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Aspects of the hydrolysis of formamide: revisitation of the water reaction and determination of the solvent deuterium kinetic isotope effect in base

Canadian journal of chemistry, 2002-10, Vol.80 (10), p.1343-1350

2002

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Relationship between amidic distortion and ease of hydrolysis in base. If amidic resonance does not exist, then what accounts for the accelerated hydrolysis of distorted amides?

Journal of the American Chemical Society, 1990-08, Vol.112 (17), p.6383-6385

1990

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Experimental Investigation of the Primary and Secondary Deuterium Kinetic Isotope Effects for Epoxidation of Alkenes and Ethylene with m-Chloroperoxybenzoic Acid

Journal of organic chemistry, 1999-01, Vol.64 (1), p.196-201

1999

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Electrophilic Bromination of 7-Norbornylidene-7'-Norbornane. The Observation of an Unusually Large Inverse Deuterium Kinetic Isotope Effect

Journal of the American Chemical Society, 1995-08, Vol.117 (34), p.8769-8776

1995

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The question of reversible formation of bromonium ions during the course of electrophilic bromination of olefins. 2. The crystal and molecular structure of the bromonium ion of adamantylideneadamantane

Journal of the American Chemical Society, 1985-07, Vol.107 (15), p.4504-4508

1985

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Proton Inventory Study of the Base-Catalyzed Hydrolysis of Formamide. Consideration of the Nucleophilic and General Base Mechanisms

Journal of the American Chemical Society, 2003-02, Vol.125 (7), p.1851-1858

2003

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Effect of distortion on the hydrolytic reactivity of amides. 2. N-Pyramidalization: decomposition of N-benzoylaziridines in aqueous media

Journal of organic chemistry, 1987-03, Vol.52 (5), p.805-808

1987

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Electrophilic bromination of deuterated cyclohexenes in acetic acid containing varying [bromide]: kinetics and product studies

Journal of the American Chemical Society, 1993-02, Vol.115 (4), p.1347-1352

1993

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Recent perspectives concerning the mechanism of H3O+- and hydroxide-promoted amide hydrolysis

Accounts of chemical research, 1992-11, Vol.25 (11), p.481-488

1992

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Electrophilic Additions to anti-Sesquinorbornene. Br2 in Methanol and the Addition of Acetic Acid

Journal of organic chemistry, 1996-05, Vol.61 (10), p.3458-3466

1996

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Observation of an unusually large inverse secondary deuterium kinetic isotope effect for the reaction of a sterically congested olefin with Br2

Journal of the American Chemical Society, 1994, Vol.116 (1), p.419-420

1994

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Acid-Catalyzed Hydration of anti-Sesquinorbornene

Journal of organic chemistry, 1996-11, Vol.61 (23), p.8079-8082

1996

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Determination of oxygen-18 exchange accompanying basic hydrolysis of p-toluamide and N,N-dimethyl-p-toluamide

Journal of organic chemistry, 1988-03, Vol.53 (6), p.1153-1156

1988

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Electrophilic Bromination of Specifically Deuterated Cyclohexenes: A Combined Experimental and Theoretical Investigation

Journal of the American Chemical Society, 1998-03, Vol.120 (11), p.2578-2585

1998

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Concurrent oxygen-18 exchange accompanying the acid-catalyzed hydrolysis of anilides. Implications for the lifetimes of reversibly formed intermediates

Journal of the American Chemical Society, 1990-11, Vol.112 (23), p.8497-8506

1990

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Water Catalyzed Hydrolysis of p-Nitrotrifluoroacetanilide and Trifluoroacetanilide. Carbonyl 18O-Exchange Does Not Accompany the Water Reaction

Journal of the American Chemical Society, 1997-11, Vol.119 (45), p.10969-10975

1997

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Mono and dinuclear M2+ chelates as catalysts for the hydrolysis of organophosphate triesters

Inorganica Chimica Acta, 1989-03, Vol.157 (2), p.233-238

1989

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Observation of an unusually large inverse secondary deuterium kinetic isotope effect for the reaction of a sterically congested olefin with bromine

Journal of the American Chemical Society, 1994-01, Vol.116 (1), p.419-420

1994

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A dynamic NMR investigation of the adamantylideneadamantane/Br2 system. Kinetic and thermodynamic evidence for reversible formation of the bromonium ion/Brn- pairs

Journal of organic chemistry, 1993, Vol.58 (12), p.3401-3406

1993

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Reversible formation of bromonium ions. Preferential reaction of Br- on the Br+ of the bromonium ion produced from the solvolysis of the trans-2-bromotriflate of cyclohexane in MeOH or HOAc containing added bromide

Journal of organic chemistry, 1993-04, Vol.58 (8), p.2122-2127

1993

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Carbonic anhydrase models. 5. Tris(4,5-di-n-propyl-2-imidazolyl)phosphine-zinc(2+) and bis(4,5-di-isopropyl-2-imidazolyl)-2-imidazolylphosphine-zinc(2+). Catalysts facilitating hydrogen carbonate .dblarw. carbon dioxide (HCO3- .dblarw. CO2) interconversion

Journal of the American Chemical Society, 1984-04, Vol.106 (8), p.2421-2431

1984

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Observation of large amounts of carbonyl-18O exchange concurrent with acid-catalyzed hydrolysis of toluamides having amine portions of reduced basicity. The involvement of protonated intermediates in the acid-catalyzed hydrolysis of N-toluoylpyrrole

