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Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins

Journal of the American Chemical Society, 2017-09, Vol.139 (38), p.13499-13506

2017

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Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

Organometallics, 2011-04, Vol.30 (7), p.1748-1767

2011

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Redox Noninnocent Monoatomic Silicon(0) Complex (“Silylone”): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I)

Journal of the American Chemical Society, 2020-07, Vol.142 (29), p.12608-12612

2020

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Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules

Journal of the American Chemical Society, 2019-08, Vol.141 (32), p.12916-12927

2019

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Silicon-Mediated Selective Homo- and Heterocoupling of Carbon Monoxide

Journal of the American Chemical Society, 2019-01, Vol.141 (1), p.626-634

2019

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From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

Angewandte Chemie (International ed.), 2016-04, Vol.55 (15), p.4781-4785

International ed. in English, 2016

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A New Type of N-Heterocyclic Silylene with Ambivalent Reactivity

Journal of the American Chemical Society, 2006-08, Vol.128 (30), p.9628-9629

2006

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N-Heterocyclic Carbene (NHC)-Stabilized Silanechalcogenones: NHC→Si(R2)E (E=O, S, Se, Te)

Chemistry : a European journal, 2010-01, Vol.16 (4), p.1281-1288

2010

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Distinctly different reactivity of bis(silylenyl)-versus phosphanyl-silylenyl-substituted o-dicarborane towards O2, N2O and CO2

Chemical communications (Cambridge, England), 2021-01, Vol.57 (48), p.5965-5968

2021

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A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity

Angewandte Chemie (International ed.), 2016-11, Vol.55 (48), p.15096-15099

International ed. in English, 2016

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An Isolable Bis(Silanone–Borane) Adduct

Chemistry : a European journal, 2020-04, Vol.26 (20), p.4500-4504

2020

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The Elusive Silyliumylidene [ClSi:]+ and Silathionium [ClSiS]+ Cations Stabilized by Bis(Iminophosphorane) Chelate Ligand

Angewandte Chemie (International ed.), 2012-10, Vol.51 (40), p.10074-10077

International ed. in English, 2012

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An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal‐Free Dehydrogenation of Water

Angewandte Chemie International Edition, 2017-03, Vol.56 (13), p.3699-3702

International ed. in English, 2017

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From an Fe2P3 complex to FeP nanoparticles as efficient electrocatalysts for water-splitting

Chemical science (Cambridge), 2018, Vol.9 (45), p.8590-8597

2018

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Silicon‐Mediated Coupling of Carbon Monoxide, Ammonia, and Primary Amines to Form Acetamides

Angewandte Chemie International Edition, 2019-09, Vol.58 (37), p.12940-12944

International ed. in English, 2019

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Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N‑heterocyclic carbene)borate Ligand

Journal of the American Chemical Society, 2014-08, Vol.136 (32), p.11300-11303

2014

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From Silylone to an Isolable Monomeric Silicon Disulfide Complex

Angewandte Chemie (International ed.), 2015-08, Vol.54 (35), p.10254-10257

International ed. in English, 2015

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Chelate Silylene–Silyl Ligand Can Boost Rhodium‐Catalyzed C−H Bond Functionalization Reactions

Chemistry : a European journal, 2018-10, Vol.24 (55), p.14608-14612

2018

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From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature

Nature chemistry, 2010-07, Vol.2 (7), p.577

2010

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Heavier congeners of CO and CO2 as ligands: from zero-valent germanium ('germylone') to isolable monomeric GeX and GeX2 complexes (X = S, Se, Te)

Chemical science (Cambridge), 2016-01, Vol.7 (8), p.5462-5469

2016

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Synthesis, Structure, and Reactivity of a Pyridine-Stabilized Germanone

Chemistry : a European journal, 2011-04, Vol.17 (17), p.4890-4895

2011

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Activation of Ammonia by a SiO Double Bond and Formation of a Unique Pair of Sila-Hemiaminal and Silanoic Amide Tautomers

Journal of the American Chemical Society, 2010-05, Vol.132 (20), p.6912-6913

2010

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Dioxygenase-Like Reactivity of an Isolable Superoxo-Nickel(II) Complex

Chemistry : a European journal, 2010-08, Vol.16 (31), p.9669-9675

2010

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Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon-Mediated, Regio- and Stereoselective CH Activation

Chemistry : a European journal, 2009-05, Vol.15 (22), p.5545-5551

2009

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A New Domain of Reactivity for High‐Valent Dinuclear [M(μ‐O)2M′] Complexes in Oxidation Reactions

Angewandte Chemie (International ed.), 2017-01, Vol.56 (1), p.297-301

International ed. in English, 2017

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Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

Redox Noninnocent Monoatomic Silicon(0) Complex (“Silylone”): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I)

Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules

Silicon-Mediated Selective Homo- and Heterocoupling of Carbon Monoxide

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

A New Type of N-Heterocyclic Silylene with Ambivalent Reactivity

N-Heterocyclic Carbene (NHC)-Stabilized Silanechalcogenones: NHC→Si(R2)E (E=O, S, Se, Te)

Distinctly different reactivity of bis(silylenyl)-versus phosphanyl-silylenyl-substituted o-dicarborane towards O2, N2O and CO2

A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity

An Isolable Bis(Silanone–Borane) Adduct

The Elusive Silyliumylidene [ClSi:]+ and Silathionium [ClSiS]+ Cations Stabilized by Bis(Iminophosphorane) Chelate Ligand

An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal‐Free Dehydrogenation of Water

From an Fe2P3 complex to FeP nanoparticles as efficient electrocatalysts for water-splitting

Silicon‐Mediated Coupling of Carbon Monoxide, Ammonia, and Primary Amines to Form Acetamides

Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N‑heterocyclic carbene)borate Ligand

From Silylone to an Isolable Monomeric Silicon Disulfide Complex

Chelate Silylene–Silyl Ligand Can Boost Rhodium‐Catalyzed C−H Bond Functionalization Reactions

From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature

Heavier congeners of CO and CO2 as ligands: from zero-valent germanium ('germylone') to isolable monomeric GeX and GeX2 complexes (X = S, Se, Te)

Synthesis, Structure, and Reactivity of a Pyridine-Stabilized Germanone

Activation of Ammonia by a SiO Double Bond and Formation of a Unique Pair of Sila-Hemiaminal and Silanoic Amide Tautomers

Dioxygenase-Like Reactivity of an Isolable Superoxo-Nickel(II) Complex

Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon-Mediated, Regio- and Stereoselective CH Activation

A New Domain of Reactivity for High‐Valent Dinuclear [M(μ‐O)2M′] Complexes in Oxidation Reactions

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