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Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

Chemical reviews, 2015-01, Vol.115 (2), p.731-764

2015

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Trifluoromethanesulfonic Anhydride as a Low‐Cost and Versatile Trifluoromethylation Reagent

Angewandte Chemie International Edition, 2018-06, Vol.57 (23), p.6926-6929

International ed. in English, 2018

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Hydrotrifluoromethylthiolation of Unactivated Alkenes and Alkynes with Trifluoromethanesulfonic Anhydride through Deoxygenative Reduction and Photoredox Radical Processes

Angewandte Chemie International Edition, 2019-12, Vol.58 (51), p.18508-18512

International ed. in English, 2019

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Electrochemical Trifluoromethoxylation of (Hetero)aromatics with a Trifluoromethyl Source and Oxygen

Angewandte Chemie International Edition, 2022-01, Vol.61 (3), p.e202114048-n/a

International ed. in English, 2022

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Chemoselective Hydro(Chloro)pentafluorosulfanylation of Diazo Compounds with Pentafluorosulfanyl Chloride

Angewandte Chemie International Edition, 2021-07, Vol.60 (28), p.15271-15275

International ed. in English, 2021

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Transition-Metal-Free Decarboxylation of 3,3,3-Trifluoro-2,2-dimethylpropanoic Acid for the Preparation of C(CF3)Me2‑Containing Heteroarenes

Organic letters, 2018-09, Vol.20 (17), p.5497-5501

2018

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Visible-Light-Induced Hydrodifluoromethylation of Alkenes with a Bromodifluoromethylphosphonium Bromide

Angewandte Chemie (International ed.), 2016-01, Vol.55 (4), p.1479-1483

International ed. in English, 2016

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Argentination of Fluoroform: Preparation of a Stable AgCF3 Solution with Diverse Reactivities

Angewandte Chemie International Edition, 2019-07, Vol.58 (30), p.10320-10324

International ed. in English, 2019

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Visible-Light Photoredox Decarboxylation of Perfluoroarene Iodine(III) Trifluoroacetates for C–H Trifluoromethylation of (Hetero)arenes

ACS catalysis, 2018-04, Vol.8 (4), p.2839-2843

2018

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Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide

Angewandte Chemie (International ed.), 2015-01, Vol.54 (3), p.897-900

International ed. in English, 2015

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Nucleophilic and Radical Heptafluoroisopropoxylation with Redox‐Active Reagents

Angewandte Chemie International Edition, 2021-10, Vol.60 (42), p.22915-22924

International ed. in English, 2021

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Direct and Regioselective C–H Oxidative Difluoromethylation of Heteroarenes

Journal of the American Chemical Society, 2018-09, Vol.140 (37), p.11613-11617

2018

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Silver-Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers

Angewandte Chemie (International ed.), 2015-09, Vol.54 (40), p.11839-11842

International ed. in English, 2015

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Copper-catalyzed direct trifluoromethylthiolation of benzylic C-H bonds via nondirected oxidative C(sp3)-H activation

Organic letters, 2014-06, Vol.16 (12), p.3372-3375

2014

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Photoredox/Copper‐Catalyzed Trifluoromethylamino‐Cyanation of 1,3‐Enynes

European journal of organic chemistry, 2023-01, Vol.26 (1), p.n/a

2023

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Tunable and Practical Synthesis of Thiosulfonates and Disulfides from Sulfonyl Chlorides in the Presence of Tetrabutylammonium Iodide

Advanced synthesis & catalysis, 2016-11, Vol.358 (21), p.3477-3481

2016

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Chemo‑, Regio‑, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet–Triplet Energy Transfer (TTET) Processes

Journal of organic chemistry, 2014-11, Vol.79 (21), p.10434-10446

2014

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Photoredox Catalysis Mediated Application of Methyl Fluorosulfonyldifluoroacetate as the CF2CO2R Radical Source

Organic letters, 2016-10, Vol.18 (19), p.5130-5133

2016

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Nickel‐Mediated Trifluoromethylation of Phenol Derivatives by Aryl C−O Bond Activation

