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Alkynyl Sulfonium Salts Can Be Employed as Chalcogen‐Bonding Catalysts and Generate Alkynyl Radicals under Blue‐Light Irradiation

Angewandte Chemie International Edition, 2022-04, Vol.61 (16), p.e202116071-n/a

International ed. in English, 2022

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The ortho‐Difluoroalkylation of Aryliodanes with Enol Silyl Ethers: Rearrangement Enabled by a Fluorine Effect

Angewandte Chemie (International ed.), 2019-04, Vol.58 (18), p.5956-5961

International ed. in English, 2019

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Visible‐Light‐Induced Selective Photolysis of Phosphonium Iodide Salts for Monofluoromethylations

Angewandte Chemie International Edition, 2021-11, Vol.60 (48), p.25477-25484

International ed. in English, 2021

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Alkyne Insertion Enabled Vinyl to Acyl 1,5‐Palladium Migration: Rapid Access to Substituted 5‐Membered‐Dihydrobenzofurans and Indolines

Angewandte Chemie International Edition, 2023-04, Vol.62 (18), p.e202300703-n/a

International ed. in English, 2023

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Four Decades of the Chemistry of Planar Hypercoordinate Compounds

Angewandte Chemie (International ed.), 2015-08, Vol.54 (33), p.9468-9501

International ed. in English, 2015

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Enantioselective Synthesis of Axially Chiral Diaryl Ethers via NHC Catalyzed Desymmetrization and Following Resolution

Angewandte Chemie International Edition, 2024-01, Vol.63 (4), p.e202314228-n/a

International ed. in English, 2024

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Selective [5,5]‐Sigmatropic Rearrangement by Assembly of Aryl Sulfoxides with Allyl Nitriles

Angewandte Chemie (International ed.), 2019-04, Vol.58 (16), p.5316-5320

International ed. in English, 2019

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Morita–Baylis–Hillman‐Type [3,3]‐Rearrangement: Switching from Z‐ to E‐Selective α‐Arylation by New Rearrangement Partners

Angewandte Chemie International Edition, 2021-05, Vol.60 (20), p.11414-11422

International ed. in English, 2021

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Z‐Selective α‐Arylation of α,β‐Unsaturated Nitriles via [3,3]‐Sigmatropic Rearrangement

Angewandte Chemie International Edition, 2021-02, Vol.60 (5), p.2339-2345

International ed. in English, 2021

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An Efficient C−Si/C−H Cross‐Coupling Reaction Enabled by a Radical Pathway

Chemistry : a European journal, 2024-03, Vol.30 (18), p.e202303857-n/a

2024

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Mechanism of the Methyltrioxorhenium-Catalyzed Deoxydehydration of Polyols: A New Pathway Revealed

Chemistry : a European journal, 2013-03, Vol.19 (12), p.3827-3832

2013

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Visible‐Light‐Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane‐Oxindole‐Pharmaceutical Hybrids

Angewandte Chemie International Edition, 2023-08, Vol.62 (31), p.e202305088-n/a

International ed. in English, 2023

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An Efficient Direct Arylation Polycondensation via C-S Bond Cleavage

Angewandte Chemie International Edition, 2023-10, Vol.62 (41), p.e202306307-e202306307

International ed. in English, 2023

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A Unified Mechanism to Account for Manganese‐ or Ruthenium‐Catalyzed Nitrile α‐Olefinations by Primary or Secondary Alcohols: A DFT Mechanistic Study

Chemistry : a European journal, 2019-03, Vol.25 (15), p.3939-3949

2019

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Transfer Hydrogenation of Imines with Ammonia-Borane: A Concerted Double-Hydrogen-Transfer Reaction

Angewandte Chemie (International ed.), 2010-03, Vol.49 (11), p.2058-2062

2010

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Selective ortho C−H Cyanoalkylation of (Diacetoxyiodo)arenes through [3,3]‐Sigmatropic Rearrangement

Angewandte Chemie International Edition, 2018-07, Vol.57 (29), p.9078-9082

International ed. in English, 2018

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Catalytic Mechanisms of Direct Pyrrole Synthesis via Dehydrogenative Coupling Mediated by PNP-Ir or PNN-Ru Pincer Complexes: Crucial Role of Proton-Transfer Shuttles in the PNP-Ir System

Journal of the American Chemical Society, 2014-04, Vol.136 (13), p.4974-4991

2014

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Computational Insight into the Mechanism of Selective Imine Formation from Alcohol and Amine Catalyzed by the Ruthenium(II)-PNP Pincer Complex

European journal of inorganic chemistry, 2012-11, Vol.2012 (31), p.5011-5020

2012

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The Mechanism of a Ligand-Promoted C(sp3)–H Activation and Arylation Reaction via Palladium Catalysis: Theoretical Demonstration of a Pd(II)/Pd(IV) Redox Manifold

Journal of the American Chemical Society, 2015-02, Vol.137 (5), p.2006-2014

2015

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N-Heterocyclic Carbene Catalyzed Cyclocondensation of α,β-Unsaturated Carboxylic Acids: Enantioselective Synthesis of Pyrrolidinone and Dihydropyridinone Derivatives

