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Ex Uno Plures ("Out of One, Many"): New Paradigms for Expanding the Range of Polyolefins through Reversible Group Transfers

Angewandte Chemie (International ed.), 2009-03, Vol.48 (14), p.2464-2472

Sita, Lawrence R.

2009

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An Exceptionally Stable and Scalable Sugar–Polyolefin Frank–Kasper A15 Phase

Angewandte Chemie International Edition, 2020-01, Vol.59 (4), p.1521-1526

International ed. in English, 2020

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Small‐Molecule Modulation of Soft‐Matter Frank–Kasper Phases: A Method for Adding Function to Form

Angewandte Chemie International Edition, 2020-02, Vol.59 (9), p.3563-3567

International ed. in English, 2020

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Dynamic Sub-10-nm Nanostructured Ultrathin Films of Sugar–Polyolefin Conjugates Thermoresponsive at Physiological Temperatures

Journal of the American Chemical Society, 2017-04, Vol.139 (15), p.5281-5284

2017

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End-Group-Functionalized Poly(α-olefinates) as Non-Polar Building Blocks: Self-Assembly of Sugar-Polyolefin Hybrid Conjugates

Angewandte Chemie (International ed.), 2016-04, Vol.55 (15), p.4683-4687

International ed. in English, 2016

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Metal-Mediated Production of Isocyanates, R3ENCO from Dinitrogen, Carbon Dioxide, and R3ECl

Angewandte Chemie (International ed.), 2015-08, Vol.54 (35), p.10220-10224

2015

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Aufbaureaktion Redux: Scalable Production of Precision Hydrocarbons from AlR₃ (R=Et or iBu) by Dialkyl Zinc Mediated Ternary Living Coordinative Chain-Transfer Polymerization

Angewandte Chemie (International ed.), 2010-03, Vol.49 (10), p.1768-1772

2010

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Steric Switching from Photochemical to Thermal Reaction Pathways for Enhanced Efficiency in Metal-Mediated Nitrogen Fixation

Journal of the American Chemical Society, 2016-11, Vol.138 (45), p.14856-14859

2016

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Closing the Loop on Transition-Metal-Mediated Nitrogen Fixation: Chemoselective Production of HN(SiMe3)2 from N2, Me3SiCl, and X-OH (X = R, R3Si, or Silica Gel)

Journal of the American Chemical Society, 2017-12, Vol.139 (48), p.17241-17244

2017

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Dinuclear Bis-Propagators for the Stereoselective Living Coordinative Chain Transfer Polymerization of Propene

Journal of the American Chemical Society, 2013-02, Vol.135 (6), p.2132-2135

2013

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Stereoengineering of Poly(1,3-methylenecyclohexane) via Two-State Living Coordination Polymerization of 1,6-Heptadiene

Journal of the American Chemical Society, 2013-06, Vol.135 (24), p.8778-8781

2013

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Metal-Catalyzed "On-Demand" Production of Carbonyl Sulfide from Carbon Monoxide and Elemental Sulfur

Angewandte Chemie (International ed.), 2015-03, Vol.54 (14), p.4269-4273

International ed. in English, 2015

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Highly Versatile Strategy for the Production of Telechelic Polyolefins

ACS macro letters, 2022-03, Vol.11 (3), p.402-409

2022

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Fine-Tuning the Energy Barrier for Metal-Mediated Dinitrogen NN Bond Cleavage

Journal of the American Chemical Society, 2014-07, Vol.136 (28), p.9906-9909

2014

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De Novo Design of a New Class of “Hard–Soft” Amorphous, Microphase-Separated, Polyolefin Block Copolymer Thermoplastic Elastomers

ACS macro letters, 2015-09, Vol.4 (9), p.921-925

2015

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Programmable Modulation of Co‐monomer Relative Reactivities for Living Coordination Polymerization through Reversible Chain Transfer between “Tight” and “Loose” Ion Pairs

Angewandte Chemie (International ed.), 2010-11, Vol.49 (48), p.9140-9144

2010

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Discrete, Multiblock Isotactic-Atactic Stereoblock Polypropene Microstructures of Differing Block Architectures through Programmable Stereomodulated Living Ziegler-Natta Polymerization

Angewandte Chemie (International ed.), 2006-04, Vol.45 (15), p.2400-2404

2006

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Investigation of Dynamic Intra- and Intermolecular Processes within a Tether-Length Dependent Series of Group 4 Bimetallic Initiators for Stereomodulated Degenerative Transfer Living Ziegler-Natta Propene Polymerization

Advanced synthesis & catalysis, 2008-02, Vol.350 (3), p.439-447

2008

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Dinitrogen Complexation and Extent of NN Activation within the Group 6 “End-On-Bridged” Dinuclear Complexes, {(η5-C5Me5)M[N(i-Pr)C(Me)N(i-Pr)]}2(μ-η1:η1-N2) (M = Mo and W)

Journal of the American Chemical Society, 2010-09, Vol.132 (35), p.12273-12285

2010

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Dinitrogen Activation at Ambient Temperatures: New Modes of H2 and PhSiH3 Additions for an “End-On-Bridged” [Ta(IV)]2(μ-η:η1-N2) Complex and for the Bis(μ-nitrido) [Ta(V)(μ-N)]2 Product Derived from Facile N⋮N Bond Cleavage

Journal of the American Chemical Society, 2007-08, Vol.129 (30), p.9284-9285

2007

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Temporal Control over Two‐ and Three‐State Living Coordinative Chain Transfer Polymerization for Modulating the Molecular Weight Distribution Profile of Polyolefins

