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Importance of Inherent Substrate Reactivity in Enzyme‐Promoted Carbocation Cyclization/Rearrangements

Angewandte Chemie International Edition, 2017-08, Vol.56 (34), p.10040-10045

Tantillo, Dean J.

International ed. in English, 2017

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Biosynthesis via carbocations: theoretical studies on terpene formation

Natural product reports, 2011-01, Vol.28 (6), p.1035-1053

Tantillo, Dean J

2011

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Post-transition state bifurcations gain momentum – current state of the field

Pure and applied chemistry, 2017-06, Vol.89 (6), p.679-698

2017

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The carbocation continuum in terpene biosynthesis-where are the secondary cations?

Chemical Society reviews, 2010-01, Vol.39 (8), p.2847-2854

Tantillo, Dean J

2010

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Dynamic effects on organic reactivity—Pathways to (and from) discomfort

Journal of physical organic chemistry, 2021-06, Vol.34 (6), p.n/a

Tantillo, Dean J.

2021

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Impacts of noncovalent interactions involving sulfur atoms on protein stability, structure, folding, and bioactivity

Organic & biomolecular chemistry, 2022-12, Vol.21 (1), p.11-23

2022

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Faster, Catalyst! React! React! Exploiting Computational Chemistry for Catalyst Development and Design

Accounts of chemical research, 2016-06, Vol.49 (6), p.1079-1079

Tantillo, Dean J

2016

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Post-transition state bifurcations induce dynamical detours in Pummerer-like reactions

Chemical science (Cambridge), 2018-12, Vol.9 (48), p.8937-8945

2018

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Does Nature Know Best? Pericyclic Reactions in the Daphniphyllum Alkaloid-Forming Cation Cascade

Organic letters, 2016-09, Vol.18 (18), p.4482-4484

Tantillo, Dean J

2016

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Unearthing a sesterterpene biosynthetic repertoire in the Brassicaceae through genome mining reveals convergent evolution

Proceedings of the National Academy of Sciences - PNAS, 2017-07, Vol.114 (29), p.E6005-E6014

2017

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Traversing Biosynthetic Carbocation Landscapes in the Total Synthesis of Andrastin and Terretonin Meroterpenes

Angewandte Chemie International Edition, 2017-10, Vol.56 (41), p.12498-12502

International ed. in English, 2017

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Interrogating chemical mechanisms in natural products biosynthesis using quantum chemical calculations

Wiley interdisciplinary reviews. Computational molecular science, 2020-05, Vol.10 (3), p.e1453-n/a

Tantillo, Dean J.

2020

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How cyclobutanes are assembled in nature - insights from quantum chemistry

Chemical Society reviews, 2014-07, Vol.43 (14), p.542-55

2014

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Dynamic behavior of rearranging carbocations - implications for terpene biosynthesis

Beilstein journal of organic chemistry, 2016-02, Vol.12 (1), p.377-390

2016

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Diverged Plant Terpene Synthases Reroute the Carbocation Cyclization Path towards the Formation of Unprecedented 6/11/5 and 6/6/7/5 Sesterterpene Scaffolds

Angewandte Chemie International Edition, 2018-01, Vol.57 (5), p.1291-1295

International ed. in English, 2018

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A Maze of Dyotropic Rearrangements and Triple Shifts: Carbocation Rearrangements Connecting Stemarene, Stemodene, Betaerdene, Aphidicolene, and Scopadulanol

Journal of organic chemistry, 2018-04, Vol.83 (7), p.3780-3793

2018

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Exploiting the Potential of Meroterpenoid Cyclases to Expand the Chemical Space of Fungal Meroterpenoids

Angewandte Chemie International Edition, 2020-12, Vol.59 (52), p.23772-23781

International ed. in English, 2020

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The chemical biology of the persulfide (RSSH)/perthiyl (RSS·) redox couple and possible role in biological redox signaling

Free radical biology & medicine, 2016-12, Vol.101, p.20-31

2016

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Secondary Carbocations in the Biosynthesis of Pupukeanane Sesquiterpenes

