Details
- Autor(en) / Beteiligte
- Titel
- Recoverable and recyclable catalysts
- Beschreibungen/Notizen
- Description based upon print version of record.
- Includes bibliographical references and index.
- Recoverable and Recyclable Catalysts; Contents; Preface; Acknowledgements; Contributors; 1 The Experimental Assay of Catalyst Recovery: General Concepts; 1.1 Introduction; 1.2 Catalyst Precursor vs Catalyst; 1.3 Catalyst vs Catalyst Resting State; 1.4 Catalyst Inventory: Loss Mechanisms; 1.4.1 Catalyst Decomposition; 1.4.2 Catalyst Leaching; 1.5 Evaluation of Catalyst Recovery; 1.5.1 Product Yield, Conversion, or TON as a Function of Cycle: Poor and Potentially Deceptive Criteria; 1.5.2 Reaction Rate or TOF as a Function of Cycle; 1.5.3 Gravimetric and Other Assays of Recovered Catalyst
- 1.5.4 Special Caveats when 'Residues' are Recycled1.6 Prospective; References; 2 Surface-functionalized Nanoporous Catalysts for Renewable Chemistry; 2.1 Introduction; 2.1.1 Homogeneous Catalysis vs Heterogeneous Catalysis; 2.1.2 Multi-Site vs Single-Site Heterogeneous Catalysis; 2.2 Immobilization Strategies of Heterogeneous Catalysts; 2.2.1 Supported Materials; 2.2.2 Conventional Methods to Functionalize Silica Surfaces; 2.2.3 Alternative Synthesis of Immobilized Complex Catalysts on a Solid Support; 2.2.4 Techniques for Characterization of Heterogeneous Catalysts
- 2.3 Efficient Heterogeneous Catalysts with Enhanced Reactivity and Selectivity with Functionality2.3.1 Surface Interaction of Silica and Immobilized Homogeneous Catalysts; 2.3.2 Introduction of Functionalities and Control of Silica Support Morphology; 2.3.3 Selective Surface Functionalization of Solid Support for Utilization of Nanospace Inside the Porous Structure; 2.3.4 Cooperative Catalysis by Multifunctionalized Heterogeneous Catalyst Systems; 2.3.5 Mesoporous Mixed Metal Oxides for Heterogeneous Catalysts; 2.4 Other Heterogeneous Catalyst Systems on Nonsilica Supports; 2.5 Conclusion
- References3 Insoluble Resin-supported Catalysts; 3.1 Introduction; 3.2 Transition Metal Catalyzed C-C Bond Formation Reactions; 3.2.1 Pd-catalyzed Reactions; 3.2.2 Asymmetric Additions of Organozinc Reagents to Aldehydes; 3.2.3 Rh-catalyzed Asymmetric Intermolecular C-H Activation; 3.2.4 Cu-catalyzed Asymmetric Cyclopropanation; 3.3 Oxidation; 3.3.1 Oxidation of Sulfides to Sulfoxide; 3.3.2 Oxidation of Alkanes, Alkenes and Alcohols; 3.3.3 Epoxidation of Alkenes; 3.3.4 Asymmetric Hydroformylation of Olefins; 3.3.5 Asymmetric Dihydroxylation of Alkenes; 3.4 Reduction
- 3.4.1 Asymmetric Reduction of Ketones3.4.2 Reduction of Carboxamides to Amines; 3.5 Organocatalyzed Reactions; 3.5.1 Asymmetric Aldol Reaction and Aminoxylation; 3.5.2 Asymmetric Tandem Reaction; 3.5.3 Allylation of Aldehydes; 3.5.4 Nucleophilic Substitution Reactions; 3.6 Annulation Reactions; 3.6.1 Cycloaddition; 3.6.2 Intramolecular Hydroamination; 3.7 Miscellaneous; 3.8 Conclusion; References; 4 Catalysts Bound to Soluble Polymers; 4.1 Introduction; 4.2 Soluble Supports - General Considerations; 4.3 Recent Developments of Soluble Polymer-supported Catalysts
- 4.3.1 Attachment of Catalysts to Polymer Supports
- Drawing on international research, Recoverable and Recyclable Catalysts provides the essentials on recoverable and recyclable catalysts. This practical guide explores the general principles of catalyst recovery and recycling, catalysts on insoluble or soluble supports, thermoresponsive catalysts, self-supported catalysts, and more. Each chapter combines basic general principles, practical information on the design and synthesis of catalysts, and strategies for catalyst recovery. The book presents a comparison of several different catalytic systems. This textbook is essential for student
- English