Angewandte Chemie (International ed.), 2020-09, Vol.59 (37), p.16076-16082

International ed. in English, 2020

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Photoredox-Catalyzed Addition of Dibromofluoromethane to Alkenes: Direct Synthesis of 1‑Bromo-1-fluoroalkanes

Organic letters, 2021-03, Vol.23 (6), p.2364-2369

2021

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Photoredox catalyzed C-H trifluoroethylamination of heteroarenes

Chemical communications (Cambridge, England), 2022-01, Vol.58 (9), p.1346-1349

2022

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Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes

Advanced synthesis & catalysis, 2015-06, Vol.357 (9), p.2039-2044

2015

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Deoxygenative 1,1‐Bis‐trifluoromethylthiolation of Aromatic Aldehydes to Access Bis(trifluoromethylthio)methylarenes

Advanced synthesis & catalysis, 2020-11, Vol.362 (22), p.5031-5035

2020

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Transition metal free decarboxylative fluoroalkylation of N-acrylamides with 3,3,3-trifluoro-2,2-dimethylpropanoic acid (TFDMPA)

Organic & biomolecular chemistry, 2018-11, Vol.16 (44), p.8472-8476

2018

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Copper-catalyzed chemoselective C-H functionalization of quinoxalin-2(1)-ones with hexafluoroisopropanol

Chemical communications (Cambridge, England), 2020-10, Vol.56 (84), p.1285-1288

2020

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Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

Trifluoromethanesulfonic Anhydride as a Low‐Cost and Versatile Trifluoromethylation Reagent

Hydrotrifluoromethylthiolation of Unactivated Alkenes and Alkynes with Trifluoromethanesulfonic Anhydride through Deoxygenative Reduction and Photoredox Radical Processes

Electrochemical Trifluoromethoxylation of (Hetero)aromatics with a Trifluoromethyl Source and Oxygen

Chemoselective Hydro(Chloro)pentafluorosulfanylation of Diazo Compounds with Pentafluorosulfanyl Chloride

Transition-Metal-Free Decarboxylation of 3,3,3-Trifluoro-2,2-dimethylpropanoic Acid for the Preparation of C(CF3)Me2‑Containing Heteroarenes

Visible-Light-Induced Hydrodifluoromethylation of Alkenes with a Bromodifluoromethylphosphonium Bromide

Argentination of Fluoroform: Preparation of a Stable AgCF3 Solution with Diverse Reactivities

Visible-Light Photoredox Decarboxylation of Perfluoroarene Iodine(III) Trifluoroacetates for C–H Trifluoromethylation of (Hetero)arenes

Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide

Nucleophilic and Radical Heptafluoroisopropoxylation with Redox‐Active Reagents

Direct and Regioselective C–H Oxidative Difluoromethylation of Heteroarenes

Silver-Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers

Copper-catalyzed direct trifluoromethylthiolation of benzylic C-H bonds via nondirected oxidative C(sp3)-H activation

Photoredox/Copper‐Catalyzed Trifluoromethylamino‐Cyanation of 1,3‐Enynes

Tunable and Practical Synthesis of Thiosulfonates and Disulfides from Sulfonyl Chlorides in the Presence of Tetrabutylammonium Iodide

Chemo‑, Regio‑, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet–Triplet Energy Transfer (TTET) Processes

Photoredox Catalysis Mediated Application of Methyl Fluorosulfonyldifluoroacetate as the CF2CO2R Radical Source

Nickel‐Mediated Trifluoromethylation of Phenol Derivatives by Aryl C−O Bond Activation

Photoredox-Catalyzed Addition of Dibromofluoromethane to Alkenes: Direct Synthesis of 1‑Bromo-1-fluoroalkanes

Photoredox catalyzed C-H trifluoroethylamination of heteroarenes

Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes

Deoxygenative 1,1‐Bis‐trifluoromethylthiolation of Aromatic Aldehydes to Access Bis(trifluoromethylthio)methylarenes

Transition metal free decarboxylative fluoroalkylation of N-acrylamides with 3,3,3-trifluoro-2,2-dimethylpropanoic acid (TFDMPA)

Copper-catalyzed chemoselective C-H functionalization of quinoxalin-2(1)-ones with hexafluoroisopropanol

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