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Effects of Conformation on the Stereochemistry of Solvent Attack on Benzylic β-Hydroxycarbocations: Mechanisms of Epoxide Hydrolysis Reactions

Journal of organic chemistry, 2006-09, Vol.71 (19), p.7252-7260

2006

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Transition-State Effects in Acid-Catalyzed Aryl Epoxide Hydrolyses

Journal of organic chemistry, 2004-08, Vol.69 (16), p.5204-5211

2004

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Transition State Effects in the Acid-Catalyzed Hydrolysis of 5-Methoxyacenaphthylene 1,2-Oxide: Implications for the Mechanism of Acid-Catalyzed Hydrolysis of Cyclopenta[cd]pyrene 3,4-Oxide

Chemical research in toxicology, 2006-02, Vol.19 (2), p.217-222

2006

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Synthesis and Hydrolysis of a cis-Chlorohydrin Derived from a Benzo[a]pyrene 7,8-Diol 9,10-Epoxide

Journal of organic chemistry, 2004-11, Vol.69 (23), p.8012-8017

2004

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Chloride Ion Catalyzed Conformational Inversion of Carbocation Intermediates in the Hydrolysis of a Benzo[a]pyrene 7,8-Diol 9,10-Epoxide

Journal of the American Chemical Society, 2002-12, Vol.124 (48), p.14382-14387

2002

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Mechanisms of hydrolysis and rearrangements of epoxides

Advances in Physical Organic Chemistry, 2005, Vol.40, p.247-298

2005

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Role of Hydrophobic Interactions in Binding S-(N-Aryl/Alkyl-N-hydroxy- carbamoyl)glutathiones to the Active Site of the Antitumor Target Enzyme Glyoxalase I

Journal of medicinal chemistry, 2000-10, Vol.43 (21), p.3981-3986

2000

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Spontaneous Hydrolysis Reactions of cis- and trans-β-Methyl-4-methoxystyrene Oxides (Anethole Oxides): Buildup of trans-Anethole Oxide as an Intermediate in the Spontaneous Reaction of cis-Anethole Oxide

Journal of organic chemistry, 2000-03, Vol.65 (5), p.1407-1413

2000

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New Insights on the Mechanisms of the pH-Independent Reactions of Benzo[a]pyrene 7,8-Diol 9,10-Epoxides

Journal of the American Chemical Society, 2001-07, Vol.123 (28), p.6785-6791

2001

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Acid-Catalyzed Phenylcyclohexene Oxide Hydrolysis: Role of Para-Phenyl Substituent on Syn:Anti Hydration Ratio

Journal of organic chemistry, 1999-08, Vol.64 (17), p.6227-6234

1999

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Change of Rate Limiting Step in General Acid-Catalyzed Benzo[a]pyrene Diol Epoxide Hydrolysis

Journal of the American Chemical Society, 1998-05, Vol.120 (18), p.4327-4333

1998

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Stereochemistry of the Spontaneous, Acid-Catalyzed and Base-Catalyzed Hydrolyses of Styrene Oxide

Journal of organic chemistry, 1994-04, Vol.59 (7), p.1638-1641

1994

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Halide Effects in the Hydrolysis Reactions of (±)-7β,8α-Dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo- [a]pyrene

Chemical research in toxicology, 1998-06, Vol.11 (6), p.630-638

1998

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Kinetic deuterium isotope effects on the reactions of 4-methoxystyrene oxide in water solution

ARKIVOC, 2005-08, Vol.2006 (3), p.48-58

2005

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Acid-catalyzed hydrolysis of cis- and trans-anethole oxides: discrete carbocation intermediates and syn/anti hydration ratios

Journal of organic chemistry, 1993-05, Vol.58 (10), p.2663-2669

1993

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Effects of para-substituents on the mechanisms of solvolysis of styrene oxides

Journal of organic chemistry, 1993-02, Vol.58 (4), p.924-932

1993

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Structural effects on charge delocalization in benzylic anions

Journal of organic chemistry, 1993-06, Vol.58 (13), p.3490-3495

1993

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Structural effects on the energetics of s-cis and s-trans dienolates

Journal of organic chemistry, 1993-12, Vol.58 (25), p.7100-7105

1993

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Structural effects on the rates of formation and the stability of enols of cyclic benzyl ketones

Journal of the American Chemical Society, 1991-02, Vol.113 (4), p.1344-1349

1991

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Solvolysis of K-region arene oxides: substituent effects on reactions of benz[a]anthracene 5,6-oxide

