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Kinetics and mechanism of the exo cyclizations of .omega.-formylalkyl radicals

Journal of the American Chemical Society, , Vol.111 (7), p.2674-2681

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Intramolecular radical additions to the azo group. Fast and indiscriminate 5-exo and 6-endo cyclizations

Journal of the American Chemical Society, 1987-08, Vol.109 (17), p.5289-5291

1987

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Mechanistic and kinetic studies of the thiodediazoniation reaction

Journal of the American Chemical Society, 1986-12, Vol.108 (26), p.8227-8229

1986

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Cobalt-Catalyzed Heck-Type Reaction of Alkyl Halides with Styrenes

Journal of the American Chemical Society, 2002-06, Vol.124 (23), p.6514-6515

2002

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Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck Reaction

Journal of the American Chemical Society, 2006-06, Vol.128 (24), p.8068-8077

2006

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Factors Influencing the Autoxidation of Fatty Acids: Effect of Olefin Geometry of the Nonconjugated Diene

Journal of the American Chemical Society, 2004-08, Vol.126 (30), p.9240-9247

2004

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Highly Enantioselective Copper−Bisoxazoline-Catalyzed Allylic Oxidation of Cyclic Olefins with tert-Butyl p-nitroperbenzoate

Journal of the American Chemical Society, 2002-07, Vol.124 (30), p.8806-8807

2002

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Free-radical macrocyclization-transannular cyclization

Journal of the American Chemical Society, 1988-05, Vol.110 (11), p.3554-3560

1988

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Selective 6-endo Cyclization of the Acyl Radicals onto the Nitrogen of Imine and Oxazoline C−N Bonds

Journal of the American Chemical Society, 2006-06, Vol.128 (24), p.7712-7713

2006

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The Azulene-to-Naphthalene Rearrangement Revisited: a DFT Study of Intramolecular and Radical-Promoted Mechanisms

Journal of the American Chemical Society, 2003-05, Vol.125 (18), p.5375-5387

2003

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Evidence for HOOO radicals in the formation of alkyl hydrotrioxides (ROOOH) and hydrogen trioxide (HOOOH) in the ozonation of C-H bonds in hydrocarbons

Journal of the American Chemical Society, 2002-01, Vol.124 (3), p.404-409

2002

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Tandem Polar/Radical Crossover Sequences for the Formation of Fused and Bridged Bicyclic Nitrogen Heterocycles Involving Radical Ionic Chain Reactions, and Alkene Radical Cation Intermediates, Performed under Reducing Conditions: Scope and Limitations

Journal of the American Chemical Society, 2003-07, Vol.125 (26), p.7942-7947

2003

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The .beta.-(phosphonooxy)alkyl radical rearrangement

Journal of the American Chemical Society, 1993-02, Vol.115 (3), p.1165-1166

1993

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Atom-transfer cyclization. A novel isomerization of hex-5-ynyl iodides to (iodomethylene)cyclopentanes

Journal of the American Chemical Society, 1986-04, Vol.108 (9), p.2489-2490

1986

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The chemistry of acyl tellurides: generation and trapping of acyl radicals, including aryltellurium group transfer

Journal of the American Chemical Society, 1992-10, Vol.114 (21), p.8313-8314

1992

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Thermally and photochemically initiated radical chain decomposition of ketone-free methyl(trifluoromethyl)dioxirane

Journal of the American Chemical Society, 1991-09, Vol.113 (20), p.7654-7658

1991

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Oxidative ring expansion of 1-(tert-butylamino)indolines to 1,4-dihydrocinnolines. Novel neophyl rearrangement of hydrazyl radicals

Journal of the American Chemical Society, 1988-10, Vol.110 (21), p.7235-7236

1988

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Hydrogen atom transfer reactions of transition-metal hydrides. Kinetics and mechanism of the hydrogenation of .alpha.-cyclopropylstyrene by metal carbonyl hydrides

Journal of the American Chemical Society, 1990-09, Vol.112 (19), p.6886-6898

1990

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Reversible cyclopropyl ring opening of 1-aroyl-2-phenylcyclopropane radical anions. Determination of the ring opening and closure rates of the intermediate ketyls

Journal of the American Chemical Society, 1992-01, Vol.114 (2), p.713-717

1992

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The mechanism of formation of Grignard reagents: trapping of free alkyl radical intermediates by reaction with tetramethylpiperidine-N-oxyl

