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Amine–Borane Dehydropolymerization: Challenges and Opportunities

Chemistry : a European journal, 2019-01, Vol.25 (6), p.1379-1390

2019

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Solvent-free anhydrous Li + , Na + and K + salts of [B(3,5-(CF 3 ) 2 C 6 H 3 ) 4 ] - , [BAr F 4 ] - . Improved synthesis and solid-state structures

Dalton transactions : an international journal of inorganic chemistry, 2019-03, Vol.48 (11), p.3551-3554

2019

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Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species

Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences, 2015-03, Vol.373 (2037), p.20140187

2015

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B----H Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine-Boranes

Angewandte Chemie (International ed.), 2010-01, Vol.49 (3), p.581-584

2010

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Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)]+ Catalyst

Journal of the American Chemical Society, 2014-06, Vol.136 (25), p.9078-9093

2014

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The Simplest Amino-borane H2B=NH2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine-Borane Dehydropolymerization

Angewandte Chemie International Edition, 2016-06, Vol.55 (23), p.6651-6656

International ed. in English, 2016

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Intermolecular Hydroacylation: High Activity Rhodium Catalysts Containing Small-Bite-Angle Diphosphine Ligands

Journal of the American Chemical Society, 2012-03, Vol.134 (10), p.4885-4897

2012

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Bis(σ-amine-borane) Complexes: An Unusual Binding Mode at a Transition-Metal Center

Angewandte Chemie (International ed.), 2009-01, Vol.48 (37), p.6875-6878

2009

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Exploiting Carbonyl Groups to Control Intermolecular Rhodium-Catalyzed Alkene and Alkyne Hydroacylation

Journal of the American Chemical Society, 2017-07, Vol.139 (29), p.10142-10149

2017

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Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes

Angewandte Chemie International Edition, 2015-07, Vol.54 (29), p.8520-8524

International ed. in English, 2015

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Polyphosphinoborane Block Copolymer Synthesis Using Catalytic Reversible Chain‐Transfer Dehydropolymerization

Angewandte Chemie International Edition, 2023-01, Vol.62 (3), p.e202216106-n/a

International ed. in English, 2023

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A Rhodium-Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques

Angewandte Chemie International Edition, 2016-03, Vol.55 (11), p.3677-3681

International ed. in English, 2016

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Traceless Chelation-Controlled Rhodium-Catalyzed Intermolecular Alkene and Alkyne Hydroacylation

Chemistry : a European journal, 2013-02, Vol.19 (9), p.3125-3130

2013

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Solid–State Molecular Organometallic Catalysis in Gas/Solid Flow (Flow-SMOM) as Demonstrated by Efficient Room Temperature and Pressure 1‑Butene Isomerization

ACS catalysis, 2020-02, Vol.10 (3), p.1984-1992

2020

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[Ir(PCy3)2(H)2(H2BNMe2)]+ as a Latent Source of Aminoborane: Probing the Role of Metal in the Dehydrocoupling of H3B⋅NMe2H and Retrodimerisation of [H2BNMe2]2

Chemistry : a European journal, 2011-03, Vol.17 (10), p.3011-3020

2011

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Dehydrocoupling of phosphine-boranes using the [RhCpMe(PMe 3 )(CH 2 Cl 2 )][BAr F 4 ] precatalyst: stoichiometric and catalytic studies

Chemical science (Cambridge), 2016-03, Vol.7 (3), p.2414-2426

2016

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Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

Chemical communications (Cambridge, England), 2011-01, Vol.47 (13), p.3763-3765

2011

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Model - state-of-the-art modelling and computational analysis of reactive sites: general discussion

Faraday discussions, 2023-08, Vol.244, p.336-355

2023

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Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes

Dalton transactions : an international journal of inorganic chemistry, 2016-04, Vol.45 (14), p.6183-6195

2016

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Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism

Angewandte Chemie International Edition, 2022-01, Vol.61 (5), p.e202111462-n/a

International ed. in English, 2022

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Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch

Angewandte Chemie International Edition, 2011-05, Vol.50 (22), p.5134-5138

International ed. in English, 2011

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Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [CpIr{κ2‑N,O}][BArF 4]

Organometallics, 2015-08, Vol.34 (15), p.3849-3856

2015

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Intermolecular Alkene and Alkyne Hydroacylation with β-S-Substituted Aldehydes: Mechanistic Insight into the Role of a Hemilabile P-O-P Ligand

Chemistry : a European journal, 2008-09, Vol.14 (27), p.8383-8397

2008

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Intramolecular C-C agostic complexes: C-C sigma interactions by another name

Chemical Society reviews, 2014-01, Vol.43 (1), p.242-259

2014

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Stoichiometric and Catalytic Solid–Gas Reactivity of Rhodium Bis-phosphine Complexes

Organometallics, 2015-04, Vol.34 (8), p.1487-1497

2015

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Amine–Borane Dehydropolymerization: Challenges and Opportunities

Solvent-free anhydrous Li + , Na + and K + salts of [B(3,5-(CF 3 ) 2 C 6 H 3 ) 4 ] - , [BAr F 4 ] - . Improved synthesis and solid-state structures

Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species

B----H Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine-Boranes

Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)]+ Catalyst

The Simplest Amino-borane H2B=NH2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine-Borane Dehydropolymerization

Intermolecular Hydroacylation: High Activity Rhodium Catalysts Containing Small-Bite-Angle Diphosphine Ligands

Bis(σ-amine-borane) Complexes: An Unusual Binding Mode at a Transition-Metal Center

Exploiting Carbonyl Groups to Control Intermolecular Rhodium-Catalyzed Alkene and Alkyne Hydroacylation

Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes

Polyphosphinoborane Block Copolymer Synthesis Using Catalytic Reversible Chain‐Transfer Dehydropolymerization

A Rhodium-Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques

Traceless Chelation-Controlled Rhodium-Catalyzed Intermolecular Alkene and Alkyne Hydroacylation

Solid–State Molecular Organometallic Catalysis in Gas/Solid Flow (Flow-SMOM) as Demonstrated by Efficient Room Temperature and Pressure 1‑Butene Isomerization

[Ir(PCy3)2(H)2(H2BNMe2)]+ as a Latent Source of Aminoborane: Probing the Role of Metal in the Dehydrocoupling of H3B⋅NMe2H and Retrodimerisation of [H2BNMe2]2

Dehydrocoupling of phosphine-boranes using the [RhCpMe(PMe 3 )(CH 2 Cl 2 )][BAr F 4 ] precatalyst: stoichiometric and catalytic studies

Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

Model - state-of-the-art modelling and computational analysis of reactive sites: general discussion

Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes

Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism

Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch

Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [CpIr{κ2‑N,O}][BArF 4]

Intermolecular Alkene and Alkyne Hydroacylation with β-S-Substituted Aldehydes: Mechanistic Insight into the Role of a Hemilabile P-O-P Ligand

Intramolecular C-C agostic complexes: C-C sigma interactions by another name

Stoichiometric and Catalytic Solid–Gas Reactivity of Rhodium Bis-phosphine Complexes

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