Journal of the American Chemical Society, 1992-04, Vol.114 (8), p.3088-3092

1992

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Reversible formation of bromonium ions. Preferential reaction of Br- on the Br+ of the bromonium ion produced from the solvolysis of trans-2-bromocyclohexyl triflate in methanol or acetic acid containing added bromide

Journal of organic chemistry, 1993-04, Vol.58 (8), p.2122-2127

1993

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Base-catalyzed hydrolysis and carbonyl-18O exchange kinetics for toluamides containing amine portions of reduced basicity. N-Toluoyl-3,3,4,4-tetrafluoropyrrolidine and N-toluoylpyrrole

Journal of the American Chemical Society, 1992-04, Vol.114 (8), p.3092-3098

1992

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Predominant oxygen-18 exchange accompanying the base hydrolysis of a tertiary toluamide: N-ethyl-N-(trifluoroethyl)toluamide. Assessment of the factors that influence partitioning of anionic tetrahedral intermediates

Journal of the American Chemical Society, 1991-02, Vol.113 (4), p.1288-1294

1991

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Aspects of the hydrolysis of formamide: revisitation of the water reaction and determination of the solvent deuterium kinetic isotope effect in base

Relationship between amidic distortion and ease of hydrolysis in base. If amidic resonance does not exist, then what accounts for the accelerated hydrolysis of distorted amides?

Experimental Investigation of the Primary and Secondary Deuterium Kinetic Isotope Effects for Epoxidation of Alkenes and Ethylene with m-Chloroperoxybenzoic Acid

Electrophilic Bromination of 7-Norbornylidene-7'-Norbornane. The Observation of an Unusually Large Inverse Deuterium Kinetic Isotope Effect

The question of reversible formation of bromonium ions during the course of electrophilic bromination of olefins. 2. The crystal and molecular structure of the bromonium ion of adamantylideneadamantane

Proton Inventory Study of the Base-Catalyzed Hydrolysis of Formamide. Consideration of the Nucleophilic and General Base Mechanisms

Effect of distortion on the hydrolytic reactivity of amides. 2. N-Pyramidalization: decomposition of N-benzoylaziridines in aqueous media

Electrophilic bromination of deuterated cyclohexenes in acetic acid containing varying [bromide]: kinetics and product studies

Recent perspectives concerning the mechanism of H3O+- and hydroxide-promoted amide hydrolysis

Electrophilic Additions to anti-Sesquinorbornene. Br2 in Methanol and the Addition of Acetic Acid

Observation of an unusually large inverse secondary deuterium kinetic isotope effect for the reaction of a sterically congested olefin with Br2

Acid-Catalyzed Hydration of anti-Sesquinorbornene

Determination of oxygen-18 exchange accompanying basic hydrolysis of p-toluamide and N,N-dimethyl-p-toluamide

Electrophilic Bromination of Specifically Deuterated Cyclohexenes: A Combined Experimental and Theoretical Investigation

Concurrent oxygen-18 exchange accompanying the acid-catalyzed hydrolysis of anilides. Implications for the lifetimes of reversibly formed intermediates

Water Catalyzed Hydrolysis of p-Nitrotrifluoroacetanilide and Trifluoroacetanilide. Carbonyl 18O-Exchange Does Not Accompany the Water Reaction

Mono and dinuclear M2+ chelates as catalysts for the hydrolysis of organophosphate triesters

Observation of an unusually large inverse secondary deuterium kinetic isotope effect for the reaction of a sterically congested olefin with bromine

A dynamic NMR investigation of the adamantylideneadamantane/Br2 system. Kinetic and thermodynamic evidence for reversible formation of the bromonium ion/Brn- pairs

Reversible formation of bromonium ions. Preferential reaction of Br- on the Br+ of the bromonium ion produced from the solvolysis of the trans-2-bromotriflate of cyclohexane in MeOH or HOAc containing added bromide

Carbonic anhydrase models. 5. Tris(4,5-di-n-propyl-2-imidazolyl)phosphine-zinc(2+) and bis(4,5-di-isopropyl-2-imidazolyl)-2-imidazolylphosphine-zinc(2+). Catalysts facilitating hydrogen carbonate .dblarw. carbon dioxide (HCO3- .dblarw. CO2) interconversion

Observation of large amounts of carbonyl-18O exchange concurrent with acid-catalyzed hydrolysis of toluamides having amine portions of reduced basicity. The involvement of protonated intermediates in the acid-catalyzed hydrolysis of N-toluoylpyrrole

Reversible formation of bromonium ions. Preferential reaction of Br- on the Br+ of the bromonium ion produced from the solvolysis of trans-2-bromocyclohexyl triflate in methanol or acetic acid containing added bromide

Base-catalyzed hydrolysis and carbonyl-18O exchange kinetics for toluamides containing amine portions of reduced basicity. N-Toluoyl-3,3,4,4-tetrafluoropyrrolidine and N-toluoylpyrrole

Predominant oxygen-18 exchange accompanying the base hydrolysis of a tertiary toluamide: N-ethyl-N-(trifluoroethyl)toluamide. Assessment of the factors that influence partitioning of anionic tetrahedral intermediates

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