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X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center

Angewandte Chemie (International ed.), 2019-07, Vol.58 (28), p.9373-9377

International ed. in English, 2019

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Temperature Dependence of the Catalytic Two- versus Four-Electron Reduction of Dioxygen by a Hexanuclear Cobalt Complex

Journal of the American Chemical Society, 2017-10, Vol.139 (42), p.15033-15042

2017

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Modifying the Steric Properties in the Second Coordination Sphere of Designed Peptides Leads to Enhancement of Nitrite Reductase Activity

Angewandte Chemie International Edition, 2018-04, Vol.57 (15), p.3954-3957

International ed. in English, 2018

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Mechanism of N–N Bond Formation by Transition Metal–Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases

Inorganic chemistry, 2018-04, Vol.57 (8), p.4252-4269

2018

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Resolving the structure of the E1 state of Mo nitrogenase through Mo and Fe K-edge EXAFS and QM/MM calculations

Chemical science (Cambridge), 2019-11, Vol.10 (42), p.9807-9821

2019

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Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (CoxRh100−x@SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates

Small (Weinheim an der Bergstrasse, Germany), 2021-02, Vol.17 (5), p.e2006683-n/a

2021

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A designed Copper Histidine-brace enzyme for oxidative depolymerization of polysaccharides as a model of lytic polysaccharide monooxygenase

Proceedings of the National Academy of Sciences - PNAS, 2023-10, Vol.120 (43), p.e2308286120-e2308286120

2023

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Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity

Nature chemistry, 2019-11, Vol.11 (11), p.1019-1025

2019

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Mechanism of L2,3-edge x-ray magnetic circular dichroism intensity from quantum chemical calculations and experiment—A case study on V(IV)/V(III) complexes

The Journal of chemical physics, 2020-03, Vol.152 (11), p.114107-114107

2020

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Structural correlations of nitrogenase active sites using nuclear resonance vibrational spectroscopy and QM/MM calculations

Faraday discussions, 2023-07, Vol.243, p.253-269

2023

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Preparation and spectroscopic characterization of lyophilized Mo nitrogenase

Journal of biological inorganic chemistry, 2021-02, Vol.26 (1), p.81-91

2021

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Distorted tetrahedral nickel-nitrosyl complexes: spectroscopic characterization and electronic structure

Journal of biological inorganic chemistry, 2016-09, Vol.21 (5-6), p.757-775

2016

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A conformational role for NifW in the maturation of molybdenum nitrogenase P-cluster

Chemical science (Cambridge), 2022-03, Vol.13 (12), p.3489-35

2022

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Methylated Histidines Alter Tautomeric Preferences that Influence the Rates of Cu Nitrite Reductase Catalysis in Designed Peptides

Journal of the American Chemical Society, 2019-05, Vol.141 (19), p.7765-7775

2019

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X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center

Angewandte Chemie, 2019-07, Vol.131 (28), p.9473-9477

2019

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Innentitelbild: X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center (Angew. Chem. 28/2019)

Angewandte Chemie, 2019-07, Vol.131 (28), p.9392-9392

2019

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Designing Artificial Metalloenzymes by Tuning of the Environment beyond the Primary Coordination Sphere

Chemical reviews, 2022-07, Vol.122 (14), p.11974-12045

2022

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The Spectroscopy of Nitrogenases

Chemical reviews, 2020-06, Vol.120 (12), p.5005-5081

2020

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Modifying the Steric Properties in the Second Coordination Sphere of Designed Peptides Leads to Enhancement of Nitrite Reductase Activity

Angewandte Chemie, 2018-04, Vol.130 (15), p.4018-4021

2018

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HYSCORE and QM/MM Studies of Second Sphere Variants of the Type 1 Copper Site in Azurin: Influence of Mutations on the Hyperfine Couplings of Remote Nitrogens

