Details

Autor(en) / Beteiligte

• Brown, D. J.,

Titel

The Pyrimidines. Supplement II

Ort / Verlag

New York, New York : John Wiley & Sons, Inc,

Erscheinungsjahr

1985

Beschreibungen/Notizen

• Description based upon print version of record.
• Includes bibliographical references and index.
• THE PYRIMIDINES; Contents; Chapter I. Introduction to the Pyrimidines (H1,E1); 4. General Summary of Pyrimidine Chemistry (H 9, E 2); A. Electrophilic Substitution (H 10, E 2); (1) Nitration and Nitrosation (H 10, E 2); (2) Diazo Coupling (H 11); (3) Halogenation (H 11, E 2); (4) Sulfonation (H 11, E 2); ( 5 ) Attack by Chloroform (H 11); (6) Other Electrophilic Attacks (H 11, E 3); C. Nucleophilic Metatheses (H 12, E 3); (1) Replacement of Halogens (H 13, E 3); (a) By Amino or Substituted-Amino Groups (H 13, E 4); (b) By Alkoxy Groups (H 13, E 4); (c) By Hydroxy Groups (H 14, E 5)
• (d) By Alkylthio or Arylthio Groups (H 14, E 5 )(e) By Mercapto Groups (H 14, E 5 ); (f') By Sulfo and Related Groups (H 15, E 6); (g) By Other Groups (E 6); (2) Replacement of Alkoxy, Alkylthio, Alkylsulfinyl, Alkyl-sulfonyl, and Sulfo Groups (H 15, E 6); D. Other Metatheses (H 16, E 7); (1) Hydroxy- to Chloropyrimidines (H 16, E 7); (2) Hydroxy- to Mercaptopyrimidines (H 16, E 8); (3) Mercapto- to Hydroxypyrimidines (H 17, E 8); (4) Mercapto- to Aminopyrimidines (H 17, E 8); (5) Amino- to Hydroxypyrimidines (H 17, E 9); (6) Amino- to Halogenopyrimidines (H 18, E 9)
• (7) Replacement of Trimethylammonio Groups (H 18, E 9)(8) Interchange of Halogeno Substituents (E 10); (9) Hydroxy- to Aminopyrimidines (New); E. Addition Reactions (H 18, E 10); (1) Quaternization; Dimroth Rearrangement (H 18, E 10); (2) Formation of N-Oxides (H 19, E 11); (4) Photohydrates and Photodimers (H 20, E 11); ( 5 ) Addition of Metal Alkyls (H 20, E 12); (6) Addition of Amines (E 13); F. Oxidative Reactions (H 20, E 13); G. Reductive Reactions (H 21, E 13); (1) Nuclear Reduction (H 21, E 13); (2) Reductive Removal of Groups (H 22, E 14)
• (3) Reductive Modification of Groups (H 23, E 14)H . Modification of Substituents (H 24, E 15); (1) Amino Groups (H 24. E 15); (2) Hydroxy and Alkoxy Groups (H 25, E 16); (3) Mercapto Groups (H 25); (4) Alkyl and Related Groups (H 26, E 17); (5) Carboxy and Related Groups (E 17); Chapter II . The Principal Synthetic Method (H 31, E 20); 1 . General Scope (H 31, E 20); 2 . Use of B-Dialdehydes (H 32, E 20); 3 . Use of b.Aldehydo. Ketones (H 34, E 22); 4 . Use of B-Diketones (H 36, E 23); 5 . Use of B-Aldehydo Esters (H 38, E 25); 6 . Use of B-Keto Esters (H 48, E 3 1)
• 7 . Use of B-Diesters (Malonic Esters) (H 51, E 38)8 . Use of B-Aldehydo Nitriles (H 59, E 44); 9 . Use of B-Keto Nitriles (H 65, E 47); 10 . Use of B-Ester Nitriles (H 67, E 48); 11 . Use of B-Dinitriles; Malononitriles (H 72, E 49); Chapter III. Other Methods of Primary Synthesis (H 82. E 53); 1. General Remarks (H 82, E 53); 2. Syntheses Involving Preformed Aminomethylene Groups (H 82, E53); A . Aminomethylene Derivatives with Isocyanates (H 82, E 53); B . Aminomethylene Compounds with Imino Ethers or Imidoyl Chlorides (H 84, E 56); C . Aminomethylene Derivatives with Thioamides (H 85)
• D . Use of Acylated Aminomethylene Derivatives (H 85)
• Drawing from over 2 500 papers, this volume eliminates the need for time-consuming literature surveys for pyrimidines from 1970 through 1983. Chapters summarize the major advances in pyrimidine chemistry, detailing advances in methods of primary synthesis of pyrimidines.
• English
• Description based on online resource; title from PDF title page (ebrary, viewed July 22, 2016).