The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2018-10, Vol.122 (40), p.8058-8061

2018

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Synthesis and Structure Revision of Dichrocephones A and B

Angewandte Chemie International Edition, 2018-02, Vol.57 (9), p.2419-2422

International ed. in English, 2018

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Consequences of Conformational Preorganization in Sesquiterpene Biosynthesis: Theoretical Studies on the Formation of the Bisabolene, Curcumene, Acoradiene, Zizaene, Cedrene, Duprezianene, and Sesquithuriferol Sesquiterpenes

Journal of the American Chemical Society, 2009-06, Vol.131 (23), p.7999-8015

2009

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The Correct Structure of AquatolideExperimental Validation of a Theoretically-Predicted Structural Revision

Journal of the American Chemical Society, 2012-11, Vol.134 (45), p.18550-18553

2012

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Prediction of the Structure of Nobilisitine A Using Computed NMR Chemical Shifts

Journal of natural products (Washington, D.C.), 2011-05, Vol.74 (5), p.1339-1343

2011

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Total synthesis and isolation of citrinalin and cyclopiamine congeners

Nature (London), 2014-05, Vol.509 (7500), p.318-324

2014

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Total Synthesis of Oxidized Welwitindolinones and (−)-N-Methylwelwitindolinone C Isonitrile

Journal of the American Chemical Society, 2012-01, Vol.134 (3), p.1396-1399

2012

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Importance of Inherent Substrate Reactivity in Enzyme‐Promoted Carbocation Cyclization/Rearrangements

Biosynthesis via carbocations: theoretical studies on terpene formation

Post-transition state bifurcations gain momentum – current state of the field

The carbocation continuum in terpene biosynthesis-where are the secondary cations?

Dynamic effects on organic reactivity—Pathways to (and from) discomfort

Impacts of noncovalent interactions involving sulfur atoms on protein stability, structure, folding, and bioactivity

Faster, Catalyst! React! React! Exploiting Computational Chemistry for Catalyst Development and Design

Post-transition state bifurcations induce dynamical detours in Pummerer-like reactions

Does Nature Know Best? Pericyclic Reactions in the Daphniphyllum Alkaloid-Forming Cation Cascade

Unearthing a sesterterpene biosynthetic repertoire in the Brassicaceae through genome mining reveals convergent evolution

Traversing Biosynthetic Carbocation Landscapes in the Total Synthesis of Andrastin and Terretonin Meroterpenes

Interrogating chemical mechanisms in natural products biosynthesis using quantum chemical calculations

How cyclobutanes are assembled in nature - insights from quantum chemistry

Dynamic behavior of rearranging carbocations - implications for terpene biosynthesis

Diverged Plant Terpene Synthases Reroute the Carbocation Cyclization Path towards the Formation of Unprecedented 6/11/5 and 6/6/7/5 Sesterterpene Scaffolds

A Maze of Dyotropic Rearrangements and Triple Shifts: Carbocation Rearrangements Connecting Stemarene, Stemodene, Betaerdene, Aphidicolene, and Scopadulanol

Exploiting the Potential of Meroterpenoid Cyclases to Expand the Chemical Space of Fungal Meroterpenoids

The chemical biology of the persulfide (RSSH)/perthiyl (RSS·) redox couple and possible role in biological redox signaling

Secondary Carbocations in the Biosynthesis of Pupukeanane Sesquiterpenes

Synthesis and Structure Revision of Dichrocephones A and B

Consequences of Conformational Preorganization in Sesquiterpene Biosynthesis: Theoretical Studies on the Formation of the Bisabolene, Curcumene, Acoradiene, Zizaene, Cedrene, Duprezianene, and Sesquithuriferol Sesquiterpenes

The Correct Structure of AquatolideExperimental Validation of a Theoretically-Predicted Structural Revision

Prediction of the Structure of Nobilisitine A Using Computed NMR Chemical Shifts

Total synthesis and isolation of citrinalin and cyclopiamine congeners

Total Synthesis of Oxidized Welwitindolinones and (−)-N-Methylwelwitindolinone C Isonitrile

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