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Radical aryl migration reactions and synthetic applications

Chemical Society reviews, 2015-08, Vol.44 (15), p.522-5245

2015

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Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

Angewandte Chemie (International ed.), 2013-09, Vol.52 (37), p.9781-9785

International ed. in English, 2013

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Semipinacol rearrangement in natural product synthesis

Chemical reviews, 2011-11, Vol.111 (11), p.7523-7556

2011

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Copper‐Complex‐Catalyzed Asymmetric Aerobic Oxidative Cross‐Coupling of 2‐Naphthols: Enantioselective Synthesis of 3,3′‐Substituted C1‐Symmetric BINOLs

Angewandte Chemie International Edition, 2019-08, Vol.58 (32), p.11023-11027

International ed. in English, 2019

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Enantioselective Synthesis of 3,3′‐Disubstituted 2‐Amino‐2′‐hydroxy‐1,1′‐binaphthyls by Copper‐Catalyzed Aerobic Oxidative Cross‐Coupling

Angewandte Chemie International Edition, 2021-03, Vol.60 (13), p.7061-7065

International ed. in English, 2021

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Enantioselective synthesis of cis-hydrobenzofurans bearing all-carbon quaternary stereocenters and application to total synthesis of (‒)-morphine

Nature communications, 2019-06, Vol.10 (1), p.2507-2507, Article 2507

2019

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Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis

Chemical Society reviews, 2017-04, Vol.46 (8), p.2272-235

2017

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Lewis Base/Brønsted Acid Co‐catalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di‐ and Trisubstituted Allylic Alcohols

Angewandte Chemie International Edition, 2019-09, Vol.58 (36), p.12491-12496

International ed. in English, 2019

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Catalytic asymmetric semipinacol rearrangements

Chemical communications (Cambridge, England), 2014-01, Vol.5 (19), p.2393-248

2014

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Asymmetric Intramolecular Hydroalkylation of Internal Olefin with Cycloalkanone to Directly Access Polycyclic Systems

Angewandte Chemie International Edition, 2023-09, Vol.62 (39), p.e202308858-n/a

International ed. in English, 2023

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An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade

Nature communications, 2022-04, Vol.13 (1), p.2335-2335, Article 2335

2022

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Enantioselective Catalytic Aldehyde α‐Alkylation/Semipinacol Rearrangement: Construction of α‐Quaternary‐δ‐Carbonyl Cycloketones and Total Synthesis of (+)‐Cerapicol

Angewandte Chemie International Edition, 2020-05, Vol.59 (22), p.8471-8475

International ed. in English, 2020

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Electrochemical Semipinacol Rearrangements of Allylic Alcohols: Construction of All-Carbon Quaternary Stereocenters

Organic letters, 2019-04, Vol.21 (8), p.2536-2540

2019

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Chiral 1,2,3‐Triazolium Salt Catalyzed Asymmetric Mono‐ and Dialkylation of 2,5‐Diketopiperazines with the Construction of Tetrasubstituted Carbon Centers

Angewandte Chemie International Edition, 2022-02, Vol.61 (9), p.e202114129-n/a

International ed. in English, 2022

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Recent development and applications of semipinacol rearrangement reactions

Chemical science (Cambridge), 2021-07, Vol.12 (27), p.9262-9274

2021

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Collective Total Synthesis of Aspidofractinine Alkaloids through the Development of a Bischler–Napieralski/Semipinacol Rearrangement Reaction

Angewandte Chemie International Edition, 2020-12, Vol.59 (49), p.21954-21958

International ed. in English, 2020

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Enantioselective Construction of 2‑Aryl-2,3-dihydrobenzofuran Scaffolds Using Cu/SPDO-Catalyzed [3 + 2] Cycloaddition

Organic letters, 2021-02, Vol.23 (4), p.1258-1262

2021

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Organo-Cation Catalyzed Asymmetric Homo/Heterodialkylation of Bisoxindoles: Construction of Vicinal All-Carbon Quaternary Stereocenters and Total Synthesis of (−)-Chimonanthidine

Journal of the American Chemical Society, 2018-08, Vol.140 (32), p.10099-10103

2018

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A Facile Approach to Oximes and Ethers by a Tandem NO+‐Initiated Semipinacol Rearrangement and H‐Elimination

Angewandte Chemie International Edition, 2018-10, Vol.57 (40), p.13192-13196

International ed. in English, 2018

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Copper‐Nitrene‐Catalyzed Desymmetric Oxaziridination/1,2‐Alkyl Rearrangement of 1,3‐Diketones toward Bicyclic Lactams