Journal of the American Chemical Society, 1989-07, Vol.111 (14), p.5405-5412

1989

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Mechanistic investigation of the reaction between α-sulfonyl carbanions and polyhalogenomethanes. Electron transfer versus polar pathways

Journal of the American Chemical Society, 1992-05, Vol.114 (11), p.4111-4119

1992

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An allyl radical-dioxygen caged pair mechanism for cis-allylperoxyl rearrangements

Journal of the American Chemical Society, 1992-11, Vol.114 (24), p.9689-9691

1992

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Radical intermediates in the epoxidation of alkenes by cytochrome P-450 model systems. The design of a hypersensitive radical probe

Journal of the American Chemical Society, 1988-02, Vol.110 (4), p.1313-1315

1988

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Endocyclic restriction test: evaluation of transition-structure geometry for an aryl bromide-alkyllithium exchange reaction

Journal of the American Chemical Society, 1990-02, Vol.112 (4), p.1629-1630

1990

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Molecular mechanics calculations on template-directed steroid chlorinations: are transition states rigidified by the geometric trajectory requirements for effective energy transfer?

Journal of the American Chemical Society, 1990-09, Vol.112 (19), p.6842-6847

1990

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Kinetics and mechanism of the exo cyclizations of .omega.-formylalkyl radicals

Intramolecular radical additions to the azo group. Fast and indiscriminate 5-exo and 6-endo cyclizations

Mechanistic and kinetic studies of the thiodediazoniation reaction

Cobalt-Catalyzed Heck-Type Reaction of Alkyl Halides with Styrenes

Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck Reaction

Factors Influencing the Autoxidation of Fatty Acids: Effect of Olefin Geometry of the Nonconjugated Diene

Highly Enantioselective Copper−Bisoxazoline-Catalyzed Allylic Oxidation of Cyclic Olefins with tert-Butyl p-nitroperbenzoate

Free-radical macrocyclization-transannular cyclization

Selective 6-endo Cyclization of the Acyl Radicals onto the Nitrogen of Imine and Oxazoline C−N Bonds

The Azulene-to-Naphthalene Rearrangement Revisited: a DFT Study of Intramolecular and Radical-Promoted Mechanisms

Evidence for HOOO radicals in the formation of alkyl hydrotrioxides (ROOOH) and hydrogen trioxide (HOOOH) in the ozonation of C-H bonds in hydrocarbons

Tandem Polar/Radical Crossover Sequences for the Formation of Fused and Bridged Bicyclic Nitrogen Heterocycles Involving Radical Ionic Chain Reactions, and Alkene Radical Cation Intermediates, Performed under Reducing Conditions: Scope and Limitations

The .beta.-(phosphonooxy)alkyl radical rearrangement

Atom-transfer cyclization. A novel isomerization of hex-5-ynyl iodides to (iodomethylene)cyclopentanes

The chemistry of acyl tellurides: generation and trapping of acyl radicals, including aryltellurium group transfer

Thermally and photochemically initiated radical chain decomposition of ketone-free methyl(trifluoromethyl)dioxirane

Oxidative ring expansion of 1-(tert-butylamino)indolines to 1,4-dihydrocinnolines. Novel neophyl rearrangement of hydrazyl radicals

Hydrogen atom transfer reactions of transition-metal hydrides. Kinetics and mechanism of the hydrogenation of .alpha.-cyclopropylstyrene by metal carbonyl hydrides

Reversible cyclopropyl ring opening of 1-aroyl-2-phenylcyclopropane radical anions. Determination of the ring opening and closure rates of the intermediate ketyls

The mechanism of formation of Grignard reagents: trapping of free alkyl radical intermediates by reaction with tetramethylpiperidine-N-oxyl

Mechanistic investigation of the reaction between α-sulfonyl carbanions and polyhalogenomethanes. Electron transfer versus polar pathways

An allyl radical-dioxygen caged pair mechanism for cis-allylperoxyl rearrangements

Radical intermediates in the epoxidation of alkenes by cytochrome P-450 model systems. The design of a hypersensitive radical probe

Endocyclic restriction test: evaluation of transition-structure geometry for an aryl bromide-alkyllithium exchange reaction

Molecular mechanics calculations on template-directed steroid chlorinations: are transition states rigidified by the geometric trajectory requirements for effective energy transfer?

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