trapping -- Radical Initiation -- Radical Scavengers -- Functional Group Interconversions -- Organoboron Compounds -- Haloalkanes and Haloarenes -- Nitrogen‐containing Functional Groups -- Nitrogen‐centred radicals -- Carbon‐centred radicals and nitrogen radical cations -- Oxygen‐containing Functional Groups -- Alkenes (Forming C-heteroatom Bonds) -- Alkynes (Forming C-heteroatom Bonds) -- Aromatics and Heterocycles (Forming C-heteroatom Bonds) -- Cyclizations.
• 3‐Membered Ring.
• "The way molecules react with each other in organic syntheses is explained by so called "organic reaction mechanisms". Every year a lot of research is done to better understand these mechanisms, in order to find new synthetic routes, and to improve existing syntheses in view of specificity, yield and environmental impact ["green chemistry"]. The understanding of organic reaction mechanisms is the key to every organic synthesis. Organic Reaction Mechanisms 2018, the 54th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2018"--
• Description based on print version record.