Angewandte Chemie International Edition, 2021-10, Vol.60 (42), p.22688-22692

International ed. in English, 2021

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Electrochemical halogenation/semi-pinacol rearrangement of allylic alcohols using inorganic halide salt: an eco-friendly route to the synthesis of β-halocarbonyls

Green chemistry : an international journal and green chemistry resource : GC, 2019-07, Vol.21 (15), p.414-419

2019

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Brønsted Acid Catalyzed Enantioselective Semipinacol Rearrangement for the Synthesis of Chiral Spiroethers

Angewandte Chemie (International ed.), 2009-10, Vol.48 (45), p.8572-8574

2009

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Stereoselective Construction of Quaternary Carbon Stereocenters via a Semipinacol Rearrangement Strategy

Accounts of chemical research, 2011-11, Vol.44 (11), p.1207-1222

2011

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Photoinduced reductive Reformatsky reaction of α-haloesters and aldehydes or ketones by cooperative dual-metal catalysis

Chemical communications (Cambridge, England), 2023-12, Vol.59 (97), p.14427-1443

2023

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Divergent and Efficient Syntheses of the Lycopodium Alkaloids (−)-Lycojaponicumin C, (−)-8-Deoxyserratinine, (+)-Fawcettimine, and (+)-Fawcettidine

Angewandte Chemie (International ed.), 2013-10, Vol.52 (43), p.11373-11376

2013

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Radical aryl migration reactions and synthetic applications

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

Semipinacol rearrangement in natural product synthesis

Copper‐Complex‐Catalyzed Asymmetric Aerobic Oxidative Cross‐Coupling of 2‐Naphthols: Enantioselective Synthesis of 3,3′‐Substituted C1‐Symmetric BINOLs

Enantioselective Synthesis of 3,3′‐Disubstituted 2‐Amino‐2′‐hydroxy‐1,1′‐binaphthyls by Copper‐Catalyzed Aerobic Oxidative Cross‐Coupling

Enantioselective synthesis of cis-hydrobenzofurans bearing all-carbon quaternary stereocenters and application to total synthesis of (‒)-morphine

Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis

Lewis Base/Brønsted Acid Co‐catalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di‐ and Trisubstituted Allylic Alcohols

Catalytic asymmetric semipinacol rearrangements

Asymmetric Intramolecular Hydroalkylation of Internal Olefin with Cycloalkanone to Directly Access Polycyclic Systems

An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade

Enantioselective Catalytic Aldehyde α‐Alkylation/Semipinacol Rearrangement: Construction of α‐Quaternary‐δ‐Carbonyl Cycloketones and Total Synthesis of (+)‐Cerapicol

Electrochemical Semipinacol Rearrangements of Allylic Alcohols: Construction of All-Carbon Quaternary Stereocenters

Chiral 1,2,3‐Triazolium Salt Catalyzed Asymmetric Mono‐ and Dialkylation of 2,5‐Diketopiperazines with the Construction of Tetrasubstituted Carbon Centers

Recent development and applications of semipinacol rearrangement reactions

Collective Total Synthesis of Aspidofractinine Alkaloids through the Development of a Bischler–Napieralski/Semipinacol Rearrangement Reaction

Enantioselective Construction of 2‑Aryl-2,3-dihydrobenzofuran Scaffolds Using Cu/SPDO-Catalyzed [3 + 2] Cycloaddition

Organo-Cation Catalyzed Asymmetric Homo/Heterodialkylation of Bisoxindoles: Construction of Vicinal All-Carbon Quaternary Stereocenters and Total Synthesis of (−)-Chimonanthidine

A Facile Approach to Oximes and Ethers by a Tandem NO+‐Initiated Semipinacol Rearrangement and H‐Elimination

Copper‐Nitrene‐Catalyzed Desymmetric Oxaziridination/1,2‐Alkyl Rearrangement of 1,3‐Diketones toward Bicyclic Lactams

Electrochemical halogenation/semi-pinacol rearrangement of allylic alcohols using inorganic halide salt: an eco-friendly route to the synthesis of β-halocarbonyls

Brønsted Acid Catalyzed Enantioselective Semipinacol Rearrangement for the Synthesis of Chiral Spiroethers

Stereoselective Construction of Quaternary Carbon Stereocenters via a Semipinacol Rearrangement Strategy

Photoinduced reductive Reformatsky reaction of α-haloesters and aldehydes or ketones by cooperative dual-metal catalysis

Divergent and Efficient Syntheses of the Lycopodium Alkaloids (−)-Lycojaponicumin C, (−)-8-Deoxyserratinine, (+)-Fawcettimine, and (+)-Fawcettidine

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