Angewandte Chemie International Edition, 2021-09, Vol.60 (36), p.19671-19678

International ed. in English, 2021

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Extreme N⋮N Bond Elongation and Facile N-Atom Functionalization Reactions within Two Structurally Versatile New Families of Group 4 Bimetallic “Side-on-Bridged” Dinitrogen Complexes for Zirconium and Hafnium

Journal of the American Chemical Society, 2007-10, Vol.129 (42), p.12690-12692

2007

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Stereospecific Living Ziegler−Natta Polymerization of 1-Hexene

Journal of the American Chemical Society, 2000-02, Vol.122 (5), p.958-959

2000

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Quantitative Validation of the Living Coordinative Chain-Transfer Polymerization of 1‑Hexene Using Chromophore Quench Labeling

Macromolecules, 2020-07, Vol.53 (14), p.5816-5825

2020

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Highly Efficient, Living Coordinative Chain-Transfer Polymerization of Propene with ZnEt2: Practical Production of Ultrahigh to Very Low Molecular Weight Amorphous Atactic Polypropenes of Extremely Narrow Polydispersity

Journal of the American Chemical Society, 2008-01, Vol.130 (2), p.442-443

2008

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Ex Uno Plures ("Out of One, Many"): New Paradigms for Expanding the Range of Polyolefins through Reversible Group Transfers

An Exceptionally Stable and Scalable Sugar–Polyolefin Frank–Kasper A15 Phase

Small‐Molecule Modulation of Soft‐Matter Frank–Kasper Phases: A Method for Adding Function to Form

Dynamic Sub-10-nm Nanostructured Ultrathin Films of Sugar–Polyolefin Conjugates Thermoresponsive at Physiological Temperatures

End-Group-Functionalized Poly(α-olefinates) as Non-Polar Building Blocks: Self-Assembly of Sugar-Polyolefin Hybrid Conjugates

Metal-Mediated Production of Isocyanates, R3ENCO from Dinitrogen, Carbon Dioxide, and R3ECl

Aufbaureaktion Redux: Scalable Production of Precision Hydrocarbons from AlR₃ (R=Et or iBu) by Dialkyl Zinc Mediated Ternary Living Coordinative Chain-Transfer Polymerization

Steric Switching from Photochemical to Thermal Reaction Pathways for Enhanced Efficiency in Metal-Mediated Nitrogen Fixation

Closing the Loop on Transition-Metal-Mediated Nitrogen Fixation: Chemoselective Production of HN(SiMe3)2 from N2, Me3SiCl, and X-OH (X = R, R3Si, or Silica Gel)

Dinuclear Bis-Propagators for the Stereoselective Living Coordinative Chain Transfer Polymerization of Propene

Stereoengineering of Poly(1,3-methylenecyclohexane) via Two-State Living Coordination Polymerization of 1,6-Heptadiene

Metal-Catalyzed "On-Demand" Production of Carbonyl Sulfide from Carbon Monoxide and Elemental Sulfur

Highly Versatile Strategy for the Production of Telechelic Polyolefins

Fine-Tuning the Energy Barrier for Metal-Mediated Dinitrogen NN Bond Cleavage

De Novo Design of a New Class of “Hard–Soft” Amorphous, Microphase-Separated, Polyolefin Block Copolymer Thermoplastic Elastomers

Programmable Modulation of Co‐monomer Relative Reactivities for Living Coordination Polymerization through Reversible Chain Transfer between “Tight” and “Loose” Ion Pairs

Discrete, Multiblock Isotactic-Atactic Stereoblock Polypropene Microstructures of Differing Block Architectures through Programmable Stereomodulated Living Ziegler-Natta Polymerization

Investigation of Dynamic Intra- and Intermolecular Processes within a Tether-Length Dependent Series of Group 4 Bimetallic Initiators for Stereomodulated Degenerative Transfer Living Ziegler-Natta Propene Polymerization

Dinitrogen Complexation and Extent of NN Activation within the Group 6 “End-On-Bridged” Dinuclear Complexes, {(η5-C5Me5)M[N(i-Pr)C(Me)N(i-Pr)]}2(μ-η1:η1-N2) (M = Mo and W)

Dinitrogen Activation at Ambient Temperatures: New Modes of H2 and PhSiH3 Additions for an “End-On-Bridged” [Ta(IV)]2(μ-η:η1-N2) Complex and for the Bis(μ-nitrido) [Ta(V)(μ-N)]2 Product Derived from Facile N⋮N Bond Cleavage

Temporal Control over Two‐ and Three‐State Living Coordinative Chain Transfer Polymerization for Modulating the Molecular Weight Distribution Profile of Polyolefins

Extreme N⋮N Bond Elongation and Facile N-Atom Functionalization Reactions within Two Structurally Versatile New Families of Group 4 Bimetallic “Side-on-Bridged” Dinitrogen Complexes for Zirconium and Hafnium

Stereospecific Living Ziegler−Natta Polymerization of 1-Hexene

Quantitative Validation of the Living Coordinative Chain-Transfer Polymerization of 1‑Hexene Using Chromophore Quench Labeling

Highly Efficient, Living Coordinative Chain-Transfer Polymerization of Propene with ZnEt2: Practical Production of Ultrahigh to Very Low Molecular Weight Amorphous Atactic Polypropenes of Extremely Narrow Polydispersity

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