Journal of the American Chemical Society, 1991-05, Vol.113 (10), p.3910-3919

1991

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Solvolysis of (4-Nitrophenoxy)ethylene Oxides

Journal of organic chemistry, 1994-03, Vol.59 (5), p.977-983

1994

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pH dependence of the mechanism of hydrolysis of benzo[a]pyrene-cis-7,8-diol 9,10-epoxide catalyzed by DNA, poly(G), and poly(A)

Journal of the American Chemical Society, 1987-04, Vol.109 (7), p.2108-2111

1987

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The acidity of benzyl ketones in aqueous solution. Evaluation of the intrinsic acidifying effect of a phenyl group

Journal of the American Chemical Society, 1988-03, Vol.110 (6), p.1981-1982

1988

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Evidence for reversible formation of an intermediate in the "spontaneous" hydrolysis reaction of p-methoxystyrene oxide

Journal of the American Chemical Society, 1986-08, Vol.108 (16), p.5039-5040

1986

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Solvolysis of syn- and anti-9-oxabicyclo[6.1.0]non-2-yl p-bromobenzenesulfonates

Journal of the American Chemical Society, 1970-12, Vol.92 (26), p.7619-7620

Whalen, Dale

1970

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Effects of Conformation on the Stereochemistry of Solvent Attack on Benzylic β-Hydroxycarbocations: Mechanisms of Epoxide Hydrolysis Reactions

Transition-State Effects in Acid-Catalyzed Aryl Epoxide Hydrolyses

Transition State Effects in the Acid-Catalyzed Hydrolysis of 5-Methoxyacenaphthylene 1,2-Oxide: Implications for the Mechanism of Acid-Catalyzed Hydrolysis of Cyclopenta[cd]pyrene 3,4-Oxide

Synthesis and Hydrolysis of a cis-Chlorohydrin Derived from a Benzo[a]pyrene 7,8-Diol 9,10-Epoxide

Chloride Ion Catalyzed Conformational Inversion of Carbocation Intermediates in the Hydrolysis of a Benzo[a]pyrene 7,8-Diol 9,10-Epoxide

Mechanisms of hydrolysis and rearrangements of epoxides

Role of Hydrophobic Interactions in Binding S-(N-Aryl/Alkyl-N-hydroxy- carbamoyl)glutathiones to the Active Site of the Antitumor Target Enzyme Glyoxalase I

Spontaneous Hydrolysis Reactions of cis- and trans-β-Methyl-4-methoxystyrene Oxides (Anethole Oxides): Buildup of trans-Anethole Oxide as an Intermediate in the Spontaneous Reaction of cis-Anethole Oxide

New Insights on the Mechanisms of the pH-Independent Reactions of Benzo[a]pyrene 7,8-Diol 9,10-Epoxides

Acid-Catalyzed Phenylcyclohexene Oxide Hydrolysis: Role of Para-Phenyl Substituent on Syn:Anti Hydration Ratio

Change of Rate Limiting Step in General Acid-Catalyzed Benzo[a]pyrene Diol Epoxide Hydrolysis

Stereochemistry of the Spontaneous, Acid-Catalyzed and Base-Catalyzed Hydrolyses of Styrene Oxide

Halide Effects in the Hydrolysis Reactions of (±)-7β,8α-Dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo- [a]pyrene

Kinetic deuterium isotope effects on the reactions of 4-methoxystyrene oxide in water solution

Acid-catalyzed hydrolysis of cis- and trans-anethole oxides: discrete carbocation intermediates and syn/anti hydration ratios

Effects of para-substituents on the mechanisms of solvolysis of styrene oxides

Structural effects on charge delocalization in benzylic anions

Structural effects on the energetics of s-cis and s-trans dienolates

Structural effects on the rates of formation and the stability of enols of cyclic benzyl ketones

Solvolysis of K-region arene oxides: substituent effects on reactions of benz[a]anthracene 5,6-oxide

Solvolysis of (4-Nitrophenoxy)ethylene Oxides

pH dependence of the mechanism of hydrolysis of benzo[a]pyrene-cis-7,8-diol 9,10-epoxide catalyzed by DNA, poly(G), and poly(A)

The acidity of benzyl ketones in aqueous solution. Evaluation of the intrinsic acidifying effect of a phenyl group

Evidence for reversible formation of an intermediate in the "spontaneous" hydrolysis reaction of p-methoxystyrene oxide

Solvolysis of syn- and anti-9-oxabicyclo[6.1.0]non-2-yl p-bromobenzenesulfonates

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