The journal of physical chemistry. B, 2024-04, Vol.128 (14), p.3350-3359

2024

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Primary and Secondary Coordination Sphere Effects on the Structure and Function of S‑Nitrosylating Azurin

Journal of the American Chemical Society, 2023-09, Vol.145 (37), p.20610-20623

2023

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1H HYSCORE Studies of Second Sphere Variants of the Type 1 Copper Site in Azurin: Influence of Mutations on the Hyperfine Couplings of Cys112 CβH2 Protons

Applied magnetic resonance, 2024-09, Vol.55 (9), p.1159-1174

2024

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Spectroscopic Description of the E1 State of Mo Nitrogenase Based on Mo and Fe X-ray Absorption and Mössbauer Studies

Inorganic chemistry, 2019-09, Vol.58 (18), p.12365-12376

2019

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Bimetallic MxRu100−x nanoparticles (M = Fe, Co) on supported ionic liquid phases (MxRu100−x@SILP) as hydrogenation catalysts: Influence of M and M:Ru ratio on activity and selectivity

Journal of catalysis, 2022-03, Vol.407, p.141-148

2022

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Correlating Valence and 2p3d RIXS Spectroscopies: A Ligand-Field Study of Spin-Crossover Iron(II)

Inorganic chemistry, 2024-04, Vol.63 (16), p.7386-7400

2024

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X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center

Temperature Dependence of the Catalytic Two- versus Four-Electron Reduction of Dioxygen by a Hexanuclear Cobalt Complex

Modifying the Steric Properties in the Second Coordination Sphere of Designed Peptides Leads to Enhancement of Nitrite Reductase Activity

Mechanism of N–N Bond Formation by Transition Metal–Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases

Resolving the structure of the E1 state of Mo nitrogenase through Mo and Fe K-edge EXAFS and QM/MM calculations

Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (CoxRh100−x@SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates

A designed Copper Histidine-brace enzyme for oxidative depolymerization of polysaccharides as a model of lytic polysaccharide monooxygenase

Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity

Mechanism of L2,3-edge x-ray magnetic circular dichroism intensity from quantum chemical calculations and experiment—A case study on V(IV)/V(III) complexes

Structural correlations of nitrogenase active sites using nuclear resonance vibrational spectroscopy and QM/MM calculations

Preparation and spectroscopic characterization of lyophilized Mo nitrogenase

Distorted tetrahedral nickel-nitrosyl complexes: spectroscopic characterization and electronic structure

A conformational role for NifW in the maturation of molybdenum nitrogenase P-cluster

Methylated Histidines Alter Tautomeric Preferences that Influence the Rates of Cu Nitrite Reductase Catalysis in Designed Peptides

X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center

Innentitelbild: X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center (Angew. Chem. 28/2019)

Designing Artificial Metalloenzymes by Tuning of the Environment beyond the Primary Coordination Sphere

The Spectroscopy of Nitrogenases

Modifying the Steric Properties in the Second Coordination Sphere of Designed Peptides Leads to Enhancement of Nitrite Reductase Activity

HYSCORE and QM/MM Studies of Second Sphere Variants of the Type 1 Copper Site in Azurin: Influence of Mutations on the Hyperfine Couplings of Remote Nitrogens

Primary and Secondary Coordination Sphere Effects on the Structure and Function of S‑Nitrosylating Azurin

1H HYSCORE Studies of Second Sphere Variants of the Type 1 Copper Site in Azurin: Influence of Mutations on the Hyperfine Couplings of Cys112 CβH2 Protons

Spectroscopic Description of the E1 State of Mo Nitrogenase Based on Mo and Fe X-ray Absorption and Mössbauer Studies

Bimetallic MxRu100−x nanoparticles (M = Fe, Co) on supported ionic liquid phases (MxRu100−x@SILP) as hydrogenation catalysts: Influence of M and M:Ru ratio on activity and selectivity

Correlating Valence and 2p3d RIXS Spectroscopies: A Ligand-Field Study of Spin-Crossover Iron(II)

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