Angewandte Chemie (International ed.), 2014-10, Vol.53 (43), p.11611-11615

2014

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Visible‐Light‐Induced N‐Heterocyclic Carbene‐Catalyzed Single Electron Reduction of Mono‐Fluoroarenes

Angewandte Chemie International Edition, 2023-03, Vol.62 (12), p.e202218468-n/a

International ed. in English, 2023

Volltextzugriff (PDF)

Visible-Light-Triggered Iodinations Facilitated by Weak Electrostatic Interaction of N‑Heterocyclic Carbenes

Organic letters, 2020-09, Vol.22 (18), p.7187-7192

2020

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Dearomative di- and trifunctionalization of aryl sulfoxides via [5,5]-rearrangement

Nature communications, 2022-08, Vol.13 (1), p.4719-4719, Article 4719

2022

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Gold-Catalyzed Atom-Economic Synthesis of Sulfone-Containing Pyrrolo[2,1‑a]isoquinolines from Diynamides: Evidence for Consecutive Sulfonyl Migration

ACS catalysis, 2019-03, Vol.9 (3), p.2610-2617

2019

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Unveiling Secrets of Overcoming the “Heteroatom Problem” in Palladium-Catalyzed Aerobic C–H Functionalization of Heterocycles: A DFT Mechanistic Study

Journal of the American Chemical Society, 2016-03, Vol.138 (8), p.2712-2723

2016

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Alkynyl Sulfonium Salts Can Be Employed as Chalcogen‐Bonding Catalysts and Generate Alkynyl Radicals under Blue‐Light Irradiation

The ortho‐Difluoroalkylation of Aryliodanes with Enol Silyl Ethers: Rearrangement Enabled by a Fluorine Effect

Visible‐Light‐Induced Selective Photolysis of Phosphonium Iodide Salts for Monofluoromethylations

Alkyne Insertion Enabled Vinyl to Acyl 1,5‐Palladium Migration: Rapid Access to Substituted 5‐Membered‐Dihydrobenzofurans and Indolines

Four Decades of the Chemistry of Planar Hypercoordinate Compounds

Enantioselective Synthesis of Axially Chiral Diaryl Ethers via NHC Catalyzed Desymmetrization and Following Resolution

Selective [5,5]‐Sigmatropic Rearrangement by Assembly of Aryl Sulfoxides with Allyl Nitriles

Morita–Baylis–Hillman‐Type [3,3]‐Rearrangement: Switching from Z‐ to E‐Selective α‐Arylation by New Rearrangement Partners

Z‐Selective α‐Arylation of α,β‐Unsaturated Nitriles via [3,3]‐Sigmatropic Rearrangement

An Efficient C−Si/C−H Cross‐Coupling Reaction Enabled by a Radical Pathway

Mechanism of the Methyltrioxorhenium-Catalyzed Deoxydehydration of Polyols: A New Pathway Revealed

Visible‐Light‐Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane‐Oxindole‐Pharmaceutical Hybrids

An Efficient Direct Arylation Polycondensation via C-S Bond Cleavage

A Unified Mechanism to Account for Manganese‐ or Ruthenium‐Catalyzed Nitrile α‐Olefinations by Primary or Secondary Alcohols: A DFT Mechanistic Study

Transfer Hydrogenation of Imines with Ammonia-Borane: A Concerted Double-Hydrogen-Transfer Reaction

Selective ortho C−H Cyanoalkylation of (Diacetoxyiodo)arenes through [3,3]‐Sigmatropic Rearrangement

Catalytic Mechanisms of Direct Pyrrole Synthesis via Dehydrogenative Coupling Mediated by PNP-Ir or PNN-Ru Pincer Complexes: Crucial Role of Proton-Transfer Shuttles in the PNP-Ir System

Computational Insight into the Mechanism of Selective Imine Formation from Alcohol and Amine Catalyzed by the Ruthenium(II)-PNP Pincer Complex

The Mechanism of a Ligand-Promoted C(sp3)–H Activation and Arylation Reaction via Palladium Catalysis: Theoretical Demonstration of a Pd(II)/Pd(IV) Redox Manifold

N-Heterocyclic Carbene Catalyzed Cyclocondensation of α,β-Unsaturated Carboxylic Acids: Enantioselective Synthesis of Pyrrolidinone and Dihydropyridinone Derivatives

Visible‐Light‐Induced N‐Heterocyclic Carbene‐Catalyzed Single Electron Reduction of Mono‐Fluoroarenes

Visible-Light-Triggered Iodinations Facilitated by Weak Electrostatic Interaction of N‑Heterocyclic Carbenes

Dearomative di- and trifunctionalization of aryl sulfoxides via [5,5]-rearrangement

Gold-Catalyzed Atom-Economic Synthesis of Sulfone-Containing Pyrrolo[2,1‑a]isoquinolines from Diynamides: Evidence for Consecutive Sulfonyl Migration

Unveiling Secrets of Overcoming the “Heteroatom Problem” in Palladium-Catalyzed Aerobic C–H Functionalization of Heterocycles: A DFT Mechanistic Study

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